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1.
Ioana Dumitriu Alan Edelman 《Annales de l'Institut Henri Poincaré (B) Probabilités et Statistiques》2005,41(6):1083-1099
In this paper we examine the zero and first order eigenvalue fluctuations for the β-Hermite and β-Laguerre ensembles, using tridiagonal matrix models, in the limit as β→∞. We prove that the fluctuations are described by multivariate Gaussians of covariance O(1/β), centered at the roots of a corresponding Hermite (Laguerre) polynomial. The covariance matrix itself is expressed as combinations of Hermite or Laguerre polynomials respectively.We show that the approximations are of real value even for small β; we can use them to approximate the true functions even for the traditional β=1,2,4 values. 相似文献
2.
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4.
During irradiation of liquid samples of 1-vinylimidazole, 2-vinylnaphthalene, 2-vinylpyridine, 4-vinylpyridine and 1,1-diphenylethene
with positive muons, radicals of the type MuCH2ĊHAr (Ar=the appropriate aromatic group), and the MuCH2ĊPh2 radical were observed by transverse field μSR; the muon hyperfine couplings are considered in the context of the effectiveness
of the aryl groups in delocalising the unpaired electron. 相似文献
5.
Gašper Jaklič Jernej Kozak Marjeta Krajnc Vito Vitrih Emil Žagar 《Numerical Algorithms》2007,45(1-4):49-60
In this paper, three-pencil lattices on triangulations are studied. The explicit representation of a lattice, based upon barycentric
coordinates, enables us to construct lattice points in a simple and numerically stable way. Further, this representation carries
over to triangulations in a natural way. The construction is based upon group action of S
3 on triangle vertices, and it is shown that the number of degrees of freedom is equal to the number of vertices of the triangulation.
相似文献
6.
Juan Pablo Trelles Emil Pfender Joachim Heberlein 《Plasma Chemistry and Plasma Processing》2006,26(6):557-575
The dynamics of the electric arc inside a direct current non-transferred arc plasma torch are simulated using a three-dimensional, transient, equilibrium model. The fluid and electromagnetic equations are solved numerically in a fully coupled approach by a multiscale finite element method. Simulations of a torch operating with argon and argon–hydrogen under different operating conditions are presented. The model is able to predict the operation of the torch in steady and takeover modes without any further assumption on the reattachment process except for the use of an artificially high electrical conductivity near the electrodes, needed because of the equilibrium assumption. The results obtained indicate that the reattachment process in these operating modes may be driven by the movement of the arc rather than by a breakdown-like process. It is also found that, for a torch operating in these modes and using straight gas injection, the arc will tend to re-attach to the opposite side of its original attachment. This phenomenon seems to be produced by a net angular momentum on the arc due to the imbalance between magnetic and fluid drag forces. 相似文献
7.
A necessary and sufficient condition for regularity of the
-Neumann operator on (0,q)-forms in a smooth bounded pseudoconvex domain in Cn is that the orthogonal projections onto
-closed forms of degrees (0,q−1), (0,q), and (0,q+1) all be regular.
The first author partially supported by NSF Grant DMS-8701038 相似文献
8.
Kolman David Heberlein Joachim Pfender Emil 《Plasma Chemistry and Plasma Processing》1998,18(1):73-89
In this paper, a comprehensive model for thermal plasma chemical vapor deposition (TPCVD) with liquid feedstock injection is documented. The gas flow is assumed to be steady, of a single temperature. Radiation and charged species contributions are excluded, but extensive homogeneous and heterogeneous chemistry is included. The liquid phase is traced by considering individual droplets. Discussion on the model's application to diamond production from acetone in a hydrogen–argon plasma is included. The major conclusions are: (1) Liquid injection possesses a capability to deliver the hydrocarbon precursor directly onto the deposition target. (2) For the case of complete evaporation of the droplet before reaching the substrate, the deposition rate is similar to that obtained with gaseous precursors. (3) The computational results compare well with experimental data. The modeling results can be used to optimize the injection parameters with regard to the deposition rate. 相似文献
9.
Distribution of some major and trace elements in Danube Delta lacustrine sediments and soil 总被引:2,自引:0,他引:2
L. C. Dinescu E. Steinnes O. G. Duliu C. Ciortea T. E. Sjobakk D. E. Dumitriu M. M. Gugiu M. Haralambie 《Journal of Radioanalytical and Nuclear Chemistry》2004,262(2):345-354
Sediment cores collected from lakes Mesteru and Furtuna (eastern part), Sontea channel and soil samples collected from Caraorman
bar, all located in the Danube Delta, were analyzed for 42 elements (Ag, Al, As, Be, Na, Mg, P, S, K, Ca, Sc, Ti, V, Cr, Mn,
Fe, Co, Ni, Cu, Zn, Ga, As, Se, Br, Rb, Sr, Y, Mo, Ag, Cd, In, Sn, Sb, Cs, Ce, Hf, Hg, Tl. Pb, Bi, Th. U) by instrumental
neutron activation analysis (INAA), thick target proton induced X-ray emission (TT-PIXE) and inductively coupled plasma-mass
spectrometry (ICP-MS). The INAA and TTPIXE yielded total concentrations whereas the ICP-MS data reflected the fractions soluble
in 14M HNO3. The ICP-MS data exhibited surface enrichment relative to the lower part of the sediment core of Cu, Zn, As, Ag, Cd, In,
Sn, Sb, Hg, Tl, Pb, and Bi, most prominently by Cd and Hg. Their vertical distribution in the investigated cores generally
reflected the pollution history of recent sediments in Danube delta, showing a steady increase until the end of the 1980s
followed by a slow decrease after 1990. The vertical profiles of most remaining elements were characterized by a relatively
uniform distribution along the cores. In some cases, the concentrations of As, Cd, Cu, Cr, Mn, Ni and Pb exceeded minimum
thresholds of safety, as defined by the Romanian regulations. The elemental composition of the sediment below 20 cm depth
(total concentrations) was similar to that of the upper continental crust (UCC) for most elements. Values distinctly higher
than UCC were observed for As, Sb (factor ~5) and Cr, Ni, Cu (factor 2 to 3). The nitric acid soluble element concentrations
in the soil samples in some cases showed increased values at the surface as compared to 30 cm depth, either due to air pollution
or to the action of plants. In no case a large contribution to the topsoil from atmospheric deposition was evident, indicating
that the surface contamination of the sediments was mainly by riverine transport.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
10.
Complexes of osmium tetroxide with nitrogen ligands were developed and used in our laboratory as probes of the DNA structure. Here, we show that the complex of osmium tetroxide with 2,2'-bipyridine (Os,bipy) can be used for modification and electrochemical detection of proteins at neutral pH. Salmon luteinizing hormone (SLH) containing two tryptophan (Trp) residues and human luteinizing hormone (HLH) containing one Trp were modified by Os,bipy and measured by differential pulse adsorptive stripping voltammetry (DPAdSV) at a hanging mercury drop electrode (HMDE). The intensity of the DPAdSV catalytic signals corresponded to the number of Trp residues in the peptide molecule. Decreasing pH of the background electrolyte from 6.6 to 3.8 led to the increase of DPAdSV signals, suggesting that at pH 3.8, the DPAdSV detection limit might be well below 1 ng/ml. Our results suggest that Os,bipy is potentially useful for chemical modification of proteins. 相似文献