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A palladium(Ⅱ) complex, [PdLCl]2· [PdCl4], [L=4-bromo-2,6-bis(N,N-diethylaminomethylene)pyridine], was synthesized and its crystal structure was determined by X-ray analysis. The complex crystallizes in monoclinic system with space group Cc, a=0.845 1(17) nm, b=1.836 5(4) nm, c=2.715 8(5) nm,β=93.99(3)°, V=4.204 8(15) nm^3, Z=4, R,=0.037 7 and wR2=0.076 9. The coordination geometry of the Pd atom in the cation is a slightly distorted square planar, with one pyridyl N and two N atoms of the diethylamine ligand, together with one Cl atom. The dihedral angle between the square planar (N3PdCl) and the pyridyl ring is 10.3(4)°. CCDC: 623421. 相似文献
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