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排序方式: 共有933条查询结果,搜索用时 171 毫秒
1.
Dr. Sabin Llona‐Minguez Dr. Matthieu Desroses Artin Ghassemian Dr. Sylvain A. Jacques Dr. Lars Eriksson Rebecka Isacksson Tobias Koolmeister Dr. Pål Stenmark Dr. Martin Scobie Prof. Thomas Helleday 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(20):7394-7398
A two‐step synthesis of structurally diverse pyrrole‐containing bicyclic systems is reported. ortho‐Nitro‐haloarenes coupled with vinylic N‐methyliminodiacetic acid (MIDA) boronates generate ortho‐vinyl‐nitroarenes, which undergo a “metal‐free” nitrene insertion, resulting in a new pyrrole ring. This novel synthetic approach has a wide substrate tolerance and it is applicable in the preparation of more complex “drug‐like” molecules. Interestingly, an ortho‐nitro‐allylarene derivative furnished a cyclic β‐aminophosphonate motif. 相似文献
2.
Emiliana Damian Lars Eriksson Magnus Sandstrm 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(9):m419-m420
Sodium trichloromethanesulfonate monohydrate, Na+·CCl3SO3−·H2O, crystallizes in P21/a with all the atoms located in general positions. The trichloromethanesulfonate (trichlate) anion consists of pyramidal SO3 and CCl3 groups connected via an S—C bond in a staggered conformation with approximate C3v symmetry. The water molecule is hydrogen bonded to the sulfonate O atoms, with one water H atom forming weak bifurcated O—H⋯O hydrogen bonds to two different trichlate ions. Two water O atoms and three O atoms from different SO3 groups form a square‐pyramidal arrangement around the sodium ion. 相似文献
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引言和主要结果设X是一维随机变量,其分布函数为;。={F_θ:θ∈Θ}此处,v 为σ有限测度.记(?)={F_θ:θ∈Θ}.设参数空间Θ和行动空间(?)都是 R_1的子集,损失函数 L(θ,α),对每一个固定的θ,是α的下半连续函数,且存在θ的单调上升函数 q(θ),使a)对每一个固定的θ,L(θ,α)在α=q(θ)处达到极小,且当 α>q(θ)时非降,当α
α有 L(θ_α,α′)> 相似文献
5.
在误差序列为Lqmixingale情形下,给出了半参数回归模型中β和g(t)估计,研究了估计量的q阶平均相合性在较一般的条件下,得到了理想的结果 相似文献
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Pure-silica optical waveguides, fiber couplers, and high-aspect ratio submicrometer channels for electrokinetic separation devices 总被引:1,自引:0,他引:1
Mogensen KB Eriksson F Gustafsson O Nikolajsen RP Kutter JP 《Electrophoresis》2004,25(21-22):3788-3795
A new fabrication procedure for integration of ultraviolet transparent pure-silica planar waveguides, fiber couplers and high-aspect ratio submicrometer channels is presented. Only a single photolithographic mask step is required. The channels are 80-90 microm deep and the width can be reduced to about 0.5 microm, corresponding to a height-to-width ratio of more than 150. The core of the waveguides consists of pure silicon dioxide, which is favorable over doped silica, due to the absence of absorption centers associated with the dopants. This furthermore improves the long-term stability of the waveguides, because of an increased radiation resistance of the glass. The propagation loss decreases from 1.0 dB/cm at 200 nm to 0.2 dB/cm at 800 nm, which, to our knowledge, is the lowest propagation loss reported for integrated planar waveguides in the ultraviolet wavelength region to date. The effective optical path length is 1.2 mm for an absorbance cell with a nominal length of 1.0 mm, indicating effective suppression of stray light. The limit of detection for paracetamol when present in the entire channel network was determined to 3 microg/mL. Finally, the applicability of the fabricated devices for capillary electrophoresis was evaluated by separation of caffein, paracetamol and ketoprofone using absorbance detection at 254 nm. 相似文献
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P.-A. Eriksson A.-C. Albertsson K. Eriksson J.-A.E. Månson 《Journal of Thermal Analysis and Calorimetry》1998,53(1):19-26
The thermal stability of heat-stabilised polyamide 66 in an oxidative environment is evaluated by DSC. The oxidative stability
of the polyamide decreases as a result of repeated injection moulding. The results also indicate that the presence of glass
fibres in the polyamide has a negative influence on the oxidative stability. Both isothermal and dynamic DSC measurements
seem to be useful tools for assessing the stability of polyamides and there is a relationship between data determined using
both procedures.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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