全文获取类型
收费全文 | 165篇 |
免费 | 9篇 |
国内免费 | 1篇 |
专业分类
化学 | 115篇 |
晶体学 | 1篇 |
数学 | 31篇 |
物理学 | 28篇 |
出版年
2023年 | 1篇 |
2021年 | 5篇 |
2020年 | 2篇 |
2019年 | 6篇 |
2018年 | 9篇 |
2017年 | 3篇 |
2016年 | 5篇 |
2015年 | 3篇 |
2014年 | 4篇 |
2013年 | 10篇 |
2012年 | 18篇 |
2011年 | 11篇 |
2010年 | 12篇 |
2009年 | 9篇 |
2008年 | 8篇 |
2007年 | 6篇 |
2006年 | 14篇 |
2005年 | 5篇 |
2004年 | 6篇 |
2003年 | 4篇 |
2002年 | 6篇 |
2001年 | 3篇 |
2000年 | 2篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1994年 | 3篇 |
1990年 | 3篇 |
1989年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1978年 | 1篇 |
1974年 | 1篇 |
1970年 | 1篇 |
1969年 | 1篇 |
1933年 | 1篇 |
排序方式: 共有175条查询结果,搜索用时 245 毫秒
1.
Stewart C Zieminski A Blessing S Crittenden R Draper P Dzierba A Heinz R Krider J Marshall T Martin J Sambamurti A Smith P Sulanke T Gomez R Dauwe L Haggerty H Malamud E Nikolic M Hagopian S Abrams R Ares J Goldberg H Halliwell C Margulies S McLeod D Salminen A Solomon J Wu G Ellsworth R Goodman J Gupta S Yodh G Watts T Abramov V Antipov Y Baldin B Denisov S Glebov V Gorin Y Kryshkin V Petrukhin A Polovnikov S Sulyaev R 《Physical review D: Particles and fields》1990,42(5):1385-1395
2.
Mikko Keränen Marcin Gnyba Paavo Raerinne Terho Kololuoma Arto Maaninen Juha T. Rantala 《Journal of Sol-Gel Science and Technology》2004,31(1-3):369-372
Sol–gel adhesive material for isostatic hotpressing lamination process was synthesized using 3-aminopropyltrimethoxysilane (APTES), 3-glycidyloxypropyltrimethoxysilane (GPTS) and methacryloxypropyltrimethoxysilane (MPTS) as precursors. Reaction dynamics between APTES and GPTS was followed on-line with Raman spectroscopy. The lamination process was optimized by varying hotpressing times and pressures at the constant temperature. Mechanical shear strength properties were found to be excellent for studied composition, 25–30 kg/cm2 at its best. One possible application of laminated polycarbonate (PC) structure is a soldier helmet visor. Therefore, the ballistic protection properties were tested by shooting with 1.1 gram standard fragment, and determining the v50 velocity value, which corresponds to 50% perforation. The laminated structure gave 5.7% better protection compared with the solid polycarbonate. The laminated components were found to have high optical transparency at the visible wavelengths as well as high environmental stability. 相似文献
3.
Both (±)-17α-hydroxytacamonine (3) and its 17β-isomer (4) were synthesized in two steps (one-pot) from aldehyde mixture 5/6 via the cyanohydrin reaction. NMR spectral characterization of isomer 3 revealed it to be unidentical with natural 17-hydroxytacamonine, whereas spectral data of isomer 4 were in agreement with those published for the natural isomer. The configuration at C-17 was confirmed by NOE difference spectroscopy. 相似文献
4.
The synthesis of aldehyde intermediates suitable for the preparation of indole alkaloids of the tacamine ( 1 ) type is described. The four possible aldehydes 4–7 were prepared from methyl 5-ethylnicotinate ( 8 ) in a few simple steps using a base-catalyzed epimerization as the final step (Schemes 1 and 2). The key aldehyde 4 , which is an analogue of the important vincamine intermediate 3 (‘Oppolzer's aldehyde’), was finally converted into the indole alkaloid (±)-apotacamine ( 21 ). 相似文献
5.
