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排序方式: 共有685条查询结果,搜索用时 578 毫秒
1.
Polymer melting and polymer powder sintering by thermal analysis 总被引:10,自引:0,他引:10
Sintering of polymeric powders is a peculiar characteristic of many processing technologies, including rotational moulding
and selective laser sintering (SLS). During polymer sintering, viscosity reduction in the melt state promotes densification
of polymer powders, through a double stage mechanism, involving powder coalescence and bubble removal. In particular, sintering
of semi-crystalline polymers is strongly influenced by the melting behaviour. Nevertheless, melting itself in absence of pressure
is not necessarily accompanied by powder sintering, unless low viscosities are achieved. In this work, the melting and sintering
behaviour of recycled high density polyethylene (rHDPE) have been analysed through differential scanning calorimetry (DSC)
and Thermomechanical Analysis (TMA). Efficient models capable of describing the melting temperature distribution and rate
of sintering of rHDPE powders have been developed, highlighting the inherent differences between the two distinct processes.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
2.
Verardo G Pagani E Geatti P Martinuzzi P 《Analytical and bioanalytical chemistry》2003,376(5):659-667
The composition of the surface waxes of three apple ( Malus domestica L.) cultivars ("Florina", "Golden B" and "Ozark Gold") has been studied by means of spectroscopic and GC–MS analysis of the class-fractionated mixture of components. Odd n -alkanes, mainly C27 and C29 molecules, are prevalent in the saturated fraction. Small concentrations of alkenes were also found; the C28:1 component is strongly (72%) in excess over the other 1-alkenes. Straight-chain esters (mainly of palmitic acid) of saturated primary alcohols (C18–C30) were also detected; whereas the acyl moiety is made up essentially of an even number of carbons, the alcohol counterpart does not exhibit this characteristic. Aldehydes are present (C20–C30) with the homologue patterns C26–C30 most strongly represented. Straight-chain free secondary alcohols characterize the waxes of "Florina" and "Ozark Gold"; the hydroxy function is located far from the extremity of the carbon framework. Outstanding is the presence of three alcohols with 29 carbon centres. These alcohols are accompanied by free straight-chain primary alcohols, mainly with even-numbered carbon chains in the range C26–C30. Free fatty acids are present; all of have a framework of even-numbered carbon chains mainly in the range C16–C20. C18:1 (oleic acid) is well represented. 相似文献
3.
Gaetano Alberghina Maria Emanuela Amato Francesco Agatino Bottino Antonino Corsaro Salvatore Fisichella 《Journal of heterocyclic chemistry》1986,23(6):1747-1752
The 1H-nmr data of some (Z)-α-(p-substituted-phenyl)-β-(2-furyl), -(2-pyrrolyl), and -(N-methyl-2-pyrrolyl)-acrylonitriles have been investigated to indicate the preferred conformation and to establish the conformational preferences of the β-heterocyclic ring. The ultraviolet spectra have been discussed in order to obtain information about the chromophores responsible for the absorption. The infrared spectra have been analyzed for the identification of the main absorption frequencies of cyano and ethylenic groups and to assign the characteristic absorption bands to specific normal vibrations of the heteroaromatic nuclei. 相似文献
4.
Atmospheric bulk deposition of major and trace elements was measured at Venice from November 1995 to October 1997. Collection was carried out using polyethylene bulk passive samplers, samples being collected bi-weekly. In order to highlight the contribution of the atmosphere to water chemistry and particle budgets in the Lagoon of Venice, the geochemical composition (Si, Al, Ca, Mg, K, Na, Mn, Cr, Zn, Pb, Cd, Cu, As) of dissolved and insoluble bulk fractions was determined by AAS + ICP mass spectrometry. Great sample variability was found, with almost two orders of magnitude between maximum and minimum values for several metals. All fluxes in 1995/96 were 30% lower than in 1996/97, ranging from -3% (Ca) to -57% (Li), except for Zn, Cd and As. On the contrary, the solubility of all elements decreased during 1996/97. Partitioning between soluble and insoluble phases shows that Al, Cr, Fe and Si are mainly in the insoluble form, whereas for As, Ca, Cu, Mg, Na, Ni, K, Pb and Zn the dissolved fraction represents 50-90% of total input. The amount of particle load affects partitioning between dissolved and particulate, especially for Al and Pb. Seasonal variability was evident. The lowest pH values (approximately 5.2) were recorded in winter, causing an increase of solubility for all metals except for As, which showed the highest solubility in summer. 相似文献
5.
We study Sobolev embedding theorems in Lorentz-Zygmund spaces. Some limiting cases are considered.Supported by M.U.R.S.T. (1990). 相似文献
6.
