A weight-function approach for determining watershed initial conditions for combustion waves

In many generic combustion models, one finds that a combustionwave will develop with a specific wave speed. However, thereare possible initial temperature profiles which do not evolveinto such waves, but rather die out to the ambient temperature.There can exist, in some models, a clear distinction betweenthose initial conditions that do evolve into combustion wavesand those that do not; this is sometimes referred to as thewatershed initial condition. When fuel consumption is consideredto be negligible, analytical methods can be used to obtain theexact watershed. In this paper, we consider the problem of determiningpseudo-watersheds and ascertaining the relationship betweenthese pseudo-watersheds and the exact watersheds. In the processa novel weight-function approach for infinite spatial domainsis developed.     

Meson production in p + d reactions

Total and differential cross sections for the reactions p + d → ³He + m ⁰ with m=π, η and p + d → ³H+π⁺ were measured with the GEM detector at COSY for beam momenta between threshold and the maximum of the corresponding baryon resonance. For both reactions a strong forward-backward asymmetry was found. The data were compared with model calculations. The aspect of isospin symmetry breaking is studied. Representing the GEM Collaboration     

The onset of coulomb explosions in polyatomic molecules

With the development of high intensity femtosecond lasers, the ionisation and dissociation dynamics of molecules has become an area of considerable interest. Using the technique of femtosecond laser mass spectrometry (FLMS), the molecules carbon disulphide, pyrimidine, toluene, cyclohexanone and benzaldehyde are studied with pulse widths of 50 fs in the near infrared (IR) wavelength region (790 nm). Results are presented and contrasted for laser beam intensities around 10(15) and 10(16) W cm(-2). For the lower intensities, the mass spectra yield dominant singly charged parent ions. Additionally, the appearance of doubly charged parent ions is evident for carbon disulphide, toluene and benzaldehyde with envelopes of doubly charged satellite species existing in these local regions. Carbon disulphide also reveals a small triply charged component. Such atomic-like features are thought to be a strong fingerprint of FLMS at these intensities. However, upon increasing the laser intensity to approximately 10(16) W cm(-2), parent ion dominance decreases and the appearance of multiply charged atomic species occurs, particularly carbon. This phenomenon has been attributed to Coulomb explosions in which the fast absorption of many photons may produce transient highly ionised parent species which can subsequently blow apart. Copyright 1999 John Wiley & Sons, Ltd.     

Hydrogenic systems,frequency standards and fundamental constants

Hydrogenic (two-body) systems are the only atomic systems for which uncertainties in calculations of the energy levels approach the current state of the art in frequency measurement. This article discusses progress in the theory and measurement of transition frequencies in hydrogenic systems. These studies have relevance to the determination of fundamental constants and the testing of physical theories, especially quantum electrodynamics. A set of high accuracy calculable frequency standards could also be realized by using hydrogenic systems.     

Synthesis and in vitro behavior of iron-crosslinked N-methyl and N-benzyl hydroxamated derivatives of alginic acid as controlled release carriers

N-methyl and N-benzyl hydroxylamines were synthetically conjugated to alginic acid to produce hydroxamated derivatives with different degrees of substitution. The new polymeric materials were used to form coordinate complexes with iron(III). The hydroxamated derivatives as well as their iron complexes were characterized using infrared spectroscopy and differential scanning calorimetry.Phenobarbitone-loaded and blank beads were prepared utilizing the new iron-crosslinked hydroxamated polymers and evaluated with respect to their ability to control drug release, as well as their iron leaching properties.The iron-crosslinked polymeric composites proved capable of encapsulating the model drug and sustaining its release in the dissolution media, the release profiles were sensitive to the type and degree of substitution.