全文获取类型
收费全文 | 2169篇 |
免费 | 117篇 |
国内免费 | 6篇 |
专业分类
化学 | 1696篇 |
晶体学 | 11篇 |
力学 | 22篇 |
数学 | 163篇 |
物理学 | 400篇 |
出版年
2023年 | 27篇 |
2022年 | 26篇 |
2021年 | 105篇 |
2020年 | 80篇 |
2019年 | 59篇 |
2018年 | 37篇 |
2017年 | 39篇 |
2016年 | 82篇 |
2015年 | 71篇 |
2014年 | 92篇 |
2013年 | 119篇 |
2012年 | 189篇 |
2011年 | 138篇 |
2010年 | 85篇 |
2009年 | 69篇 |
2008年 | 113篇 |
2007年 | 116篇 |
2006年 | 92篇 |
2005年 | 89篇 |
2004年 | 85篇 |
2003年 | 62篇 |
2002年 | 62篇 |
2001年 | 25篇 |
2000年 | 12篇 |
1999年 | 19篇 |
1998年 | 12篇 |
1997年 | 13篇 |
1996年 | 26篇 |
1995年 | 11篇 |
1994年 | 17篇 |
1993年 | 15篇 |
1992年 | 18篇 |
1991年 | 16篇 |
1990年 | 17篇 |
1989年 | 19篇 |
1988年 | 23篇 |
1987年 | 22篇 |
1986年 | 9篇 |
1985年 | 16篇 |
1984年 | 15篇 |
1983年 | 9篇 |
1982年 | 10篇 |
1981年 | 7篇 |
1980年 | 8篇 |
1979年 | 7篇 |
1978年 | 13篇 |
1977年 | 10篇 |
1975年 | 6篇 |
1967年 | 5篇 |
1918年 | 5篇 |
排序方式: 共有2292条查询结果,搜索用时 281 毫秒
1.
Vereshchagin Anatoly N. Karpenko Kirill A. Elinson Michail N. Minaeva Alexandra P. Goloveshkin Alexander S. Hansford Karl A. Egorov Mikhail P. 《Molecular diversity》2020,24(4):1327-1342
Molecular Diversity - A novel five-component diastereoselective synthesis of polysubstituted 2-piperidinones is reported. The Knoevenagel condensation–Michael addition–Mannich cascade... 相似文献
2.
Susana Estopiñá-Durán Liam J. Donnelly Euan B. Mclean Bryony M. Hockin Prof. Alexandra M. Z. Slawin Dr. James E. Taylor 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(15):3950-3956
A combination of pentafluorophenylboronic acid and oxalic acid catalyses the dehydrative substitution of benzylic alcohols with a second alcohol to form new C−O bonds. This method has been applied to the intermolecular substitution of benzylic alcohols to form symmetrical ethers, intramolecular cyclisations of diols to form aryl-substituted tetrahydrofuran and tetrahydropyran derivatives, and intermolecular crossed-etherification reactions between two different alcohols. Mechanistic control experiments have identified a potential catalytic intermediate formed between the aryl boronic acid and oxalic acid. 相似文献
3.
Alexandra Shlapentokh 《Monatshefte für Mathematik》2002,110(4):59-67
Let F be a function field of characteristic over a finite field . Then for any finite set of F-primes S and any , there exists a set of F-primes W of density greater than such that and has a Diophantine definition over . (Here and is defined analogously.) 相似文献
4.
Stability of a Model of Relativistic Quantum Electrodynamics 总被引:1,自引:0,他引:1
The relativistic “no pair” model of quantum electrodynamics uses the Dirac operator, D(A) for the electron dynamics together with the usual self-energy of the quantized ultraviolet cutoff electromagnetic field
A– in the Coulomb gauge. There are no positrons because the electron wave functions are constrained to lie in the positive
spectral subspace of some Dirac operator, D, but the model is defined for any number, N, of electrons, and hence describes a true many-body system. In addition to the electrons there are a number, K, of fixed nuclei with charges ≤Z. If the fields are not quantized but are classical, it was shown earlier that such a model is always unstable (the ground
state energy E=−∞) if one uses the customary D(0) to define the electron space, but is stable (E > − const.(N+K)) if one uses D(A) itself (provided the fine structure constant α and Z are not too large). This result is extended to quantized fields here, and stability is proved for α= 1/137 and Z≤ 42. This formulation of QED is somewhat unusual because it means that the electron Hilbert space is inextricably linked
to the photon Fock space. But such a linkage appears to better describe the real world of photons and electrons.
