全文获取类型
收费全文 | 133篇 |
免费 | 1篇 |
专业分类
化学 | 117篇 |
物理学 | 17篇 |
出版年
2023年 | 2篇 |
2022年 | 1篇 |
2021年 | 1篇 |
2020年 | 2篇 |
2019年 | 1篇 |
2017年 | 1篇 |
2015年 | 3篇 |
2014年 | 5篇 |
2013年 | 5篇 |
2012年 | 9篇 |
2011年 | 9篇 |
2010年 | 8篇 |
2009年 | 2篇 |
2008年 | 10篇 |
2007年 | 7篇 |
2006年 | 10篇 |
2005年 | 10篇 |
2004年 | 14篇 |
2003年 | 3篇 |
2002年 | 3篇 |
2001年 | 3篇 |
2000年 | 3篇 |
1997年 | 1篇 |
1994年 | 1篇 |
1993年 | 4篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1977年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有134条查询结果,搜索用时 312 毫秒
1.
D3h‐Symmetric Porphyrin‐Based Rigid Macrocyclic Ligands for Multicofacial Multinuclear Complexes in a One‐Nanometer‐Sized Cavity 下载免费PDF全文
Yohei Ohkoda Akane Asaishi Tomoya Namiki Tomoaki Hashimoto Midori Yamada Koichiro Shirai Yuta Katagami Dr. Tomoaki Sugaya Prof. Makoto Tadokoro Prof. Akiharu Satake 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(33):11745-11756
The one‐step synthesis of D3h‐symmetric cyclic porphyrin trimers 1 composed of three 2,2′‐[4,4′‐bis(methoxycarbonyl)]bipyridyl moieties and three porphyrinatozinc moieties was achieved from a nickel‐mediated reductive coupling of meso‐5,15‐bis(6‐chloro‐4‐methoxycarbonylpyrid‐2‐yl)porphyrinatozinc. Although cyclic trimers 1 were obtained as a mixture that included other cyclic and acyclic porphyrin oligomers, an extremely specific separation was observed only for cyclic trimers 1 when using columns of silica gel modified with pyrenylethyl, cyanopropyl, and other groups. Structural analysis of cyclic trimers 1 was carried out by means of NMR spectroscopy and X‐ray crystallography. Treatment of an η3‐allylpalladium complex with a cyclic trimer gave a tris(palladium) complex containing three η3‐allylpalladium groups inside the space, which indicated that the bipyridyl moieties inside the ring could work as bidentate metalloligands. 相似文献
2.
Spectral data during a chelatometric titration were utilized for determining an equivalence point of the titration. Three-dimensional titration data were analyzed by fitting to a theoretical equation that was derived from equilibrium equations among a metal ion, an indicator and EDTA. The equation with optimized parameters successfully explained the three-dimensional titration data. This method was applied to EDTA titration systems of zinc, cadmium and lead with xylenol orange (XO) as an indicator. These systems were analyzed while taking the formation of 1:1 and 2:1 metal-indicator complexes into account. By this method, an accurate equivalence point was determined as well as stability constants and molar absorption spectra of metal-indicator complexes in each titration system. Moreover, the comparability among the concentrations of the metal standard solutions prepared from pure metals (Zn, Pb, and Cd) was also confirmed by the proposed evaluation method. 相似文献
3.
4.
The highly specific molecular recognition of a twisted hexaporphyrin complex, tris[5,5'-bis[5,10,15-tris[methoxy(ethoxy)(2)carbonylethyl]porphyrinatozinc(II)]-2,2'-bipyridine]ruthenium(II) chloride (2), is described. Complex 2 has two trisporphyrin binding sites and can bind two triamines, tris(2-aminoethyl)amine (3) (K(1) = 3.0 x 10(8) M(-1), K(2) = 3.0 x 10(7) M(-1)), 1,1,1-tris(aminomethyl)ethane (4) (K(1) = 2.0 x 10(7) M(-1), K(2) = 1.4 x 10(6) M(-1)), tris(3-aminopropyl)amine (5) (K(1) = 3.5 x 10(6) M(-1), K(2) = 6.0 x 10(6) M(-1)), and 1,3,5-tris(aminomethyl)benzene (6) (K(1) = 2.9 x 10(6) M(-1), K(2) = 1.2 x 10(6) M(-1)), strongly with its torsional motion. The 1:2 complex between 2 and the best fit triamine 3 showed the nature of the specific rigid structure in the UV-vis, fluorescence, and (1)H NMR spectra and isothermal titration calorimetry (ITC) measurements. 相似文献
5.
Kunishima M Kitao A Kawachi C Watanabe Y Iguchi S Hioki K Tani S 《Chemical & pharmaceutical bulletin》2002,50(4):549-550
Racemization of the C-terminal amino acid (Ala) has been studied in various solvents during coupling between 4-methoxybenzyloxycarbonyl (Z(OMe))-Gly-L-Ala-OH and phenylalanine benzyl ester (H-Phe-OBzl) with 4-(4,6-dimethoxy-1,3,5-thiazin-2-yl)-4-methylmorpholinium chloride (DMT-MM). The reaction occurred without substantial racemization in AcOEt, tetrahydrofuran (THF), N,N-dimethylformamide (DMF), CH3CN, and 2-PrOH, while a slight racemization was observed in dimethyl sulfoxide (DMSO), EtOH, and MeOH. The extent of racemization may correlate with the polarity of the solvents. 相似文献
6.
Porphyrin macrocycles composed of five and six units of m-gable imidazolylporphyrinatozinc (1-Zn) were synthesized by self-assembled cyclization followed by ring-closing metathesis linkings. Each porphyrin macrocycle was isolated by GPC chromatography, and their molecular weights were determined by MALDI-TOF mass spectroscopy. These structures represent mimics of light-harvesting complexes in photosynthetic bacteria. [structure: see text] 相似文献
7.
A precise and accurate method in which ammonia and ammonium ions are coulometrically titrated with electrogenerated hypobromite was studied. Through the measurement of the current efficiency for generating hypobromite and the dependencies of titration results on electrolysis current and delay time between sampling and starting electrolysis, precision and accuracy of 0.01 and 0.02%, respectively, were obtained. The accuracy of the titration was compared with that of acidimetric coulometric titration of ammonia. 相似文献
8.
9.
Hwang IW Park M Ahn TK Yoon ZS Ko DM Kim D Ito F Ishibashi Y Khan SR Nagasawa Y Miyasaka H Ikeda C Takahashi R Ogawa K Satake A Kobuke Y 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(12):3753-3761
The excitation-energy-hopping (EEH) times within two-dimensional cyclic zinc(II)-porphyrin arrays 5 and 6, which were prepared by intermolecular coordination and ring-closing metathesis reaction of olefins, were deduced by modeling the EEH process based on the anisotropy depolarization as well as the exciton-exciton annihilation dynamics. Assuming the number of energy-hopping sites N = 5 and 6, the two different experimental observables, that is, anisotropy depolarization and exciton-excition annihilation times, consistently give the EEH times of 8.0 +/- 0.5 and 5.3 +/- 0.6 ps through the 1,3-phenylene linkages of 5 and 6, respectively. Accordingly, the self-assembled cyclic porphyrin arrays have proven to be well-defined two-dimensional models for natural light-harvesting complexes. 相似文献
10.