全文获取类型
收费全文 | 63篇 |
免费 | 1篇 |
专业分类
化学 | 43篇 |
力学 | 2篇 |
数学 | 13篇 |
物理学 | 6篇 |
出版年
2024年 | 1篇 |
2023年 | 1篇 |
2021年 | 1篇 |
2018年 | 2篇 |
2016年 | 4篇 |
2014年 | 1篇 |
2013年 | 8篇 |
2012年 | 3篇 |
2011年 | 6篇 |
2010年 | 3篇 |
2009年 | 1篇 |
2008年 | 4篇 |
2007年 | 2篇 |
2006年 | 1篇 |
2005年 | 2篇 |
2004年 | 2篇 |
2003年 | 3篇 |
2002年 | 2篇 |
2001年 | 2篇 |
2000年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1987年 | 2篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1974年 | 2篇 |
1972年 | 1篇 |
1930年 | 1篇 |
排序方式: 共有64条查询结果,搜索用时 19 毫秒
1.
This paper analyses the implications of persistent growth upon the stability properties of dynamic models. Besides the traditional concept of asymptotic stability, new stability criteria-strong/weak absolute, strong/weak relative, strong/weak logarithmic stability-are introduced, and global stability conditions for satisfying these criteria are stated for general first-order autonomous differential equations. The conflict between rapidity of growth and the degree of stability is demonstrated. Economic applications of the stability theorems are illustrated within the growth models of Harrod and Solow. 相似文献
2.
Mycotoxins are secondary metabolites, formed by the action of fungi on agricultural crops in the field or during storage. These metabolites are highly toxic to animals and humans and high levels have been measured in agricultural crops. In order to evaluate human risks due to ingestion of mycotoxin-contaminated food different methods have been developed for analysis of mycotoxins in cereals and maize. In this project the focus was on mycotoxins in agricultural soil and the fate of these toxins in the soil-water-plant system. Two different mycotoxins were selected in the study: zearalenone (ZON) produced by species of Fusariumor Aspergillusand ochratoxin A (OTA) produced by species of Penicillium. We developed a method for analysis of these toxins in soil. Soil samples were extracted with methanol-water (9:1) and purified by solid-phase extraction (SPE, C8-columns). The final extract was analysed using high-pressure liquid chromatography (HPLC) with fluorescence detection. A Phenyl Hexyl column was used to separate the toxins. The detection limits obtained were 0.1 and 1.0 microg kg(-1) dry weight (dw) for OTA and ZON, respectively. The developed method has been used for analysis of different soils in connection with growth chamber experiments. The soil types used in the growth chamber experiments were a sandy soil, a sandy clay soil, and a soil with high content of organic matter. The recovery was determined as 85.8 and 93.4% and the repeatability to 5.1 and 12.8% for OTA and ZON, respectively. The reproducibility obtained was 8.5 and 15.0% for soil samples, representing concentration levels from 0.2-30 microg kg(-1) dw (OTA) and from 1.0-100 microg kg(-1) dw (ZON). 相似文献
3.
Rapid prototyping of polymer microsystems via excimer laser ablation of polymeric moulds 总被引:1,自引:0,他引:1
Jensen MF McCormack JE Helbo B Christensen LH Christensen TR Geschke O 《Lab on a chip》2004,4(4):391-395
This study presents a novel method for rapid prototyping of polymer microsystems. The method is based on excimer laser ablation of a thermally and mechanically stable polymer, such as PEEK (poly-ether-ether-ketone). A negative of the desired microsystem is laser machined in PEEK, which can then be used directly for hot embossing or injection moulding of a series of prototypes. This approach is very rapid and considerably cheaper than more traditional approaches to toolmaking, while still performing well in terms of reproduction of tool dimensions. The reduction in time and cost for a master tool using this method opens up new possibilities for testing small series in the R&D phase of a microsystem. Finally, two particular applications of the technique are presented. 相似文献
4.
