排序方式: 共有27条查询结果,搜索用时 31 毫秒
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Mohammad El-khateeb Hassan Abul-Futouh Hadil Alshurafa Helmar Görls Wolfgang Weigand 《应用有机金属化学》2020,34(11):e5940
Substitution of carbonyl ligands of the hydrogenase model complex [Fe2(μ-SeCH2CH(Me)CH2Se-μ)(CO)6] ( A ), by 1,1′-bis (diphenylphosphino)ferrocene (dppf), 1,2-bis (diphenylphosphino)benzene (dppbz) or 1,2-bis (diphenylphosphino)acetylene (dppac) is investigated. It is found that the reaction product depends on the diphosphine used. In the case of dppf, the product is an intramolecular bridged disubstituted complex [Fe2{μ-SeCH2CH(Me)CH2Se-μ}(CO)4{μ,κ1,κ1(P,P)-dppf}] ( 1 ), while the dppac-reaction produces an intermolecular bridged tetra-iron model [Fe2{μ-SeCH2CH(Me)CH2Se-μ}(CO)5]2{μ,κ1,κ1(P,P)-dppac} ( 2 ). However, the dppbz-reaction gives [Fe2{μ-SeCH2CH(Me)CH2Se-μ}(CO)4{κ2(P,P)-dppbz}] ( 3 ) in which the dppbz ligand is bonded to one Fe atom in a chelated manner. The newly prepared complexes ( 1 – 3 ) have been characterized by elemental analysis, IR, 1H-, 13C{H}-, 31P{H}-, 77Se{H}-NMR spectroscopy and X-ray structure determination. The electrochemical behavior of 2 and 3 , in absence and presence of acid, is described by cyclic voltammetric measurements in CH2Cl2. 相似文献
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Treatment of the hydrosulfido tungsten complex CpW(CO)3SH with acid chlorides (RCOCl) or sulfonyl chlorides (RSO2Cl) affords CpW(CO)3SCOR (1) [R = Me (a), CH2Cl (b), Ph (c), 4-C6H4NO2 (d)] and CpW(CO)3SSO2R (2) [R = Me (a), Ph (b), 4-C6H4Cl (c), 4-C6H4NO2 (d)], respectively. The novel complexes, 1 and 2, were fully characterized by elemental analyses, IR and 1H NMR spectroscopy. The solid state structures of CpW(CO)3SCOPh (1c) and CpW(CO)3SSO2-4-C6H4Cl (2c) were determined by an X-ray crystal structure analysis. 相似文献
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Mousa Al-Noaimi Mohammad El-khateeb Salim F. Haddad Haytham Saadeh 《Transition Metal Chemistry》2010,35(7):877-883
Abstract
Five ruthenium complexes bearing phenylazo-(2-(phenylthio))phenylmethine ligands of the general type trans-[RuII(bpy)(L)(Cl)2] (C1–C5) {L = YC6H4N=NC(COCH3)=NC6H4(2-SC6H5), H (L1), Cl (L2), OCH3 (L3), Br (L4), or NO2 (L5)} have been synthesized. The crystal structure of trans-[Ru(bpy)(L1)(Cl)2] (C1) is reported and shows no direct metal–S interaction. The complexes have been characterized through spectroscopic (IR, UV/vis and NMR) and electrochemical (CV) techniques. The electrochemical parameters (E L(L)) of the azoimine ligands are reported. 相似文献7.
The synthesis and characterization of several new ruthenium complexes containing heterocyclic thiolate ligands are described. CpRu(PPh3)2Cl reacts with thiolate anions to give CpRu(PPh3)2SR, (1) [R = 2-mercaptobenzimidazolyl (a), 2-mercaptobenzothiazolyl (b), and 2-mercaptobenzoxazolyl (c)] in good yields. The CpRu(PPh3)-(CO)SR (2) complexes are obtained by treating (1) with CO gas in THF at room temperature. The one-pot reaction of CpRu(PPh3)2Cl, thiolate anions with chelate bisphosphine ligands (P–P), gave CpRu(P–P)SR where P–P = Ph2PCH2PPh2 (dppm) (3); Ph2PCH2CH2PPh2 (dppe) (4). 相似文献
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Deeb Taher Firas Awwadi Mohammad El-khateeb Heinrich Lang 《Transition Metal Chemistry》2012,37(6):601-604
New homo-trimetallic complexes of general formula?1,1??-fc[SeFeCp(CO)2]2 (fc?=?Fe(??5-C5H4)2) are accessible in high yield by the reaction of 1,1??-fc(SeLi)2, which is generated from 1,1??-fc(SeSiMe3)2 and n-BuLi, with two equivalents of CpFe(CO)2I. Photolytic CO-substitution reactions of the organoiron diselenolate with bis-phosphines at ?50?°C using 1:2 (metal/ligand) molar ratio afforded 1,1??-fc(SeFeCp(P^P)2. All these complexes were characterized by physicochemical and spectroscopic methods. 相似文献
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Khaled Shawakfeh Mohammad El-khateeb Deeb Taher Helmar Görls Wolfgang Weigand 《Transition Metal Chemistry》2008,33(3):387-391
A synthetic study of ruthenium complexes containing pentafluorobenzenethiolato ligand is presented. The bis(triphenylphosphine)
complex CpRu(PPh3)2SC6F5 (1) is prepared from CpRu(PPh3)2Cl and C6F5S− in high yield. This complex is readily reacted with CO gas to give the mixed carbonyl-phosphine complex CpRu(PPh3)(CO)SC6F5 (2) and with NOBF4 at room temperature to give [CpRu(PPh3)(NO)SC6F5]BF4 (3). The one-pot reaction of CpRu(PPh3)2Cl, dppa ligands, and C6F5S− produces CpRu(dppa)SC6F5 [dppa = bis(diphenylphosphino)methane: dppm (4); bis(diphenylphosphino)ethane: dppe (5)]. Complexes (1)–(5) have been characterized by spectroscopic techniques (i.r., 1H-n.m.r., 31P-n.m.r.) and by elemental analysis. The X-ray structural analysis of (5) is reported.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献