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1.
Reynaldo C. Castells Eleuterio L. Arancibia Angel M. Nardillo 《Journal of solution chemistry》1993,22(1):85-94
The retention behavior of eight halomethanes and four saturated hydrocarbons was measured in gas chromatographic stationary phases consisting in tri-n-octylamine (TOA), squalane (SQ) and six TOA+SQ mixtures, at 55.0, 58.5, 62.5 and 65.0°C. Equlibrium constants for complex formation were extracted from experimental data by using a lattice model developed by Martire. The results may be interpreted in terms of the formation of weak hydrogen-bonded complexes, with sociation constants of about 0.13 L-mol–1 for haloforms and 0.07 L-mol–1 for dihalomethanes at 60°C. 相似文献
2.
Summary The solubility parameters of cationic surfactants were obtained using the inverse gas chromatographic technique. The surfactants
didodecyl dimethyl ammonium bromide, dioctadecyl dimethyl ammonium bromide and dodecyl pyridinium chloride were used as stationary
phase and retention data of different probe solutes were measured at different temperatures. The results were analysed by
the combination of Flory-Huggins and Hildebrand theories, and the solubility parameters of the surfactants were obtained in
a range of temperatures between 80–120°C. 相似文献
3.
4.
Two different spectrofluorimetric methods for the determination of piroxicam (PX) in serum are presented and discussed. One of them is based on the use of three-way fluorescence data and multivariate calibration performed with parallel factor analysis (PARAFAC) and self-weighted alternating trilinear decomposition (SWATLD). This methodology exploits the so-called second-order advantage of the three-way data, allowing to obtain the concentration of the studied analyte in the presence of any number of uncalibrated (serum) components. The method was developed following two different procedures: internal standard addition and external calibration with standard solutions, which were compared and discussed. The second approach investigated is based on the combination of solid-phase extraction (SPE) and room temperature fluorimetry. Both methods here presented yield satisfactory results. The concentration range in which PX could be determined in serum was 1–10 μg ml−1. The limits of quantification for the experimental solutions using the chemometric approach were 0.09 μg ml−1 for the standard addition mode and 0.12 μg ml−1 using external calibration (both for PARAFAC and SWATLD algorithms). In the solid-surface fluorimetric method, the calibration graph was linear up to 0.22 μg ml−1 and the limit of quantification was 0.02 μg ml−1. 相似文献
5.
First- and second-order multivariate calibration applied to biological samples: determination of anti-inflammatories in serum and urine 总被引:1,自引:0,他引:1
First- and second-order multivariate calibration of fluorescence data have been compared as regards the determination of anti-inflammatories and metabolites in the biological fluids serum and urine. The simultaneous resolution of naproxen-salicylic acid mixtures in serum and naproxen-salicylic acid-salicyluric acid mixtures in urine was accomplished and employed for a discussion of the relative advantages of the applied chemometric tools. The analysis of second-order fluorescence excitation-emission matrices was performed using iteratively reweighted generalized rank annihilation method (IRGRAM), parallel factor analysis (PARAFAC), and self-weighted alternating trilinear decomposition (SWATLD). The results were compared with first-order fluorescence emission data analyzed with partial least-squares regression (PLS). In all cases, the performance of the methods was improved through the formation of inclusion complexes of the analytes with beta-cyclodextrin. The concentration ranges in which the analytes could be determined were as follows: naproxen, 0-250 ng mL(-1) in serum and 0-200 ng mL(-1) in urine; salicylic acid, 0-500 ng mL(-1) in serum and 0-300 ng mL(-1) in urine, and salicyluric acid, 0-300 ng mL(-1) in urine. 相似文献
6.
Portilla Y Chávez I Arancibia V Loeb B Manríquez JM Roig A Molins E 《Inorganic chemistry》2002,41(7):1831-1836
In this work, we report the synthesis and a study on the degree of electronic delocalization in the asymmetric mixed valence complexes [CpFe(C(8)H(6))Fe(C(8)H(7))](+), 3a(+), and [CpCo(C(8)H(6))Fe(C(8)H(7))](+), 3b(+), (Cp = C(5)Me(5), C(8)H(6) = pentalenyde, C(8)H(7) = hydropentalenyde, and = ((3,5(CF(3))(2)C(6)H(3))(4)B(-))). Electrochemical methods, (57)Fe M?ssbauer spectroscopy, electronic spectroscopy, and electron paramagnetic resonance were used for this purpose. Although the anti conformation of the complexes precludes any metal-metal interaction, all the techniques employed show that 3a(+) is a electronic delocalized system, while 3b(+) behaves as two individual metallic centers with localized electron density. 相似文献
7.