Sorption of spruce acetylated galactoglucomannans (GGM) onto different pulps, among which unbleached and peroxide-bleached mechanical pulps, and unbleached and bleached kraft (BK) pulps, was studied as a means of understanding the retention of acetylated GGMs in mechanical pulping and papermaking. The fibre surface coverage of lignin and carbohydrates was estimated by X-ray photoelectron spectroscopy (XPS) or electron spectroscopy for chemical analysis (ESCA). GGM sorption was clearly favoured on kraft pulps. Hardly any differences in sorption were, however, observed between unbleached and BK pulps, even if the surface coverage of lignin was lower on the bleached pulp. Neither thermomechanical pulp (TMP) nor chemithermomechanical pulp (CTMP) manufactured from spruce sorbed any acetylated GGMs. Peroxide bleaching of the pulp did not increase sorption. Only CTMP produced from aspen sorbed some GGMs. The anionic charge of neither chemical nor mechanical pulps influenced GGM sorption. 相似文献
5.
Sten Scheibye Bjarne S. Pedersen S.-O. Lawesson 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-2):271-272
Abstract Recent studies have shown that the dimer of p-methoxyphenylthionophosphinesulfide, 1, is a very superior thiation reagent, as ketones, amides, and esters are in most cases quantitatively converted to their thio-analogues. 相似文献
6.
Steffen Dachwitz Bjarne Scharkowski Prof. Norbert Sewald 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(72):18043-18046
Mild transition-metal catalysed cross-couplings enable direct functionalisation of biocatalytically halogenated tryptophans with alkyl iodides, representing a new alternative for late-stage derivatisations of halogenated aromatic amino acids. Moreover, this strategy enables preparation of (homo)tryptophan regioisomers in a simple two-step synthesis using a Pd-catalysed Negishi cross coupling. This method provides access to non-canonical constitutional surrogates of tryptophan, ready for use in peptide synthesis. 相似文献
7.
Bernas A Kumar N Mäki-Arvela P Laine E Holmbom B Salmi T Murzin DY 《Chemical communications (Cambridge, England)》2002,(10):1142-1143
Development of a new heterogeneous catalytic pathway for isomerization of linoleic acid to conjugated linoleic acids at mild reaction conditions over Ni/H-MCM-41 in a soluted system. 相似文献
8.
9.
Andreia F. Sousa Alessandro Gandini Armando J. D. Silvestre Carlos Pascoal Neto José J. C. Cruz Pinto Christer Eckerman Bjarne Holmbom 《Journal of polymer science. Part A, Polymer chemistry》2011,49(10):2281-2291
This article reports the successful synthesis and characterization of two types of completely biobased polymers prepared by the polycondensation or polytransesterification of suberin fragments, isolated by different procedures and from two different vegetable sources. These polymerizations were conducted with different experimental conditions in terms of the type of catalyst, the reaction medium and temperature, as well as the molar ratio between the reactive moieties. The ensuing linear or partly crosslinked polyesters were characterized by conventional spectroscopic techniques, SEC, DSC, XRD, DMA, and TGA. These hydrophobic materials represent an original contribution to the growing field of polymers from renewable resources. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
10.
Hansen M Jacobsen NW Nielsen FK Björklund E Styrishave B Halling-Sørensen B 《Analytical and bioanalytical chemistry》2011,400(10):3409-3417
This paper presents the development, optimization and validation of a methodology to determine nine key steroid hormones (viz.
pregnenolone, progesterone, dehydroepiandrosterone, androstenedione, testosterone, dihydrotestosterone, estrone, 17α-estradiol
and 17β-estradiol) expressed in the steroidogenesis in biological fluids. The analytical method allows for the determination
of steroid hormones in blood plasma and serum down to 0.08–0.16 ng/mL for estrogens, 0.20–0.36 ng/mL for androgens and 0.36–0.43 ng/mL
for progestagens. These limits of detection were obtainable using a two-step solid-phase clean-up for fractionation and elimination
of interfering lipids (fatty acids, phospholipids, glycerides and sterols) from the steroid hormones. The accuracy of the
method was 50–112% in the range 0.10 to 2.00 ng/mL. 相似文献