P. Salminen 《Probability Theory and Related Fields》1981,55(1):41-53
Summary One considers a simple exclusion particle jump process on , where the underlying one particle motion is a degenerate random walk that moves only to the right. One starts with the configuration in which the left halfline is completely occupied and the right one free. It is shown that the number of particles at time t between site [u t] and [v t], divided by t, converges a.s. to
, where f might be called the density profile. It is explicitely determined and shown to be an affine function. Secondly we prove that the distribution of the process looked at by an observer travelling at constant speed u, converges weakly to the Bernoulli measure with density f(u), as the time tends to infinity.This work has been supported by the Deutsche Forschungsgemeinschaft 相似文献
6.
Rajendran Arunachalam Eswaran Chinnaraja Arto Valkonen Kari Rissanen Palani S. Subramanian 《应用有机金属化学》2019,33(11)
The multidentate ligand H2 L upon complexation with Zn (II) and Cd (II) provide a one‐dimensional polymeric networks. These coordination polymers (CPs) CP‐1 and CP‐2 containing Zn (II) and Cd (II) metals respectively are well characterized. The single crystal structural analysis confirms the formation of one‐dimensional coordination polymer with zigzag fashion in CP‐1 and ladder chain CP‐2 . Both the CPs are applied as catalysts to synthesize various cyclic carbonates from epoxides and carbon dioxide. The catalysts are giving better conversion under solvent‐free and additive‐free condition using 10 bar CO2 and 100 °C as optimized pressure and temperature. The detailed kinetic experiments suggesting the first order kinetics, the energy of activation (Ea) is calculated for this catalytic conversion. 相似文献
7.
Nikolaos Pahimanolis Arto Salminen Paavo A. Penttilä Juuso T. Korhonen Leena-Sisko Johansson Janne Ruokolainen Ritva Serimaa Jukka Seppälä 《Cellulose (London, England)》2013,20(3):1459-1468
In this paper, nanofibrillated cellulose/carboxymethyl cellulose (CMC) composite films were prepared using tape casting. The obtained transparent films showed shear induced partial alignment of fibrils along the casting direction, resulting in birefringence in cross polarized light. The carboxyl groups of CMC could be further utilized to create ionic crosslinking by treatment with glycidyl trimethyl ammonium chloride (GTMA). The GTMA treated composite films had improved mechanical properties both in wet and dry state. The chemical composition and morphologies of composites were analyzed with X-ray photoelectron spectroscopy, elemental analysis, scanning electron microscopy and wide-angle X-ray scattering. 相似文献
8.
For very large proteins in the highest magnetic fields, the large chemical shift anisotropy (CSA) of carbonyl carbon deteriorates coherence transfer efficiency in experiments designed for unambiguous sequential backbone assignment. In this communication, coherence throughput of several TROSY experiments is evaluated. Two new experiments, MP-HNCA and HN(CO)CANH, are also introduced as attractive alternatives for sequential assignment purposes of large proteins with correlation time over 50 ns. Their theoretical coherence transfer efficiencies for the interresidual (13)C(alpha) correlations are significantly better than in recently introduced MP-CT-HNCA and sequential HNCA experiments. The improvement with the new experiments is observed already on 60.8 kDa homodimer of protein Cel6A at 800 (1)H MHz. 相似文献
9.
Pekka Salminen Jeffrey E. Teich Jyrki Wallenius 《The Journal of the Operational Research Society》1996,47(8):1046-1053
A decision model is developed for solving the discrete multiple criteria group secretary problem. The model extends the single decision-maker progressive algorithm by Korhonen, Moskowitz and Wallenius to group contexts. As the original progressive algorithm, it relaxes the usual assumption of a fixed set of available decision alternatives and complete knowledge of a decision-maker's preference structure (value function). The decision-makers are requested to settle on a compromise, if possible. The model then proceeds with determining the likelihood of finding possibly/surely better settlements (compromises). Linear value functions, linear prospect theory-type value functions, and quasiconcave value functions are considered. 相似文献
10.
Thin films of polyelectrolyte/J aggregate dye bilayers with high absorption coefficient (6 nm thick with alpha approximately equal to 1.0 x 10(6) cm(-1)) inserted in an optical microcavity enable the cavity quantum electrodynamic strong coupling limit to be reached at room temperature with a coupling strength (Rabi splitting) of 265 +/- 15 meV. By embedding these films in a resonant cavity organic LED structure, we demonstrate the first emissive electrically pumped exciton-polariton device. 相似文献