X-ray determination of the mean amplitudes of vibration and debye temperatures of some rare earth monochalcogenides

The x-ray diffraction intensities of Bragg reflections have been measured at room temperature for thulium selenide, samarium sulphide, samarium selenide and samarium telluride. On the basis of a common amplitude approximation, the Debye-Waller factor, the mean amplitude of vibration and the Debye temperature have been evaluated. The values of the Debye temperatures and mean amplitudes of vibration are 176±16°K, 0·185 ± 0·017 Å (TmSe), 155 ± 7°K, 0·244 ± 0·012 Å (SmS), 153 ± 14°K, 0·221 ± 0·020 Å (SmSe) and 151 ± 20°K, 0·204 ± 0·027 Å (SmTe).     

帕隆藏布流域堆积体边坡的工程地质特征及稳定性评价

位于藏东南的帕隆藏布流域,处在东喜马拉雅构造结的北缘,是新构造强烈隆升区,断层、褶皱等地质构造发育。在青藏高原隆升及气候变化等内外动力作用下,研究区内堆积体分布广泛,具有独特的工程地质特征并成为该区内地质灾害的主要物源。由于河流的下切及川藏公路的修建,形成了许多高陡的堆积体边坡,以冰碛边坡最为典型。由于其特殊的物源特征及形成过程,冰碛物具有粒度分布范围广、粗粒含量多等与其他沉积物不同的粒度特征。冰碛物粒度分布范围广的特征,导致随着研究尺度的不同,其结构特征也不相同,具有明显的尺度效应。冰碛土的力学强度一般强于其他堆积体,但受不同粒径颗粒的含量及分布、形成时代的影响,其力学特征也有所差异。作者对川藏公路沿线部分典型的剖面进行了量测,所量测的剖面虽然只是整个斜坡的一部分,与经验数据相比,仍表现出高陡的特征,而且很多边坡在既高且陡的形态下仍能保持稳定。本文以极限平衡理论为基础,采用多种方法对这类边坡的稳定性进行计算分析,求出边坡的安全系数。考虑各种地震烈度下边坡的稳定性,得出这些边坡的安全系数与地震加速度具有严格的指数相关关系。     

"Green"-enzymatic synthesis of pegylated phenolic macromer and polymer

Environmentally benign synthesis of novel pegylated polyphenolics, by combining the extraordinary selectivities of a lipase and an oxidase to develop polymeric electrolytes for applications in dye sensitised solar cells.     

Biotinylated Poly(3-Hexylthiophene-co-3-Methanolthiophene): A Langmuir Monolayer-Forming Copolymer

Abstract

Copolymers of 3-substituted thiophenes have been synthesized by organosynthetic routes. The chemical synthesis of the copolymer was carried out by dehydrogenation of 3-hexylthiophene and 3-methanolthiophene. Attachment of biotin to the resulting copolymer, poly(3-hexylthiophene-co-3-methanolthiophene) [PMHT], is accomplished by room temperature esterification using N,N-dicyclohexylcarbodiimide (DCC) and 4-pyrrolidinopyridine as catalyst. The resulting copolymers have well-defined chemical and electronic structures and molecular weights. The biotinylated copolymer forms a stable monolayer at the air-water interface due to the polar groups along the polymer backbone.     

Dose–Response Relationship of Photobiomodulation Therapy on Matrix Metalloproteinase in Healing Dynamics of Diabetic Neuropathic Ulcers—An in vivo Study

Individuals with diabetic foot ulcers have overlapped the inflammatory, proliferative and remodeling phase, making the tissue vulnerable to delayed healing responses. We aimed to establish the dose–response relationship of photobiomodulation therapy of different doses and matrix metalloproteinases in the healing dynamics of diabetic neuropathic ulcers. Diabetes was induced in 126 Albino Wistar rats, and neuropathy was induced to the hind paw by a sciatic nerve injury method. An excisional wound was created on the neuropathy-induced leg. Photobiomodulation therapy of dosages 4, 6, 8, 10, 12 and 15 J cm⁻² and wavelength 655 nm and 808 nm was irradiated. Photobiomodulation therapy of dosages 4, 6 and 8 J cm⁻² showed better wound healing properties with optimized levels of matrix metalloproteinases-1 and 8. We observed a strong dose response in the experimental group treated with 6 and 8 J cm⁻². The findings from the present study conclude that photobiomodulation therapy of dosages 4, 6 and 8 J cm⁻² is suggestive of usefulness in diabetic neuropathic ulcer healing. Markers like matrix metalloproteinases may give a clear direction on response to the therapy. Based on the findings from the present study, we recommend to validate the findings for safety and efficacy in future through human prospective randomized controlled clinical trials.     

W1{infty}-convergence of the discrete free boundary for obstacle problems

We examine the discrete free boundaries arising from a finiteelement discretization of a variational inequality. We giveL error bounds for the Hausdorff distance of the discrete andtrue free boundary, as well as for the normals. The theoreticalresults are confirmed by numerical experiments in two and threedimensions.