全文获取类型
收费全文 | 1294篇 |
免费 | 26篇 |
国内免费 | 4篇 |
专业分类
化学 | 851篇 |
晶体学 | 7篇 |
力学 | 12篇 |
数学 | 131篇 |
物理学 | 323篇 |
出版年
2023年 | 9篇 |
2022年 | 6篇 |
2021年 | 102篇 |
2020年 | 40篇 |
2019年 | 38篇 |
2018年 | 55篇 |
2017年 | 59篇 |
2016年 | 64篇 |
2015年 | 42篇 |
2014年 | 64篇 |
2013年 | 104篇 |
2012年 | 80篇 |
2011年 | 104篇 |
2010年 | 69篇 |
2009年 | 76篇 |
2008年 | 76篇 |
2007年 | 69篇 |
2006年 | 70篇 |
2005年 | 38篇 |
2004年 | 28篇 |
2003年 | 15篇 |
2002年 | 18篇 |
2001年 | 10篇 |
2000年 | 17篇 |
1999年 | 13篇 |
1998年 | 8篇 |
1997年 | 11篇 |
1996年 | 6篇 |
1995年 | 2篇 |
1993年 | 1篇 |
1991年 | 5篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1987年 | 2篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1975年 | 1篇 |
1973年 | 1篇 |
1969年 | 1篇 |
1966年 | 1篇 |
1963年 | 1篇 |
排序方式: 共有1324条查询结果,搜索用时 543 毫秒
1.
Rutkowski Paweł Klimczyk Piotr Jaworska Lucyna Stobierski Ludosław Dubiel Aleksandra 《Journal of Thermal Analysis and Calorimetry》2015,122(1):105-114
Journal of Thermal Analysis and Calorimetry - The work concerns the alumina–graphene materials sintered by two different pressure methods. The different particle sizes of graphene were used.... 相似文献
2.
S. N. Solov’ev K. A. Minasyan A. A. Korunov 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2006,80(4):663-664
The enthalpies of reactions of La2CoO4(cr) and CoCl2(cr) with hydrochloric acid were measured with an isothermal-jacket calorimeter. The results obtained and the available literature data were used to calculate the standard enthalpy of formation of La2CoO4(cr) at 298.15 K, Δf H o = ?2179 ± 7 kJ/mol. 相似文献
3.
Ching Sum Hui Lillian Sze Man Lam Chun Yin Wai Kin Chan Aleksandra B. Djurii 《Journal of polymer science. Part A, Polymer chemistry》2003,41(11):1708-1715
Polyurethanes incorporated with rhenium diimine complexes were synthesized. The polymers exhibited interesting morphologies and solution properties. Results from gel permeation chromatography suggested the formation of polymer aggregates in solutions. The polymers could act as probes for metal ions. The addition of metal ions to polymer solutions led to significant changes in the electronic absorption properties of the polymer solutions. This was attributed to the interactions between the polyether moieties and metal ions. The metal complexes could also act as efficient photosensitizers. After doping with charge‐transport viologens, the photoconductivity of the polymers was greatly enhanced. The experimental quantum efficiency was simulated with Onsager's theory. The thermalization distances and the primary yields were typically 12–14 Å and 10?3, respectively. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1708–1715, 2003 相似文献
4.
A. P. Solov’ev M. I. Perchenko Yu. P. Sinichkin O. V. Zyuryukina 《Technical Physics》2002,47(8):996-1001
An expression for a signal at the ultrasonic frequency from a photodetector arising when diffraction waves at the cathode
mix is obtained for the case when the optical and acoustic beams are space-limited and Bragg angles are small. The alternating
current generated when the scattering medium is crossed by a focused 3-MHz ultrasonic beam and illuminated by a cw He-Ne laser
is measured. Satisfactory agreement between experimental results and those calculated from the formulas obtained indicates
that our model treating acoustooptical interaction in the medium in terms of Raman-Nath diffraction is valid. Conditions for
measuring the alternating current (which is a parameter of acoustooptical imaging) that are optimal from the viewpoint of
maximizing the signal and signal-to-noise ratio are predicted theoretically and corroborated experimentally. 相似文献
5.
6.
A. A. Solov’ev M. A. Pashina O. E. Lebedeva 《Russian Journal of Applied Chemistry》2007,80(2):275-278
The influence of inorganic salts on the kinetics of oxidation of 2,4-and 2,6-dinitrophenols by Fenton’s reagent, hydrogen peroxide, in the presence of iron(II) ions was studied. 相似文献
7.
S. M. Arabei D. V. Novik T. A. Pavich K. N. Solov’ev 《Journal of Applied Spectroscopy》2006,73(4):511-521
We have studied the fluorescence and fluorescence excitation spectra at 300 K, 77 K, and 4.2 K for silicate gel matrices colored
with meso-tetrapropylporphin by impregnation of the matrix with a solution of the pigment. Comparison of the data obtained
with the absorption spectra in acidified solutions and analysis of the low-temperature fine-structure vibronic spectra, and
also taking into account data obtained earlier for octaethylporphin in a xerogel showed formation of two cationic forms of
meso-tetrapropylporphin in the gel matrix: the short-wavelength form has a dicationic structure, while the long-wavelength form
has a monocationic structure. We have traced out the correlations of the vibrational structure in the spectra of the dicationic
form with data for the porphin dication, and we have drawn a number of conclusions concerning the normal vibrational modes
that are active in the vibronic fluorescence and absorption spectra of the studied cationic forms. Using the AM1 semiempirical
quantum chemical method, we optimized the geometry of the mesotetrapropylporphin dication: the most stable of the possible
conformers is the dication structure with saddleshaped macrocycle nonplanarity.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 4, pp. 453–461, July–August, 2006. 相似文献
8.
The 2-meter liquid-hydrogen bubble chamber is exposed to a separated beam of α particles from the ITEP synchrotron. The momentum of the incident 4He nuclei, averaged over the fiducial volume of the chamber, is 5 GeV/c (the kinetic energy of initial protons in the nucleus rest frame is T
p
=620 MeV). The spectral functions of decays α→tp and α→τn) are extracted in the 4π geometry (the latter is extracted for the first time) from the exclusive reactions αp→tpp and αp→τpn in the spectator momentum region 0<q<0.3 GeV/c. The pole dominance criteria are carefully checked. Extrapolation of the nuclear vertex function to the pole gives a lower
bound on the nuclear vertex constant. Our experimental data are compared with the results of other studies and with theoretical
calculations.
Pis’ma Zh. éksp. Teor. Fiz. 66, No. 2, 69–74 (25 July 1997)
Published in English in the original Russian journal. Edited by Steve Torstveit. 相似文献
9.
10.
Sergey V. Avgustinovich Olof Heden Faina I. Solov’eva 《Designs, Codes and Cryptography》2006,39(3):317-322
The main result is that to any even integer q in the interval 0 ≤ q ≤ 2n+1-2log(n+1), there are two perfect codes C1 and C2 of length n = 2m − 1, m ≥ 4, such that |C1 ∩ C2| = q. 相似文献