Ag(TCNQ)准一维微米结构的制备及表征

利用溶液化学反应法制备了准一维结构的金属有机配合物Ag(TCNQ). X射线衍射(XRD)表明，所制备的Ag(TCNQ)为晶态结构;扫描电子显微镜(SEM)的观察证明，Ag(TCNQ)为准一维的微米管或线；Raman 测试结果表明，单根的Ag(TCNQ)形成时,Ag原子与TCNQ分子之间发生了电荷转移.对样品的制备工艺,即 Ag膜厚度和浸入溶液的反应时间对生成Ag(TCNQ)晶体形貌的影响进行了研究.结果表明，Ag膜越薄，生长出的晶体越稀疏;Ag膜与TCNQ乙腈溶液的反应时间影响其形貌的变化.反应历经三个阶段,晶体形成和长大阶段、反应完全阶段及溶解阶段.     

篮球阴影问题——研究性学习课例示范

1问题1的引入经常打篮球的学生提出一个问题:篮球停止在地面上的时候,太阳光斜照下来,篮球的阴影部分是否是一个椭圆呢?对此可用立体几何、解析几何的原理进行探讨.解法1画图分析,如图1,假设球的半径为R,地面为平面γ,光线与地面所成的角为α,过球心且垂直于光线的平面为φ,它和地面γ的交线为l,平面φ截球面所得的大圆的直径为A′B′,并记二面角γ-l-φ的大小为θ,θ=2π-α.图1点P是阴影曲线上的任一点,它从圆O′上的点P′处射过来的.则PP′⊥φ.因为PP′、PH都是球的切线,所以PP′=PH.作PQ⊥l于Q,则有PPPQ′=sinθ=cosα,PHPQ…     

Growth Mechanism of Vertically Aligned Ag（TCNQ） Nanowires

Highly oriented Ag(TCNQ) nanowires have been prepared on Si(111) wafer at 1O0℃ by the vapour-transport reaction between silver and TCNQ without any other catalyst. X-ray diffraction analysis shows that the composition and crystal structure of the obtained nanostructure were Ag(TCNQ) crystalline. Most Ag(TCNQ) nanowires were grown uniformly and vertically on the substrate with diameters ranging from 50 to 30Onto and the lengths measuring from 2 to 50μm by scanning electron microscopy. Ag particles were observed on the substrate from pure thin Ag film heated under the same conditions as used in synthesizing the nanowires. Nucleation and short Ag(TCNQ) nanowires were prepared by controlling the reaction time, providing direct evidence of the growth mechanism in a nanometre scale. The growth process was explained according to the vapour-liquid-solid model. The gradient of temperature and the densely distributed Ag particles may contribute to the vertically aligned growth. These results will be helpful for the controllable synthesis of Ag(TCNQ) nanowires.