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Anthonysamy A Balasubramanian S Shanmugaiah V Mathivanan N 《Dalton transactions (Cambridge, England : 2003)》2008,(16):2136-2143
The synthesis and characterization of Ru(II) terpyridine complexes derived from 4'-functionalized 2,2':6',2'-terpyridine ligands by a multi step procedure have been described. The complexes are redox-active, showing both metal-centred (oxidation) and ligand-centred (reduction) processes. The antibacterial and antifungal activity of the synthesized ruthenium(II) complexes [Ru(attpy)2](PF6)2 (attpy = 4'-(4-acryloyloxymethylphenyl)-2,2':6',2'-terpyridine); [Ru(mttpy)2](PF6)2 (mttpy = 4'-(4-methacryloyloxymethylphenyl)-2,2':6',2'- terpyridine); [Ru(mttpy)(MeOPhttpy)](PF6)2 (MeOPhttpy = 4'-(4-methoxyphenyl)-2,2':6',2'-terpyridine); and [Ru(mttpy)(ttpy)](PF6)2 (ttpy = 4'-(4-methylphenyl)-2,2':6',2'-terpyridine) were tested against four human pathogens (Proteus vulgaris, Proteus mirabilis, Pseudomonas aeruginosa and Escherichia coli) and five plant pathogens (Curvularia lunata, Fusarium oxysporum, Fusarium udum, Macrophomina phaseolina and Rhizoctonia solani) by the well diffusion method and MIC values of the complexes are reported. A biological study of the complexes indicated that the complexes [Ru(mttpy)2](PF6)2 and [Ru(mttpy)(MeOPhttpy)](PF6)2 exhibit very good activity against most of the test pathogens and their activity is better than those of some of the commercially available antibiotics like tetracycline and the fungicide carbendazim. 相似文献
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Arockiam Anthonysamy Sengottuvelan Balasubramanian Govindasamy Usha Devadasan Velmurugan 《Transition Metal Chemistry》2008,33(6):681-690
The free Schiff bases H2MABCE, H2MABCP, and H2MABCT and their complexes [Ni(MABCE)], [Ni(MABCP)], [Ni(MABCT)], [Cu(MABCE)], [Cu(MABCP)], and [Cu(MABCT)] have been synthesized and characterized by spectroscopic, cyclic voltammetric, and thermal studies. The geometry around nickel is square planar with N2O2 donor atoms. Cyclic voltammetric studies of the Ni(II) complexes show one-electron quasi-reversible waves corresponding to Ni(II)/Ni(I) and Ni(II)/Ni(III) processes. The Cu(II) complexes exhibit an irreversible well defined one electron transfer reduction peak in the range of ?0.34 to ?1.08 V. The electronic spectra of the complexes suggest a four-coordinate geometry. The crystal structure of the ligand H2MABCT and the complex [Ni(MABCP)] have also been reported. The mean Ni–N and Ni–O bond distances are Ni–N = 1.849(4) and Ni–O = 1.837(4) Å. 相似文献
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Regioselective Pd‐Catalyzed Methoxycarbonylation of Alkenes Using both Paraformaldehyde and Methanol as CO Surrogates 下载免费PDF全文
Dr. Qiang Liu Kedong Yuan Dr. Percia‐Beatrice Arockiam Robert Franke Dr. Henri Doucet Dr. Ralf Jackstell Prof. Dr. Matthias Beller 《Angewandte Chemie (International ed. in English)》2015,54(15):4493-4497
In recent years, considerable effort has focused on the development of novel carbonylative transformations using CO surrogates. Consequently, toxic CO gas can be replaced by more convenient inorganic or organic carbonyl compounds. Herein, the first regioselective methoxycarbonylation of alkenes with paraformaldehyde and methanol as CO substitutes is reported. This new procedure is applicable to a series of alkenes in the presence of a palladium catalyst under relatively mild conditions and is highly atom efficient. 相似文献
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M.A. Jothi Rajan Arockiam Thaddeus T. Mathavan T.S. Vivekanandam S. Umapathy 《Macromolecular Symposia》2005,222(1):287-296
During the past few years, another optical technique has been developed to study those materials, which cannot be studied, by the conventional transmission or reflection techniques. The present technique called Photoacoustic spectroscopy or PAS is different from the conventional techniques chiefly in that the interaction of the incident energy of the photons with the materials under investigation is studied not through subsequent detection and analysis of some of the photons, but rather through a direct measure of the energy absorbed by the material. The aim of this presentation is to highlight the construction of a simple Photoacoustic spectrometer which can easily be constructed even in high school and college laboratories with the available low cost but efficient components and use it for characterization of solid (opaque or transparent), liquid and gas samples under investigations. The essential parts of the photoacoustic spectrometer designed in the laboratory (MADURAI – PA SPECTROMETER), consists of three main components.The total cost comes around 900 Euros. It is an affordable cost for researchers working with paucity of funds and facilities and many constraints especially in the developing countries. In the next few years we aim to study material characterization using MADURAI –PA SPECTROMETER. 相似文献
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Nidhin Paul Selvam Kaladevi Arockiam Jesin Beneto Shanmugam Muthusubramanian Nattamai Bhuvanesh 《Tetrahedron》2012,68(34):6892-6901
Synthesis of a set of isomeric 2,4,6-triarylmorpholines and 2,6-diaryloxathianes from the corresponding 1,5-diols has been described. The method provides an efficient route to six-membered heterocycles from acyclic diols and is found to be better than Mitsunobu procedure in yield and waste management. In a related study, the ring contraction of pyranone to two isomeric cyclopentenone derivatives through Nazarov reaction has been noticed. 相似文献
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Ponmuthu Kottala Vijaya Kumaraguru Duraimurugan Arockiam Jesin Beneto Velu Sadhasivam Sepperumal Murugesan Ayyanar Siva 《Research on Chemical Intermediates》2016,42(12):8345-8358
The present work describes the C-alkylation reactions of fluorene and curcumin catalyzed by a new phosphonium salt, benzene-1,3,5-triyltris(methylene))tris(triphenylphosphonium)bromide, as a multi-site phase-transfer catalyst (MPTC). The catalytic efficiencies were found to be quite effective for di- and tetra-alkylation reactions with very excellent yields under mild base and low concentrations of the catalyst. The synthesized MPTC 3 have privileged catalytic activity compared to commercially available single-site phase-transfer catalysts.
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Dr. Percia Beatrice Arockiam Ulrich Lennert Christina Graf Robin Rothfelder Dr. Daniel J. Scott Tillmann G. Fischer Prof. Dr. Kirsten Zeitler Prof. Dr. Robert Wolf 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(69):16374-16382
Asymmetrically substituted tertiary phosphines and quaternary phosphonium salts are used extensively in applications throughout industry and academia. Despite their significance, classical methods to synthesize such compounds often demand either harsh reaction conditions, prefunctionalization of starting materials, highly sensitive organometallic reagents, or expensive transition-metal catalysts. Mild, practical methods thus remain elusive, despite being of great current interest. Herein, we describe a visible-light-driven method to form these products from secondary and primary phosphines. Using an inexpensive organic photocatalyst and blue-light irradiation, arylphosphines can be both alkylated and arylated using commercially available organohalides. In addition, the same organocatalyst can be used to transform white phosphorus (P4) directly into symmetrical aryl phosphines and phosphonium salts in a single reaction step, which has previously only been possible using precious metal catalysis. 相似文献
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