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排序方式: 共有133条查询结果,搜索用时 31 毫秒
1.
Optics and Spectroscopy - Scattering of light by disordered structures is normally detrimental to their applicability in many optoelectronic devices. However, some micro and nanostructures are... 相似文献
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Cerium(IV) ammonium nitrate in substoichiometric amounts, promotes the intramolecular cyclization of epoxypropyl cinnamyl ethers to the corresponding 3,4,5-trisubstituted tetrahydropyran derivatives in moderate to good yields. 相似文献
4.
Nataša Pejić Slobodan Anić Vesna Kuntić Vladana Vukojević Ljiljana Kolar-Anić 《Mikrochimica acta》2003,143(4):261-267
A kinetic method is described for the microquantitative (microconcentration/microvolume) determination of rutin based on potentiometric monitoring of the concentration perturbations of the Bray-Liebhafsky (BL) oscillatory reaction being in a non-equilibrium stationary state close to a bifurcation point. The experiments are carried out in an open reactor. The response of the matrix system to perturbations by different concentrations of rutin ethanolic solutions is followed by a Pt-electrode. In the concentration range between 7.8×10–8moldm–3 and 9.1×10–6mol dm–3, we found a linear dependence of the maximal potential shift, Em, on the logarithm of the rutin concentrations. The unknown concentrations can be determined from the calibration curve up to an accuracy of ±5%. The detection limit is 3.6×10–8mol dm–3. The amount of required sample can be as small as 10µL. 相似文献
5.
Lj. Kolar-Ani? Dj. Misljenovi? S. Ani? G. Nicolis 《Reaction Kinetics and Catalysis Letters》1995,54(1):35-41
The reduction of iodate ion by hydrogen peroxide, originally postulated by Liebhafsky, is considered as a possible step in the kinetic model proposed by Kolar-Ani and G. Schmitz for the overall Bray-Liebhafsky oscillatory process. 相似文献
6.
The use of open-access mass spectrometry to monitor synthetic chemistry reactions, and also the integrity and purity of new chemical entities, has been a part of the medicinal chemist's tool-box for more than 5 years. Originally in our group at Wyeth Research there were two open-access methods available to the chemists, flow injection analysis (FIA) and liquid chromatography/mass spectrometry (LC/MS). The FIA method was approximately 3 min long, while the LC/MS method was approximately 20 min long (including an 8 min gradient). Within the first 2 years, the total number of open-access analyses increased by approximately 125%. It is interesting, however, that the number of LC/MS analyses increased by more than 285%. This is attributed to the fact that the chemists began using the LC/MS data to monitor reactions and also to check final product integrity and purity. In addition, the number of chemists performing parallel synthesis reactions has increased; thus, individual chemists can produce sample sets of up to 100 vials. This paper describes the implementation of new methodology, which accommodates the need for much faster run times and also the ability to acquire alternating positive and negative ion spectra within the same run. In addition, the instrument has been configured to e-mail the resulting processed data report to the submitting chemist. Several methods have been developed, including structure elucidation using in-source collision-induced dissociation (CID) and night-time analysis. The LC/MS methods for this system are described herein and are applicable to both industrial and academic synthetic chemistry optimization efforts. 相似文献
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H.V. Baghdasaryan T.M. Knyazyan T.H. Baghdasaryan B. Witzigmann F. Roemer 《Opto-Electronics Review》2010,18(4):438-445
Electrodynamical model of a classical distributed Bragg reflector (DBR) consisting of alternating quarter-wave layers of high
and low permittivity is considered at the plane wave normal incidence. Reflective characteristics of DBR possessing absorption
loss in constituting layers are analysed via correct wavelength-scale boundary problem solution by the method of single expression
(MSE). Analysis of optical field and power flow density distributions within the lossy DBR structures explained the peculiarities
of their reflective characteristics. Optimal configurations of lossless and lossy DBRs are revealed. Specific DBR structures
possessing full transparency at definite number of layers are also analysed. 相似文献
9.
D. A. Baghdasaryan D. B. Hayrapetyan E. M. Kazaryan 《Journal of Contemporary Physics (Armenian Academy of Sciences)》2016,51(2):157-161
In a uniformly charged prolate spheroidal Thomson hydrogen atom the electron states have been investigated. It has been shown from the mathematical point of view that the problem is equivalent to a spheroidal hydrogen atom in a parabolic potential with the cylindrical symmetry. In the framework of adiabatic approximation, the energy of ground state has been calculated. Comparison with the case of uncharged spheroidal quantum dot has been made, and the analytical form of wave function of electron has been also obtained. 相似文献
10.
Noble V. Thomas Vidya Sathi Ani Deepthi Sruthi Sudheendran Leena Sidharth Chopra 《Journal of heterocyclic chemistry》2021,58(1):48-55
A simple and efficient method, proceeding through a new mechanistic pathway, for the synthesis of spiro[indoline-3,4-thiopyrano[2.3-b]indole derivatives have been developed by exploiting the reaction of thieno[2,3-b]indole-2,3-dione with N-substituted isatilidenes. The compounds synthesized have been screened for antibacterial activity. The generality of the reaction and mechanistic rationale are presented. 相似文献