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Evtushok G. Yu. Boiko A. V. Yakovenko S. N. Yakovenko E. E. Chang K. C. 《Journal of Applied Mechanics and Technical Physics》2021,62(2):255-265
Journal of Applied Mechanics and Technical Physics - Numerical simulation of dam-break water flow over a horizontal dry bed has been performed. We have modified and verified computational... 相似文献
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Dr. Nataliya V. Maksimchuk Dr. Irina D. Ivanchikova Dr. Kyung Ho Cho Dr. Olga V. Zalomaeva Dr. Vasiliy Yu. Evtushok Kirill P. Larionov Dr. Tatiana S. Glazneva Prof. Jong-San Chang Prof. Oxana A. Kholdeeva 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(23):6985-6992
The catalytic performance of Zr-abtc and MIP-200 metal–organic frameworks consisting of 8-connected Zr6 clusters and tetratopic linkers was investigated in H2O2-based selective oxidations and compared with that of 12-coordinated UiO-66 and UiO-67. Zr-abtc demonstrated advantages in both substrate conversion and product selectivity for epoxidation of electron-deficient C=C bonds in α,β-unsaturated ketones. The significant predominance of 1,2-epoxide in carvone epoxidation, coupled with high sulfone selectivity in thioether oxidation, points to a nucleophilic oxidation mechanism over Zr-abtc. The superior catalytic performance in the epoxidation of unsaturated ketones correlates with a larger amount of weak basic sites in Zr-abtc. Electrophilic activation of H2O2 can also be realized, as evidenced by the high activity of Zr-abtc in epoxidation of the electron-rich C=C bond in caryophyllene. XRD and FTIR studies confirmed the retention of the Zr-abtc structure after the catalysis. The low activity of MIP-200 in H2O2-based oxidations is most likely related to its specific hydrophilicity, which disfavors adsorption of organic substrates and H2O2. 相似文献
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Chemistry of Heterocyclic Compounds - The reaction of 1-amino-8-hydroxyquinolinium mesitylenesulfonate with alkenes and alkynes containing electron-withdrawing substituents was performed in... 相似文献
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