Bazzicalupi C Bencini A Berni E Bianchi A Ciattini S Giorgi C Maoggi S Paoletti P Valtancoli B 《The Journal of organic chemistry》2002,67(25):9107-9110
The synthesis of three new tris-macrocycles, containing three [12]aneN(4) (L1), [12]aneN(3)O (L2), or [14]aneN(4) (L3) moieties appended to a tren unit, is reported. The crystal structure of the [(Na(ClO(4))(6)) subset L1(2)H(13)]Na(6)Cl(2)(ClO(4))(12) compound shows the anionic cluster [Na(ClO(4))(6)](5)(-) assembled inside the cavity defined by two bowl-shaped polyammonium receptors, held by multiple charge-charge and hydrogen bond interactions. 相似文献
7.
Summary
This paper is dedicated to the study of Hilbert functions and Betti numbers of the projective varieties in a flat family. We prove that the Hilbert function H(X
y
,n),y Y-a parameter scheme-is lower semicontinuous for any fixed n. In case Y is integral and noetherian we obtain the well-known fact that the set V Y where H(X
y
,n)is maximal for all n's is open and nonempty. We show also that bi(X
y
)-the i- th Betti number of Xy—is upper semicontinuous for y V. The paper contains also a number of results concerning the relations among the various Betti numbers.Member of G.N.S.A.G.A.-C.N.R. Supported in part by M.P.I. (Italian Minstry of Education). 相似文献
8.
Greco MN Hawkins MJ Powell ET Almond HR Corcoran TW de Garavilla L Kauffman JA Recacha R Chattopadhyay D Andrade-Gordon P Maryanoff BE 《Journal of the American Chemical Society》2002,124(15):3810-3811
The serine protease cathepsin G (EC 3.4.21.20; Cat G), which is stored in the azurophilic granules of neutrophils (polymorphonuclear leukocytes) and released on degranulation, has been implicated in various pathological conditions associated with inflammation. By employing high-throughput screening, we identified beta-ketophosphonic acid 1 as a moderate inhibitor of Cat G (IC(50) = 4.1 microM). We were fortunate to obtain a cocrystal of 1 with Cat G and solve its structure by X-ray crystallography (3.5 A). Structural details from the X-ray analysis of 1.Cat G served as a platform for optimization of this lead compound by structure-based drug design. With the aid of molecular modeling, substituents were attached to the 3-position of the 2-naphthyl ring of 1, which occupies the S1 pocket of Cat G, to provide an extension into the hydrophobic S3 region. Thus, we arrived at analogue 7 with an 80-fold potency improvement over 1 (IC(50) = 53 nM). From these results, it is evident that the beta-ketophosphonic acid unit can form the basis for a novel class of serine protease inhibitors. 相似文献
9.
A number of acetylene and mixed acetylene-nitrile complexes of tungsten and molybdenum halides have been prepared and investigated. Depending on the acetylene and the reaction conditions, one or more acetylene molecules may be coordinated to the metal. In the latter case acetylenes are coordinated not as single molecules but in systems of conjugated non-aromatic double bonds. On the basis of the supposed structure of such species and on their pyrolysis products a decomposition scheme is proposed, which consider the formation of apparent metathesis products as a side reaction of the cyclotrimerization of acetylenes to aromatic hydrocarbons. 相似文献
10.
The synthesis and photophysical evaluation of modified nucleoside analogues in which a five-membered heterocycle (furan, thiophene, oxazole, and thiazole) is attached to the 5-position of 2′-deoxyuridine are reported. The furan-containing derivative is identified as the most promising responsive nucleoside of this family due to its emission quantum efficiency and degree of sensitivity to its microenvironment. The furan moiety was then attached to the 5-position of 2′-deoxycytidine as well as the 8-position of adenosine and guanosine. Photophysical evaluation of these four furan-containing nucleoside analogues reveals distinct differences in the absorption, emission, and quantum efficiency depending upon the class of nucleoside (pyrimidine or purine). Comparing the photophysical properties of all furan-containing nucleosides, identifies the furan thymidine analogue, 5-(fur-2-yl)-2′-deoxyuridine, as the best candidate for use as a responsive fluorescent probe in nucleic acids. 5-(Fur-2-yl)-2′-deoxyuridine was then converted to the corresponding phosphoramidite and site specifically incorporated into DNA oligonucleotides with greater than 88% coupling efficiency. Such furan-modified oligonucleotides form stable duplexes upon hybridization to their complementary DNA strands and display favorable fluorescent features. 相似文献