排序方式: 共有2条查询结果,搜索用时 15 毫秒
1
1.
本文使用金电极为工作电极,银-氯化银电极为参比电极,铂电极为对电极,在硫酸-碘化四乙基铵介质中减小了铋对铜的干扰,提高了铅、镉测定灵敏度.用导数阳极溶出法,可同时测定铜、铅和镉,它们的溶出峰电位分别为 0.25,-0.12和-0.27V、检测下限分别可达:铜(Ⅱ)和铅(Ⅱ)0.2ppb,镉(Ⅱ)0.05ppb.在选定的条件下,溶出峰电流与浓度很好地成线性关系.本文还用三角波循环伏安法观察了电极反应过程. 相似文献
2.
A method of simultaneous determination of copper (II), lead (II) and cadmium (II) in sulphuric acid-iocide ion medium was established by derivative anodic stripping voltammetry (DASV) on the gold electrode. The peak theights of lead and cadmium were increased by enhancement effect of iodide ion and the peaks of bismuth and copper were well formed and completely resolved on gold electrode in the presence of iodide ion, therefore peak of copper is not affected by bismuth. The sensitivities for copper, lead and cadmium were very high and their peak potentials in the stripping voltammogram were +0.25, -0.2 and -0.27 volt, respectively. The dependence of peak height of these elemets on their concentrations was linear. The detection limits for copper, lead and cadmium were 0.2 0.2 and 0.05 ppb, respectively. We have further studied the electrode process by means of triangle cyclic voltammetry and proved that he electrode reaction of copper is reversible, and that the reversibility of electrode reactions of lead and cadmium is not good. 相似文献
1