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排序方式: 共有158条查询结果,搜索用时 250 毫秒
1.
V. V. Panić A. B. Dekanski S. K. Milonjić V. B. Mišković-Stanković B. Ž. Nikolić 《Russian Journal of Electrochemistry》2006,42(10):1055-1060
Electrocatalytic properties of RuO2/Ti anode with different coating masses, which are prepared by the alkoxide sol-gel procedure, are investigated in chlorine
and oxygen evolution reactions by polarization measurements and electrochemical impedance spectroscopy in H2SO4 and NaCl electrolytes. According to polarization measurements, the activity of anodes at overpotentials below 100 mV is independent
of coating mass. However, impedance measurements above 100 mV reveal changes in the activity of anodes in chlorine evolution
reaction for different coating masses. The diffusion limitations related to the evolved chlorine are registered in low-frequency
domain at 1.10 V (SCE), diminishing with the increase in potential to the 1.15 V (SCE). The observed impedance behavior is
discussed with respect to the activity model for activated titanium anodes in chlorine evolution reaction involving formation
of gas channels within porous coating structure. Gas channels enhance the mass transfer rate similarly to the forced convection,
which also increases the activity of anode. This is more pronounced for the anode of greater coating mass due to its more
compact surface structure. The more compact structure appears to be beneficial for gas channels formation.
Published in Russian in Elektrokhimiya, 2006, Vol. 42, No. 10, pp. 1173–1179.
The text was submitted by the authors in English. 相似文献
2.
Dragomir Ž. Đoković 《Combinatorica》1994,14(3):375-377
No Hadamard matrices of order 956 appear in the literature. In this note we construct two such matrices. They are both of Goethals-Seidel type. As a consequence of this and of a result of Seberry and Yamada, we conclude that there exist 4-Williamson type matrices of order 1913.This work was supported by NSERC of Canada Grants A-5285 and EQP0107539. 相似文献
3.
R. Ž. Nurpeisov 《Analysis Mathematica》1989,15(2):127-143
H
(G), f(g)H
(G) , (, 1)- OHMC G. , OHMC, A. H. . , . , OHMC, lim supp
n=, , ,n .. . , 117 234 . . - 相似文献
4.
Due to the high safety risks, chemistry instructors avoid demonstrating many remarkable experiments based on the addition of a liquid to a solid. Well-known examples of such demonstrations are various pyrotechnic mixtures of potassium chlorate and sugar (sucrose), which are usually activated with a drop of concentrated sulfuric acid. Other attractive demonstrations are the addition of water to freshly prepared magnesium phosphide and addition of water to burning magnesium. In all of these demonstrations the reaction that takes place immediately is very vigorous and can be hazardous for the instructor. Because chemistry teachers and instructors usually try to avoid performing experiments that include a hazard, a number of highly attractive experiments may remain unknown to the public. Using a simple homemade device called a safety dropper, one can perform all of these experiments with complete safety, both for the audience and the demonstrator. Details for performing some of these experiments as well as for the construction of the safety dropper are given in this paper. Video clips of demonstrations are included as an aid for inexperienced instructors. 相似文献
5.
6.
This paper presents qualitative and quantitative comparative results on the simultaneous TG-DTG DTA of five commercial and low-grade bauxites. The methodology of qualitative determination of the basic mineral forms contained in bauxites is currently being established. The weight losses relating to the steps in the TG curve allow determination of the contents of the basic minerals in bauxite. These are recalculated as percentages of Al2O3, SiO2, CaO moisture and total volatiles. The final results are in accordance with the results of classical chemical analyses, and this jusitifies the use of this technique as a quick method for qualitative and quantitative determinations of both commercial and low-grade bauxites.
Zusammenfassung Qualitative und quantitative Ergebnisse vergleichender simultaner TG-DTG-DTA-Untersuchungen an 5 kommerziellen und geringwertigen Bauxiten werden vorgestellt. Die Methodologie der qualitativen Bestimmung der wichtigsten im Bauxit enthaltenen Minerale wird ausgearbeitet. Die Gewichtsverluste bei den entsprechenden TG-Stufen erlauben die Berechnung der Gehalte an den wichtigsten Mineralen. Diese werden umgerechnet in die Anteile an Al2O3, SiO02, CaO, Feuchtigkeit und Glühverlust. Letztere Resultate stimmen mit denen klassisch-chemischer Analyse überein. Das erlaubt die Anwendung thermoanalytischer Methoden als Schnellverfahren für qualitative und quantitative Bestimmungen in kommerziellen und geringwertigen Bauxiten.
, . , . , , , . , , .相似文献
7.
Ž. Grahek 《Journal of Radioanalytical and Nuclear Chemistry》2001,247(2):297-305
The separation of strontium and yttrium from calcium on the anion exchanger column with alcohol solution of nitric acid as eluent may be described by Glueckauf's model of elution chromatography. Experimental and theoretical results have shown that this separation is characterized by a small number of theoretical plates of the separation column. This model may also be applied for the simulation of the separation of strontium and yttrium from calcium in the strontium isolation from natural samples. The model parameters may be used for the assessment of the optimum column dimension and the optimum working conditions for the isolation of radioactive strontium and yttrium from natural samples. 相似文献
8.
The
aim of our research was to prepare yellow pigments based on structure of pseudobrookite
Fe2TiO5. Part of Fe was substituted
with Li and Ti from Fe2TiO5
to Li0.05Fe0.07Ti2.44O5.
Synthesis and pigmentary-application properties in the Li2O–Fe2O3–TiO2 system were studied for 800 and 900°C using classical ceramic
method of preparation. The main attention was aimed to usage of four different
sources of titanium compounds as raw materials. We studied the influence of
different sources of titanium compounds on the structural and the colour properties
of the prepared pigments. The thermal analysis was used for characterization
of titanium compounds and determination of their thermal stability. 相似文献
9.
Mészáros Szécsényi K. Leovac V. M. Jaćimović Ž. K. Češljević V. I. Kovács A. Pokol G. 《Journal of Thermal Analysis and Calorimetry》2001,66(2):573-581
The synthesis of copper(II) chloride complexes with 3,5-dimethylpyrazole, 1-carboxamidine-3,5-dimethylpyrazole, 5-amino-4-carboxamide-1-phenylpyrazole
and 4-acetyl-3-amino-5-methylpyrazole is described. The compounds are characterized by elemental analysis, FT-IR spectroscopy,
thermal methods, magnetic moment and molar conductivity measurements. Thermal decomposition of the dichloro-(3,5-dimethylpyrazole)-copper(II)
complex results in an unstable intermediate with a stochiometric composition. The decomposition of the other compounds is
continuous.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
10.