5,5-Dimethyl-1,3-cyclohexanedione (dimedone) reacts in acid aqueous solution with selenium(IV) to give a benzoxaselenol which has an absorption maximum at 313 nm with a molar absorptivity of 4.00 x 10(3) l.mole(-1).cm(-1). The compound is extractable into chloroform, to give a solution with an absorption maximum at 300 nm with a molar absorptivity of 3.77 x 10(3) l.mole(-1).cm(-1). The calibration graph is linear up to 30 ppm selenium, with a detection limit of 0.1 ppm in the final solutions. Of the various other ions tested, only iron(III) interferes at all concentrations but the addition of 1000 ppm fluoride will mask 50 ppm Fe(3+). The method has good reproducibility, with a relative standard deviation of 1.0% for pure solutions. The method has been applied to the analysis of fire-refined copper. 相似文献
8.
Yolanda Prieto Marcelo Muoz Vernica Arancibia Mauricio Valderrama Fernando J. Lahoz M. Luisa Martín 《Polyhedron》2007,26(18):5527-5532
The reaction of the dimer complex [{Ru(CO)3Cl2}2] with the ligands 4,6-dichloroquinoline-5,8-dione and 6-methoxybenzo[g]quinoline-5,10-dione in ethanol solution led to the neutral mononuclear complexes of general formula [Ru(CO)2Cl2(κ2-quinolinedione-N,O)]. The complexes were characterized by elemental analysis, IR and RMN spectroscopy, and the molecular structure of [Ru(CO)2Cl2(6-methoxybenzo[g]quinoline-5,10-dione)] was determined by single-crystal X-ray diffraction. The redox chemistry of ligands and complexes was investigated by cyclic voltammetry, and their potential antitumor activity was also evaluated. 相似文献
9.
10.
Arancibia V Segura R Leiva JC Contreras R Valderrama M 《Journal of chromatographic science》2000,38(1):21-26
The supercritical fluid extraction of Pb(DDC)2 and MoO2(acac)2 complexes is performed. The previously formed complexes are used in order to simplify the extraction process. In the extraction cell, 9.0 mg of Pb(DDC)2 or 30.0 mg of MoO2(acac)2 is added. With these two complexes, a study of static and dynamic extraction as a function of pressure (1000-2500 psi), temperature (40-160 degrees C), and presence of modifier (methanol) is performed. Under the best conditions, 5.6 mg of Pb(DDC)2 (2.3 mg of Pb2+) is recovered. The parameters are 2500 psi of pressure, 160 degrees C of temperature, 0.5 mL methanol (placed in a 10-mL extraction cell), 60.0 min of static extraction, and 2.0 min of dynamic extraction. It is necessary to add 3.0 mL of methanol to enhance efficiency on the MoO2(acac)2 complex recovery. Quantitative extractions of MoO2(acac)2 (9.0 mg of MoVI) are obtained when the experiments are carried out under 1000-2500 psi of pressure, 140 degrees C, and times no longer than 10.0 min. Then, the study is carried out forming the in situ complexes. For this purpose, metallic ion and ligand are added. Under these conditions, the Pb2+ recovery decreases from 2.3 to 1.9 mg, and the MoVI recovery decreases from 9.0 to 1.0 mg. When 1.9 mg of Pb2+ and 1.0 mg of MoVI or less is placed in the extraction cell, the recoveries are always 100%. The Pb2+ extracts are directly accomplished using gas chromatography-flame ionization detection (GC-FID), and the MoVI extracts are analyzed using GC-FID and catalytic adsorption voltammetry. The quantitation of pure extracts is carried out by constructing calibration curves with complex solutions and sample solutions using the standard addition method. This method is applied by determination of Pb2+ in sodium alginate extracted from algae and blood, urine, and human milk from patients with diagnosed plumbunemy. MoVI is determined in irrigation water and pasture of animal intake. 相似文献