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以酰腙为配体钒的单核、双核配合物因其结构丰富、生物活性多样而引起广泛关注。目前该领域新配合物的合成、表征和生物活性的研究甚为活跃。本文回顾了近年来钒酰腙配合物的研究状况,主要从以下三个方面进行综述:(1)钒酰腙配合物的合成方法;(2)此类配合物的配位模式;(3)一些单、双核钒酰腙配合物抗变形虫,抗肿瘤,类胰岛素,抑制Na+, K+-ATP酶,与DNA作用的生物活性。文中着重阐述了钒酰腙化合物的结构和生物活性之间的关系。此外,还提出了钒酰腙配合物研究领域的不足之处并对其今后发展方向进行了展望。 相似文献
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The reaction of VO(acac)2 with 2-hydroxyl-1-naphthaldehyde isonicotinyl hydrazone and amines (ethylenediamine or diethylenetriamine) in CH3OH yields crystals of novel vanadium compounds characterized by IR, NMR spectroscopic methods and X-ray single-crystal structure determination. Two different vanadium units exist in the crystal cell of [VO2(C17H11N3O2)][VO- (C4H13N3)(C6H5N3O)](C2H5OH) which crystallizes in the triclinic system, space group P1 with a = 8.0104(17), b = 13.898(3), c = 14.955(3)A, α = 89.103(4), β = 79.551(4), γ = 78.352(4)°, V = 1603.3(6)A^3, Mr = 723.54, Dc = 1.499 g/cm^3, Z = 2, λ(MoKα) = 0.71073 ]A,μ= 0.644 mm^-1, F(000) = 748, the final R = 0.0547 and wR = 0.0997 for 8920 observed reflections with I 〉 2σ(I). According to structure analysis, two different molecules are arranged in the lattice and the two vanadium atoms adopt octahedral and square pyramidal coordination geometries, respectively. The interactions between DNA and vanadium complexes have been investigated by UV-Vis absorption spectro- photometry. 相似文献
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