Received: 8 September 2001 / Accepted: 18 March 2002 相似文献
5.
James K. Freericks Elliott H. Lieb Daniel Ueltschi 《Communications in Mathematical Physics》2002,227(2):243-279
The Falicov–Kimball model is a simple quantum lattice model that describes light and heavy electrons interacting with an
on-site repulsion; alternatively, it is a model of itinerant electrons and fixed nuclei. It can be seen as a simplification
of the Hubbard model; by neglecting the kinetic (hopping) energy of the spin up particles, one gets the Falicov–Kimball model.
We show that away from half-filling, i.e. if the sum of the densities of both kinds of particles differs from 1, the particles
segregate at zero temperature and for large enough repulsion. In the language of the Hubbard model, this means creating two
regions with a positive and a negative magnetization.
Our key mathematical results are lower and upper bounds for the sum of the lowest eigenvalues of the discrete Laplace operator
in an arbitrary domain, with Dirichlet boundary conditions. The lower bound consists of a bulk term, independent of the shape
of the domain, and of a term proportional to the boundary. Therefore, one lowers the kinetic energy of the itinerant particles
by choosing a domain with a small boundary. For the Falicov- Kimball model, this corresponds to having a single “compact”
domain that has no heavy particles.
Received: 21 June 2001 / Accepted: 4 January 2002 相似文献
6.
Alexander G. Ramm Alexandra B. Smirnova Angelo Favini 《Annali di Matematica Pura ed Applicata》2003,182(1):37-52
A nonlinear operator equation F(x)=0, F:H→H, in a Hilbert space is considered. Continuous Newton’s-type procedures based on a construction of a dynamical system with
the trajectory starting at some initial point x
0 and becoming asymptotically close to a solution of F(x)=0 as t→+∞ are discussed. Well-posed and ill-posed problems are investigated.
Received: June 29, 2001; in final form: February 26, 2002?Published online: February 20, 2003
This paper was finished when AGR was visiting Institute for Theoretical Physics, University of Giessen. The author thanks
DAAD for support 相似文献
7.
D. Kast A. Jungclaus K.P. Lieb M. Górska G. de Angelis P.G. Bizzeti A. Dewald C. Fahlander H. Grawe R. Peusquens M. De Poli H. Tiesler 《The European Physical Journal A - Hadrons and Nuclei》1998,3(2):115-128
In the neutron deficient isotopes 104,105In lifetimes of high spin states in the range from 0.5 ps to 600 ps have been measured in a coincidence recoil distance Doppler
shift (RDDS) experiment. By combining the Doppler shift attenuation (DSA) and RDDS methods at few μm flight distances, the
problem of delayed feeding has been avoided and very short lifetimes in the range 0.5–0.8 ps have been determined. Shell model
calculations with strong restrictions for the neutron orbitals reveal good agreement with experimental level energies and
still fair agreement for most measured B(M1) and B(E2) values.
Received: 30 June 1998 相似文献
8.
Alexandra Shlapentokh 《Compositio Mathematica》2002,132(1):99-120
Let F be a function field of characteristic p > 2, finitely generated over a field C algebraic over a finite field C
p
and such that it has an extension of degree p. Then Hilbert's Tenth Problem is not decidable over F. 相似文献
9.
Thermal properties of benzoic acids carrying one or two semiperfluorinated alkoxy tails on the aromatic core have been investigated in binary mixtures with the non-liquid crystalline bidirectional trans-1,2-bis(4-pyridyl)ethylene. The hydrogen bonded complexes built from the complementary molecular species show a significantly enhanced mesophase stability compared with the fluorinated acids in their pure states. The mesophase morphologies of the complexes are governed mainly by the number of the partially fluorinated chains grafted to the acid component. Mixed systems comprising the one-chain acids exhibit a smectic C phase followed by a smectic A phase at more elevated temperatures. Incorporation of a second semiperfluorinated chain into the acid leads to the formation of columnar mesophases. These columnar phases of the H-bonded complexes should represent ribbon phases resulting from the collapse of the smectic layers. 相似文献
10.