Two New d~(10) Supramolecular Polymers Constructed by 1H-Pyrazolo[3,4-b]pyridin-3-amine and 1,4-Benzenedicarboxylic Acids

Two new coordination polymers, [Cd(BDC)(HL)]n(I) and {[Zn(BDC)(HL)_2]·(H_2 O)}_n(Ⅱ), have been synthesized under solvothermal conditions, based on 1 H-pyrazolo[3,4-b]pyridin-3-amine(HL) along with 1,4-benzenedicarboxylic acid(H_2 BDC). Polymers I and Ⅱ have been characterized by elemental analysis, IR spectroscopy, powder X-ray diffraction(PXRD) and single-crystal X-ray diffraction analysis. Polymer I features a two-dimensional 4-connected sql structure and further extends into a three-dimensional supramolecular framework directed by hydrogen-bonding interactions and π-π interactions. Polymer Ⅱ exhibits a layered packing supramolecular structure. Hydrogen bonding interactions involved between the free water molecules and carboxylate O atoms of H2 BDC ligands as well as the amino N atom of HL ligands play a critical role in constructing the three-dimensional supramolecular structure of Ⅱ. The solid-state photoluminescent properties of the two polymers were also investigated.     

热丝辅助双偏压氢等离子体制造金刚石锥状表面研究

利用热丝辅助双偏压氢等离子体对化学气相沉积金刚石薄膜进行了纳米尺度上的表面改装,制造出锥状金刚石列阵.金刚石薄膜内在的柱状结构使氢离子在刻蚀薄膜时产生非均匀的刻蚀速率,对锥状表面的形成起着重要作用.另一方面,溅射出的含碳粒子会发生二次沉积,最终的特征表面形貌取决于刻蚀与含碳基团再沉积之间的相互竞争.栅极的使用影响基底区域放电的伏安特性,改变栅极电流可以对形成的金刚石特征表面结构进行有效调节.在处理过程中少量掺入甲烷,提高了金刚石表面附近的含碳基团浓度,促进二次成核,进而诱发均匀分布的锥状列阵. 关键词： 等离子体 表面 金刚石薄膜     

Effects of some parameters on the divertor plasma sheath characteristics and fuel retention in castellated tungsten tile gaps

Castellation of plasma facing components is foreseen as the best solution for ensuring the lifetime of future fusion devices. However, the gaps between the resulting surface elements can increase fuel retention and complicate fuel removal issues. To know how the fuel is retained inside the gaps, the plasma sheath around the gaps needs to be understood first. In this work, a kinetic model is used to study plasma characteristics around the divertor gaps with the focus on the H＋ penetration depth inside the poloidal gaps, and a rate-theory model is coupled to simulate the hydrogen retention inside the tungsten gaps. By varying the magnetic field strength and plasma temperature, we find that the H＋ cyclotron radius has a significant effect on the penetration depth. Besides, the increase of magnetic field inclination angle can also increase the penetration depth. It is found in this work that parameters as well as the penetration depth strongly affect fuel retention in tungsten gaps.     

漆树漆酶的催化氧化作用──Ⅸ．含叔丁基的儿茶酚类底物的漆酶催化氧化

用分光光度法对６个含叔丁基的儿茶酚类底物在不同ＰＨ条件下的离解和漆酶催化氧化行为进行了考察，测定了它们在ＰＨ８．０时的反应速度常数．结果表明，叔丁基的疏水性较好地适应了漆酶对底物疏水程度的要求，使这类底物更容易为漆酶所包结；漆酶活性中心周围的酸性氨基酸残基中的ω－羧基阴离子所提供的ｐＨ环境和质子转移作用，促进了这类底物的离解，使这类底物能在远低于其一级离解所需ｐＨ的环境中进行反应．速度常数数据显示，取代基的疏水作用和取代基参与双齿配位的能力是影响这类底物反应速度的主要因素；在叔丁基的存在下，取代基的电子效应对这类底物的反应速度的影响变得不明显．     

