Generating complex ontology instances from documents

This paper presents a novel Information Extraction system able to generate complex instances from free text available on the Web. The approach is based on a non-monotonical processing over ontologies, and makes use of entity recognizers and disambiguators in order to adequately extract and combine instances and their relations. Experiments conducted over the archaeology research domain provide encouraging results in both efficiency and efficacy and suggest that the tool is suitable for its application on other similar Semantic Web resources.     

The Gauss Theorem for Domain Decompositions in Sobolev Spaces

This paper belongs to a broad line of research leaded by Herrera, which encompasses a good number of numerical methods such as Localized Adjoint Method (LAM), Eulerian-Lagrangian LAM (ELAM) and Trefftz-Herrera Method. The results presented in this paper are required in order to incorporate Herrera's general theory in a Sobolev-space setting. In particular, this article introduces a class of partitions (or domain decompositions) whose internal boundaries belong to a category of manifolds with corners, here also presented. Then a version of Gauss (or divergence) theorem, in a wider sense, is established and an explicit integral formula is associated for any given linear partial differential operator L, its adjoint and concomitant. The structure of the bilinear concomitant induced by L is first determined. Then the required formula is given over that class of domain decompositions. Finally, an integral formula well on the way of the Green-Herrera formula is settled.     

Formation of a surface covalent organic framework based on polyester condensation

The reaction between 1,3,5-tris(4-hydroxyphenyl)benzene and benzene-1,3,5-tricarbonyl trichloride leads to polyester condensation and formation of a novel COF on an Au(111) surface. The characterization performed in situ by means of variable temperature STM and XPS reveals the formation of an array of hexagonal cavities with ca. 2 nm size.     

Novel Tetraspiroorthocarbonates as Successful Anti-shrinking Agents for the Photopolymerization of Epoxy Monomers

A pair of novel tetrafunctional spiroorthocarbonates (TETRASOC) was prepared in three stages. First, glycerol was reacted with tetraethyl orthocarbonate to form a pair of isomeric hemi spiroorthocarbonates (HEMI SOC-OLs) by monocyclization of glycerol. Formation of these two isomers depends on terminal or adjacent hydroxyl groups of glycerol reacting with the tetraethylorthocarbonate to form five and six-membered ring HEMI SOC-OLs. Second, the HEMI SOC-OLs were made to undergo another cyclization reaction by reacting with 1,3-propanediol, to form a pair of spiroorthocarbonates with one hydroxyl group (SOC-OL). In the third stage, the SOC-OL was used as nucleophylic reactant to displace the bromine atom of pentaerythritol bromide to form the final product TETRASOC. A volume change study was carried out to determine the efficiency of TETRASOC as an anti-shrinking additive finding that even at a low concentration of 7 mol%, it caused a 2.18% expansion of the polymeric volume of a bis epoxycyclohexane monomer (3,4-EP). Dynamic Mechanical Analysis (DMA) determined that the flexibilization induced by the TETRASOC in the polyether derived from 3,4-EP did not adversely impact the mechanical properties of the polymer.     

Crystallization Kinetics of Polypropylene-polyethylene-based Copolymers

A crystallization kinetics analysis of several polypropylene-polyethylene (PP-PE), PP-rich copolymers was made by means of differential scanning calorimetry. The crystallization was studied via calorimetric measurements at different cooling rates. Several additives were added to the base material. Some test samples were subjected to artificial ageing processes. A modified isoconversional method was used to describe the crystallization process under non-isothermal conditions. The value of the Avrami parameter was determined for primary and secondary crystallization. This revised version was published online in August 2006 with corrections to the Cover Date.     

Tuning delamination of layered covalent organic frameworks through structural design

Exfoliation of a family of polyacetylenic porous layered covalent organic frameworks by means of a simple sonication procedure results in the obtention of nanolayer structures as observed by AFM and TEM measurements. Systematic AFM analysis of the isolated nanostructures reveals that the degree of exfoliation depends on the polymer architecture, thinner layers being observed when the pore size decreases.     

Boosting video tracking performance by means of Tabu Search in intelligent visual surveillance systems

In this paper, we present a fast and efficient technique for the data association problem applied to visual tracking systems. Visual tracking process is formulated as a combinatorial hypotheses search with a heuristic evaluation function taking into account structural and specific information such as distance, shape, color, etc.