全文获取类型
收费全文 | 72篇 |
免费 | 2篇 |
专业分类
化学 | 17篇 |
晶体学 | 4篇 |
力学 | 24篇 |
数学 | 11篇 |
物理学 | 18篇 |
出版年
2022年 | 1篇 |
2020年 | 1篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2016年 | 1篇 |
2015年 | 2篇 |
2014年 | 2篇 |
2012年 | 1篇 |
2011年 | 1篇 |
2009年 | 3篇 |
2008年 | 7篇 |
2007年 | 3篇 |
2006年 | 4篇 |
2005年 | 4篇 |
2004年 | 3篇 |
2003年 | 2篇 |
2002年 | 5篇 |
2001年 | 2篇 |
2000年 | 3篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1996年 | 2篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1972年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有74条查询结果,搜索用时 468 毫秒
1.
The concentration dependence of the broad-band luminescence arising in GeO2-doped silicate fiber-optic waveguides is measured and interpreted. The spectra obtained show that electronic excitations
of a new type that are absent in pure silicate glass — charge transfer excitons — arise in the doped system. Under the action
of light an electron can be transferred both from a Ge center into the host and between Ge centers. Self-organization of these
excitations in the field of a light wave (orientational ordering of their dipole moments) results in the appearance of a macroscopic
electric field that destroys the initial centrosymmetry of the system and allows second-harmonic generation.
Pis’ma Zh. éksp. Teor. Fiz. 68, No. 10, 737–740 (25 November 1998) 相似文献
2.
Ellis MJ Antonyuk SV Strange RW Sawers G Eady RR Hasnain SS 《Inorganic chemistry》2004,43(24):7591-7593
Copper nitrite reductases contain both an electron-transfer type 1 Cu site and a catalytic type 2 Cu site. We have mutated one of the type 2 copper ligating histidines to observe the effect on catalytic turnover. This mutation has created a unique site where Cu is ligated by 2 His Nepsilon2 atoms alone. 相似文献
3.
Ryashentseva M. A. Egorova E. V. Trusov A. I. Antonyuk S. N. 《Russian Chemical Bulletin》2002,51(9):1698-1701
The activity and selectivity of mono- and bimetallic catalysts containing copper and rhenium on sibunite were studied in the decomposition of methanol to methyl formate (MF), water, H2, CO, and CO2at 200—400 °C. Methane is also formed on rhenium-containing catalysts at 300—400 °C. The dehydrogenating activity and selectivity to form MF are higher on the copper-sibunite catalysts than on the rhenium-sibunite samples. The introduction of 0.25% Re into the 4% copper-containing catalyst enhances its total activity and stability. 相似文献
4.
Spectroscopic characterization of mineral crystals produced by the bacterium Azospirillum brasilense
Kamnev AA Antonyuk LP Chernyshev AV Ignatov VV De Vargas MC 《Analytical and bioanalytical chemistry》1996,355(5-6):739-741
The results of spectroscopic structural and trace elemental analyses of mineral crystals produced by the soil nitrogen-fixing bacterium Azospirillum brasilense cultivated in a synthetic medium are presented and discussed. The mineral formed is shown to have a structure close to struvite (MgNH(4)PO(4) x 6H(2)O; ASTM file No. 15-762) with some differences which may be attributed to the presence of isomorphic admixtures of other cations (struvite is known to have a variety of forms). AAS/AES and ion chromatography analyses for a number of biologically important microelements and their role in the formation of the crystal structure, as well as some questions related to biomineralization are also discussed. 相似文献
5.
Babushkina T. A. Klimova T. P. Sviridov B. D. Antonyuk A. V. 《Russian Journal of Coordination Chemistry》2002,28(1):71-74
d,l-Hexamethylpropyleneamino oxime (HMPAO) was synthesized and isolated from a mixture of d,l - and meso-isomers. The structure of the conformers was studied using 1H NMR spectroscopy over a broad range of pH. A method for estimating the amount of meso-form present in the mixture of isomers was proposed. It was shown that specific features of the IR spectra depend on the structure of the isomers and on the difference between the packing of molecules in the crystal lattice. 相似文献
6.
International Applied Mechanics - The geometry and kinematics of a dynamic system with several degrees of freedom and controllable friction clutches are considered. The necessary kinematic... 相似文献
7.
S. V. Antonyuk A. I. Grebenko V. M. Levdikov D. V. Urusova V. R. Melik-Adamyan V. S. Lamzin K. S. Wilson 《Crystallography Reports》2001,46(4):620-625
The three-dimensional structures of two enzyme-substrate complexes of SAICAR synthase from the yeast Saccharomyces cerevisiae with adenosinetriphosphate (ATP) prepared under different conditions were studied by X-ray diffraction analysis and then refined. An enzyme molecule was shown to contain two binding sites of ATP. One of these sites is located in the central cavity of the enzyme molecule and apparently binds the ATP molecule directly involved in the enzymatic reaction. In the complexes, the phosphate groups of ATP occupying this site adopt different conformations depending on the Mg2+ concentration. The functional role of the second binding site located at a distance of approximately 15 Å from the first site away from the central enzyme cavity has not been understood as yet. It might be that the second site perform the regulatory role in enzyme functioning. 相似文献
8.
It is shown that ArF laser beam may act as effective driller producing in fuzed quartz micron radius channel up to 1 cm long while diameter of light spot is few millimeters. Drill formation is accompanied by compaction effect in the drill walls therefore material is not thrown out the channel. 相似文献
9.
The influence of the thickness of a covering liquid layer and its viscosity as well as the impact velocity on energy loss during the normal impact on a flat steel wall of spherical granules with a liquid layer was studied. Free-fall experiments were performed to obtain the restitution coefficient of elastic–plastic Al2O3 granules by impact on the liquid layer, using aqueous solutions of hydroxypropyl methylcellulose with different concentrations for variation of viscosity (1–300 mPa s). In the presence of a... 相似文献
10.
We show that a special choice of the Cameron–Martin direction in the characterization of the Wiener measure via the formula of integration by parts leads to a set of natural representations for derivatives of nonlinear diffusion semigroups. In particular, we obtain a final solution of the non-Lipschitz singularities in the Malliavin calculus. 相似文献