基于小波变换的Stark展宽算法的优化研究

为了提升Stark展宽计算等离子体电子密度的准确性,基于小波阈值去噪处理方法,对EAST氘原子光谱信号进行了处理,以信噪比(SNR)和均方根误差(RMSE)作为滤波效果的评价依据,通过对比确定了最优小波基db4,最优小波分解4层。根据噪声估计值计算适合的阈值参数进行信号重构,并将经过去噪处理后的数据应用到后期Stark展宽算法计算等离子体密度的分析过程中。结果表明,小波硬阈值去噪能够有效提高光谱信号信噪比、降低均方根误差,在消除光谱信号中噪声的同时,最大程度保留了有用的光谱细节特征信息,进而有利于光谱数据的建模效果,获得更为准确的等离子体电子密度。     

对硝基重氮氨基偶氮苯与汞的显色反应

在表面活性剂吐温-60存在下,于pH 8.05的盐酸-硼砂缓冲溶液中,汞对硝基重氮氨基偶氮苯该试剂形成稳定橘红色配合物,其最大吸收波长位于480 nm处,表观摩尔吸光率为1.54×10~5L·mol~(-1)·cm~(-1),汞量在0.7 mg·L~(-1)以内符合比耳定律。方法用于废水样中汞的测定,所得结果与二苯硫腙光度法测得结果相符合。     

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介绍了EAST偏滤器充气系统的改进措施,压电阀与冷屏一起安装在EAST颈管中,以缩短充气管道,将充气系统的延迟时间减少约200ms。冷屏起冷却阀门并屏蔽电磁场的作用。讨论了在准稳态条件下,延迟时间给偏滤器热流反馈控制带来的负面效应。在中性束加热条件下,通过在外靶板注入 Ar/D2(1：4)混合气体研究了靶板离子饱和流和热流分布的变化及充气对主等离子体的影响,得到了靶板离子饱和流显著降低、热流减少的结果。     

Radiative divertor behavior and physics in Ar seeded plasma on EAST

To investigate the radiative divertor behavior and physics for the scenario of impurity seeded plasma in ITER, the radiative divertor experiments with argon(Ar) seeding under ITER-like tungsten divertor condition were carried out during recent EAST campaigns. The experimental results reveal the high efficiency of reducing heat load and particle flux onto the divertor targets owing to increased radiation by Ar seeding. We achieve detached plasmas in these experiments. The inner–outer divertor asymmetry reduces after Ar seeding. Impurities, such as Ar, C, Li, and W, exist in the entire space of the vacuum chamber during EAST operations, and play important roles in power exhausting and accelerating the plasma detachment process. It is remarkable that the contamination of the core plasma is observed using Ar seeding owing to the sputtering of plasma facing components(PFCs), particularly when Ar impurity is injected from the upper tungsten divertor.     

漆酶/O2体系获取半醌自由基的研究

本文综述了在静态条件下用漆酶／O2体系获取高稳定浓度半醌自由基阴离子的有效办法。依据漆酶的单电子转移特性,分别采用强吸电子基团使未偶电子离域以稳定半醌自由基、适当的有机溶剂延缓半醌自由基衰减和ESR自旋稳定化技术三种途径。     

漆树漆酶的催化氧化作用(X)──叔丁基儿茶酚类底物的漆酶催化氧化和漆酶的微环境效应

对6个含叔丁基的儿茶酚类底物的离解和漆酶催化氧化反应进行了考察。结果表明:叔丁基的存在,有利于增进对底物的结合,并可以利用漆酶活性中心周围提供的pH环境和质子载体性质,促进底物的离解,使这类底物能在远低于其一级离解的弱酸性环境中进行反应。由于叔丁基的特性和漆酶的微环境效应的共同作用,这些底物在pH=6.0的水溶液环境中都能顺利地氧化成相应邻醌,并具有合成价值。ESR结果证明:这些底物在弱酸性条件下的漆酶催化反应经历了质子转移和单电子氧化步骤。