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Tommaso Carofiglio Euro Solari Carlo Floriani Angiola Chiesi-Villa Corrado Rizzoli 《Polyhedron》1996,15(24):4435-4440
The UV-stabilizer 2-(2′-hydroxy-5′-methylphenyl)benzotriazole (Tinuvin P, LH) has been used as a monoanionic bidentate ligand for complexing oxocations. Displacement of acacH from [VO(acac)2] and [MoO2(acac)2] gave [*VO(acac)2*(μ-L)] (2) and [cis-O2Mo(acac)L] (3) respectively, as crystalline compounds. Their structure has been determined by an X-ray analysis showing the structural changes occurring upon coordination. The UV spectrum of Tinuvin P is significantly affected by complexation. 相似文献
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Luca Giannini Silvia Dovesi Euro Solari Carlo Floriani Angiola Chiesi-Villa Corrado Rizzoli 《Angewandte Chemie (International ed. in English)》1999,38(6):807-810
The chemically reversible reduction of [(Me)2W(calix)] to the diamagnetic [(Me)2W(calix)Na2] [Eq. (1)], without major changes in the connectivity of the molecule, illustrates the flexibility of the calixarene ligand and stresses its potential as a molecular functional model of heterogeneous oxo surfaces. 相似文献
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