Polymer modification and synthesis using sulphenyl derivatives—10. A 13C NMR study of adducts of benzenesulphenyl chloride with cis-1,4-polybutadiene

Analysis of the CHS and CHCl multiplets in the ¹³C NMR spectra of modified polymers indicates that the addition of benzenesulphenyl chloride to cis-1,4-polybutadiene is not wholly random. The analysis of the methylene resonances was inconclusive because of peak overlap and other uncertainties. The conclusion that the partially saturated polymers have some blocky character is in general agreement with earlier results on the physical properties of the adducts and on the kinetics of the addition reaction.     

Runaway Electron Measurements in the EAST Tokamak

An experimental study of runaway electrons in the EAST tokamak has been performed by a recently developed multi‐channel hard x‐ray diagnostics based on NaI(TL) scintillator detectors. It is found that in the current quench phase, the inductive loop voltage plays an important role in the generation of runaway electrons. And the avalanche mechanism was the main mechanism for runaway electrons after the disruptions. The distribution and transportation of runaway electrons were also investigated by multi‐channel hard x‐ray diagnostics. It is also found that the intensity of runaway electrons emission in the core plasma was much higher than those in the downside of the cross‐section, while the emission intensity of runaway electrons in the core plasma was almost the same. Calculated shrinking coefficient of runaway electrons emission after the plasma disruption was about 26 m/s according to the experimental data (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Monte Carlo simulation of spin relaxation in core-shell nanowires of dilute magnetic semiconductors

Spin transport behaviour in stand-alone and core-shell nanowire (NW) structure composed of dilute magnetic semiconductor (DMS) has been analysed using Semi-classical Monte Carlo approach. Inspired by recent attempts on exploring various factors instrumental in determining the spin dynamics, we have employed four DMS materials, namely, CdMnS, CdMnSe, ZnMnSe and CdMnTe for our study. Dominant mechanisms for spin relaxation, D'yakonov-Perel and Elliot-Yafet, have been actively employed in our heuristic model to simulate the spin transport. The dependence of spin relaxation length (SRL) on the diameter of the core has been observed and explained. The first order calculations used to develop the model shows the superiority of the core-shell structure over stand-alone nanowire (NW) structure in terms of spin transport.     

Observation of Runaway Electron Behaviour During Disruptions in LHCD Discharges in the HT‐7 Tokamak

Production of runaway electrons during disruptions has been observed in the HT‐7 Tokamak. The runaway current plateaus, which can carry part of the pre‐disruptive current, are observed in lower‐hybrid current drive (LHCD) limiter discharges. It is found that the runaway current can mitigate the disruptions effectively. We can use gas puffing to increase the line‐averaged density to restrain the runaway electrons and rebuild the plasmas after the disruptions. Detailed observations are presented on the runaway electrons generated following disruptions in the HT‐7 tokamak discharges. The results indicate that the magnetic oscillations play a significant role in the loss of runaway electrons in disruptions. There are two important preconditions to rebuild plasmas by runaway electrons after the disruptions. One of them are weak magnetic oscillations; another one are LHWs (lower‐hybrid waves) (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

On the simulation of the pivot bearing inside HDD

The pivot bearing is an important mechanical component in HDD. Several quasi-rigid (QR) body motion modes of the HDD are related to the stiffness of the pivot bearing such as the axial translation mode, the lateral translation mode and the rocking mode. In the shock simulation of the HDD, the pivot bearing is often simplified to identical theoretical models wherein the bearing is simulated with springs or beams. The overall axial stiffness and the radial stiffness of these models are often carefully checked and match well with the experimental values. However, how well these theoretical models represent the rotational stiffness of the bearing is still not fully understood. This is partly due to the difficulties in obtaining the experimental rotational stiffness of the pivot bearing. In this paper, three different theoretical models are examined for the simulation of the bearing. The rotational stiffness of these three theoretical models is derived analytically. The theoretical formulations are verified with the finite element analysis results.     

Synthesis, characterization of complexes of Co(II), Ni(II), Cu(II) and Zn(II) with 12-membered Schiff base tetraazamacrocyclic ligand and the study of their antimicrobial and reducing power

Schiff base tetraazamacrocyclic ligand, L (C(40)H(28)N(4)) and its complexes of types, [MLX(2)] and [CuL]X(2) (M=Co(II), Ni(II), Zn(II); X=Cl(-), NO(3)(-)) were synthesized and characterized by elemental analyses, mass, (1)H NMR, IR, UV-vis, magnetic susceptibility and molar conductance data. An octahedral geometry has been proposed for all the complexes except the copper(II) complexes which have a square planar environment. The reducing power of the Co(II) and Cu(II) complexes have been checked and compared. The ligand (L) and its complexes have also been screened against different fungi and bacteria in vitro.