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Tapping mode atomic force microscope has been applied to observe single-chain PMMAparticles which were stored for six months at room temperature after sprayed from verydilute solutions in good solvents, good/poor mixed solvents, and a theta solvent. Monodis-perse PMMA standards of molecular weights ranging from 7.90×10~4 to 1.3×10~6 wereused to investigate the effect of molecular weight oh the size of the single-chain PMMAparticles. These single-chain particles showed close to spherical shapes. The morphologyof single-chain PMMA particles of a given molecular weight was found to be identical inspite of different solvents used for solution spraying. Molecular weigh dependence of theparticle dimension was also found. The diameters of single-chain PMMA particles aftercorrection of tlp-geometry effect were compared to the values estimated from molecularweight and density.  相似文献   
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气液界面聚离子复合结构的形成能减弱两性分手亲水基间静电排斥作用,增加单分子膜的稳定性和累积性能.X-射线衍射结果表明,纯水和聚乙烯亚胺水溶液表面上的ZC14SNa单分子膜在聚苯乙烯基片上累积成Y型膜,两种LB膜的等同周期差约为0.30um.  相似文献   
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