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Thiolate self-assembly on gold has proven to be a valuable technique for assembling monolayers on a wide variety of substrates. However, the oxidative instability of the thiols, especially aromatic thiols and alpha,omega-dithiols, presents several difficulties. Shown here is that thiocyanates, easily synthesized stable thiol derivatives, can be directly assembled on gold surfaces with no auxiliary reagents required. Assembly is complete in 24 h and leaves a similar gold thiolate structure as seen in typical thiol self-assembled monolayers. 相似文献
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Using the approach of Rulla (1996 SIAM J. Numer. Anal. 33, 68-87)for analysing the time discretization error and assuming moreregularity on the initial data, we improve on the error boundderived by Barrett and Blowey (1996 IMA J. Numer. Anal. 16,257-287) for a fully practical piecewise linear finite elementapproximation with a backward Euler time discretization of amodel for phase separation of a multi-component alloy. 相似文献
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Single-molecule transistors (SMTs) incorporating individual small molecules are unique tools for examining the fundamental physics and chemistry of electronic transport in molecular systems at the single nanometer scale. We describe the fabrication and characterization of such devices, and the synthesis and surface attachment chemistry of novel transition metal complexes that have been incorporated into such SMTs. We present gate-modulated inelastic electron tunneling vibrational spectroscopy of single molecules, strong Kondo physics (TK ∼ 75 K) as evidence of excellent molecule/electrode electronic coupling, and a demonstration that covalent attachment chemistry can produce SMTs that survive repeated thermal cycling to room temperature. We conclude with a look ahead at the prospects for these nanoscale systems. 相似文献
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He J Fu Q Lindsay S Ciszek JW Tour JM 《Journal of the American Chemical Society》2006,128(46):14828-14835
We have studied electron transport in bipyridyl-dinitro oligophenylene-ethynelene dithiol (BPDN) molecules both in an inert environment and in aqueous electrolyte under potential control, using scanning tunneling microscopy. Current-voltage (IV) data obtained in an inert environment were similar to previously reported results showing conductance switching near 1.6 V. Similar measurements taken in electrolyte under potential control showed a linear dependence of the bias for switching on the electrochemical potential. Extrapolation of the potentials to zero switching bias coincided with the potentials of redox processes on these molecules. Thus switching is caused by a change in the oxidation state of the molecules. 相似文献
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Z. Sosin R. Płaneta T. Ciszek J. Brzychczyk W. Gawlikowicz K. Grotowski S. Micek P. Pawłowski A. Wieloch A.J. Cole D. Benchekroun E. Bisquer A. Chabane M. Charvet B. Cheynis A. Demeyer P. Désesquelles E. Gerlic A. Giorni D. Guinet D. Heuer P. Lautesse L. Lebreton A. Lléres M. Stern L. Vagneron J.B. Viano 《The European Physical Journal A - Hadrons and Nuclei》2001,11(3):305-310
The shape of the velocity distributions of charged particles projected on the beam direction can be explained if emissions
from the hot projectile-like fragment and the target-like fragment are supplemented by an emission from an intermediate velocity
source located between them. The creation of this source is predicted by a two-stage reaction model where, in the second stage,
some of the nucleons identified in the first stage as participants form a group of clusters located in the region between
the colliding nuclei. The cluster coalescence process is governed on the average by the maximum value of entropy, although
its fluctuations are also significant. The properties of the intermediate velocity source are precisely described, including
the isotopic composition of the emitted particles.
Received: 12 March 2001 / Accepted: 20 June 2001 相似文献
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