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Abernethy Colin D. Baker Robert J. Cole Marcus L. Davies Aaron J. Jones Cameron 《Transition Metal Chemistry》2003,28(3):296-299
The reactivity of the carbene stabilised indium trihydride complex, [InH3(IMes)] IMes = 1,3-dimesitylimidazol-2-ylidene, toward a variety of transition metal complexes has been investigated. The study has shown that the InH3 complex can act as a carbene and/or hydride transfer reagent to transition metal centres but does not yield heterobimetallic materials. Two new complexes, [Cp2Ti(-Cl)2Zn(IMes)Cl] and [CpNi(H)(IMes)], have resulted from this work, both of which have been spectroscopically and structurally characterised. 相似文献
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In a recent paper, a “distance” function,
, was defined which measures the distance between pure classical and quantum systems. In this work, we present a new definition of a “distance”, D, which measures the distance between either pure or impure classical and quantum states. We also compare the new distance formula with the previous formula, when the latter is applicable. To illustrate these distances, we have used 2 × 2 matrix examples and two-dimensional vectors for simplicity and clarity. Several specific examples are calculated. 相似文献
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Fatemeh Mahmoodani Conrad O. Perera Grant Abernethy Bruno Fedrizzi David Greenwood Hong Chen 《Journal of the American Society for Mass Spectrometry》2018,29(7):1442-1455
In a successful fortification program, the stability of micronutrients added to the food is one of the most important factors. The added vitamin D3 is known to sometimes decline during storage of fortified milks, and oxidation through fatty acid lipoxidation could be suspected as the likely cause. Identification of vitamin D3 oxidation products (VDOPs) in natural foods is a challenge due to the low amount of their contents and their possible transformation to other compounds during analysis. The main objective of this study was to find a method to extract VDOPs in simulated whole milk powder and to identify these products using LTQ-ion trap, Q-Exactive Orbitrap and triple quadrupole mass spectrometry. The multistage mass spectrometry (MSn) spectra can help to propose plausible schemes for unknown compounds and their fragmentations. With the growth of combinatorial libraries, mass spectrometry (MS) has become an important analytical technique because of its speed of analysis, sensitivity, and accuracy. This study was focused on identifying the fragmentation rules for some VDOPs by incorporating MS data with in silico calculated MS fragmentation pathways. Diels–Alder derivatization was used to enhance the sensitivity and selectivity for the VDOPs’ identification. Finally, the confirmed PTAD-derivatized target compounds were separated and analyzed using ESI(+)-UHPLC-MS/MS in multiple reaction monitoring (MRM) mode. 相似文献
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David A. Abernethy Nicholas G. Cutmore Thressa G. Evans Michael J. Millen Brian D. Sowerby 《Particle & Particle Systems Characterization》1998,15(1):42-46
CSIRO has developed an ultrasonic attenuation and transit time technique and a microwave transmission technique for on-line determination of the mass flow of pneumatically conveyed solids. In a comparative plant trial on a single burner line at Bayswater power station, the ultrasonic technique determined the coal density and velocity with rms errors of 3.9 and 5.9% relative respectively; the microwave technique successfully determined the coal density with an rms error of 6.2% relative, but was unable to accurately determine solids flow velocity at the low coal densities typical of the trial. In a plant trial at a direct smelter, the microwave technique successfully determined the mass flow of pneumatically conveyed iron ore fines feeding the smelter with an rms error of 10.2% relative. 相似文献
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The anionic tripodal N-heterocyclic carbene (C3N2H3)3BH- first prepared by Fehlhammer, together with three neutral variants, (C3N2H3)3CH, (C3N2H3)3P, and (C3N2H3)3SiH, have been studied using quantum chemical methods. Isodesmic reactions are used to deduce that the phosphine-bridgehead species in particular has a large-resonance stabilization energy. All the podands undergo substantial conformational change on excitation to the lowest triplet electronic state, with effective localization of the excitation on one of the heterocyclic rings, dearomatizing it. On monoprotonation of the ground states, three of these species display intramolecular C-H...Ccarbene hydrogen bonding: The nature and strength of these interactions is explored using model (intermolecularly hydrogen-bonded) complexes, isodesmic reactions, and GIAO calculations of chemical shifts. One surprising result is that C-H...Ccarbene hydrogen bonds involving ethenic hydrogens can be almost as strong as those involving the imidazolium proton (first identified by Arduengo). The case of the monoprotonated carbon bridgehead species is in particular intriguing. It is stabilized by a competitive Ccarbene...N interaction of sufficient strength to override the C-H...Ccarbene bonding motif observed in the other structures. 相似文献
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Resolution of z-dl-alanine amide has been achieved through papain-catalyzed reactions with aniline, the three anisidines, the three aminophenols and the three fluoroanilines. Most of the resultant anilides displayed better than a 95% resolution of the racemic amide. The four methyl esters of hippuric acid, z-glycine, z-l-alanine and z-dl-alanine were prepared by means of a recently reported catalytic dehydrator in the presence of excess dry methanol. Subsequent treatment with ammonia produced the amides. Three N-acylaminomalonic amides were synthesized by a different route than previously used, from ethyl aminomalonate hydrochloride. Trial asymmetric syntheses were unsuccessful for papain catalysis of such achiral amides with aniline. A few organic solutes were tested for their effects on the activity of papain during anilide synthesis. The pH dependence of yield was studied for papain catalysis of reactions between aniline and hippuric amide and then aniline and z-glycine amide. 相似文献
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A method is described for determination of minoxidil in human plasma using high-performance liquid chromatography with electrochemical detection. The method is specific and sensitive (500 pg/ml), however, minoxidil and minoxidil sulfate cannot be differentiated due to rapid autohydrolysis of minoxidil sulfate to minoxidil. The extraction procedure employs a C18 preparatory column to remove endogenous plasma constituents which would interfere with the assays. The calibration curves are linear for concentrations from 500 pg to 10 ng/ml. Within-day and between-day reproducibility are satisfactory with coefficient of variation less than 5.7% for all concentrations. Sample recovery from extraction is consistent at 45 to 55% at low and high concentrations, respectively. A pharmacokinetic study in a hypertensive volunteer receiving two different oral doses of minoxidil (1.25 and 2.5 mg) on different occasions demonstrates the utility of the method. 相似文献
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A structural failure problem was solved using an integrated and iterative program of testing and analysis. The steps taken in solving the problem were: analytical calculations; operational testing; qualifications of analytical results; problem identification; design of corrective action; and confirmatory testing. 相似文献