排序方式: 共有22条查询结果,搜索用时 15 毫秒
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Chukwuemeka Okolie Yasmeen F. Belhseine Yimeng Lyu Dr. Matthew M. Yung Dr. Mark H. Engelhard Dr. Libor Kovarik Dr. Eli Stavitski Dr. Carsten Sievers 《Angewandte Chemie (International ed. in English)》2017,56(44):13876-13881
The conversion of methane into alcohols under moderate reaction conditions is a promising technology for converting stranded methane reserves into liquids that can be transported in pipelines and upgraded to value‐added chemicals. We demonstrate that a catalyst consisting of small nickel oxide clusters supported on ceria–zirconia (NiO/CZ) can convert methane to methanol and ethanol in a single, steady‐state process at 723 K using O2 as an abundantly available oxidant. The presence of steam is required to obtain alcohols rather than CO2 as the product of catalytic combustion. The unusual activity of this catalyst is attributed to the synergy between the small Lewis acidic NiO clusters and the redox‐active CZ support, which also stabilizes the small NiO clusters. 相似文献
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Chukwuemeka P. Azubuike Héctor Rodríguez Augustine O. Okhamafe Robin D. Rogers 《Cellulose (London, England)》2012,19(2):425-433
Suitable α-cellulose and cellulose II powders for use in the pharmaceutical industry can be derived from maize cob. α-Cellulose
was extracted from an agricultural residue (maize cobs) using a non-dissolving method based on inorganic substances. Modification
of this α-cellulose was carried out by its dissolution in the ionic liquid 1-butyl-3-methylimidazolium chloride ([C4mim]Cl), and subsequent regeneration by addition of either water or acetone at room temperature, or of boiling water. X-ray
diffraction and infrared spectroscopy results showed that the regenerated celluloses had lower crystallinity, and proved that
the treatment with [C4mim]Cl led to the conversion of the crystalline structure of α-cellulose from cellulose I to cellulose II. Thermogravimetric
analysis and differential scanning calorimetry data showed quite similar thermal behavior for all cellulose samples, although
with somewhat lower stability for the regenerated celluloses, as expected. The comparison of physicochemical properties of
the regenerated celluloses and the native cellulose mainly suggests that the regenerated ones might have better flow properties.
For some of the characterizations carried out, it was generally observed that the sample regenerated with boiling water had
more similar characteristics to the α-cellulose sample, evidencing an influence of the regeneration strategy on the resulting
powder after the ionic liquid treatment. 相似文献
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Characterization of dicarboxylic naphthenic acid fraction compounds utilizing amide derivatization: Proof of concept 下载免费PDF全文
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The Athabasca oil sand bitumen contains a homologous series of tricyclic terpanes containing 19–30 C atoms per molecule. The structure of the most abundant member, the C23 trycyclane, has now been elucidated. 相似文献
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In this review those fluorinated compounds which have found a role as anti-cancer agents are summarized. The emphasis is to highlight the important drugs but also to highlight the latest developments on emerging compounds. This has been done as comprehensively as possible with the objective of informing readers of some of the latest developments in this area. 相似文献
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Omeje EO Osadebe PO Esimone CO Nworu CS Kawamura A Proksch P 《Natural product research》2012,26(19):1775-1781
Column fractionation and purification of an n-hexane fraction led to the isolation of three lupeol-based triterpenoid esters from the leaves of the Eastern Nigeria mistletoe, Loranthus micranthus Linn parasitic on a local kola nut tree, Kola acuminata. These three compounds were adequately characterised using a combination of UV/visible, IR, NMR (13C-NMR and 1H-NMR), DEPT, MS and two-dimensional correlation (H-H COSY, Hetero-nuclear Single Quantum Correlation (HSQC), HMBC, NOE and NOESY) studies as 7β,15α-dihydroxyl-lup-20(29)-ene-3β-esters of palmitic (I), stearic (II) and eicosanoic acids (III). The characterisation of other isolated compounds is ongoing. Remarkably, this is the first report of the existence of fatty acid esters of an unusual 7β,15α-dihydroxylated lupeol in the Eastern Nigeria mistletoe. These isolated compounds might contribute in part to the numerous established bio-activities of the Eastern Nigeria mistletoes. 相似文献