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Liu Fan Bi Shiqing Wang Xiaorui Leng Xuanye Han Mengmeng Xue Baoda Li Qianqian Zhou Huiqiong Li Zhen 《中国科学:化学(英文版)》2019,62(6):739-745
By intelligently utilizing the odd-even effect existing in the melting points of alkanes as presented in the basic textbook of Organic Chemistry, different alkoxy groups were introduced to modify the structure of commercial Spiro-OMeTAD to give new Spiro derivatives of Spiro-OEtTAD, Spiro-OPrTAD, Spiro-OiPrTAD and Spiro-OBuTAD, with the aim to adjust the molecular packing status in perovskite solar cells as hole transporting compounds. Excitedly, with the introduction of ethoxy groups instead of the methoxy ones in Spiro-OMeTAD, Spiro-OEtTAD-based perovskite solar cells demonstrated the highest device performance of 20.16%, higher than that of Spiro-OMeTAD(18.64%). 相似文献
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Baoda Lin 《Tetrahedron letters》2009,50(15):1714-6031
A rhodium-copper-TBAF-catalyzed hydroarylation of alkynes with aryl trimethoxysilanes is described. The procedure utilizes a catalytic amount of copper(II) acetate, rhodium, PPh3 and TBAF·3H2O under air. Some asymmetric alkynes gave the products with high regioselectivities. 相似文献
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Baoda Xue Dr. Shiqing Bi Shuai You Jiyu Zhou Guangbao Wu Rui Meng Boxin Wang Jianqiu Wang Xuanye Leng Prof. Yuan Zhang Prof. Xiangdong Ma Prof. Huiqiong Zhou 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(4):1076-1082
Reaching the full potential of solar cells based on photo-absorbers of organic-inorganic hybrid perovskites requires highly efficient charge extraction at the interface between perovskite and charge transporting layer. This demand is generally challenged by the presence of under-coordinated metal or halogen ions, causing surface charge trapping and resultant recombination losses. These problems can be tackled by introducing a small molecule interfacial anchor layer based on dimethylbiguanide (DMBG). Benefitting from interactions between the nitrogen-containing functional groups in DMBG and unsaturated ions in CH3NH3PbI3 perovskites, the electron extraction of TiO2 is dramatically improved in association with reduced Schottky–Read–Hall recombination, as revealed by photoluminescence spectroscopy. As a consequence, the power conversion efficiency of CH3NH3PbI3 solar cells is boosted from 17.14 to 19.1 %, showing appreciably reduced hysteresis. The demonstrated molecular strategy based on DMBG enables one to achieve meliorations on key figures of merit in halide perovskite solar cells with improved stability. 相似文献
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In this article a palladium‐catalyzed Kumada reaction was reported. The procedure was mild and tolerated a series of aryl bromides, affording the biaryls in good to excellent yield. 相似文献
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