首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2655篇
  免费   226篇
  国内免费   206篇
化学   328篇
晶体学   7篇
力学   1350篇
综合类   36篇
数学   427篇
物理学   939篇
  2024年   1篇
  2023年   18篇
  2022年   31篇
  2021年   34篇
  2020年   72篇
  2019年   52篇
  2018年   60篇
  2017年   76篇
  2016年   88篇
  2015年   94篇
  2014年   120篇
  2013年   253篇
  2012年   88篇
  2011年   132篇
  2010年   100篇
  2009年   135篇
  2008年   132篇
  2007年   157篇
  2006年   161篇
  2005年   127篇
  2004年   156篇
  2003年   115篇
  2002年   113篇
  2001年   83篇
  2000年   79篇
  1999年   80篇
  1998年   89篇
  1997年   80篇
  1996年   52篇
  1995年   53篇
  1994年   41篇
  1993年   36篇
  1992年   43篇
  1991年   45篇
  1990年   16篇
  1989年   13篇
  1988年   10篇
  1987年   10篇
  1986年   7篇
  1985年   9篇
  1984年   4篇
  1983年   3篇
  1982年   3篇
  1981年   5篇
  1980年   2篇
  1979年   4篇
  1977年   2篇
  1971年   1篇
  1957年   2篇
排序方式: 共有3087条查询结果,搜索用时 15 毫秒
1.
为探究水牛角的结构性能关系,基于上海同步辐射光源搭建了高分辨原位CT系统,对水牛角角鞘进行初始表征和准静态压缩下的实时表征,并通过Top-Hat方法提取了角鞘内孔洞三维形貌。结果显示,水牛角角鞘孔隙率在1%左右,椭圆柱状孔洞沿牛角生长方向排列成线,首尾相连却并未连通,均匀分布在波浪状片层之间。孔洞特征椭球的轴长分布满足对数正态分布,长轴和短轴的长度均值分别为7μm和3μm。原位CT结果表明,角鞘在屈服之后,初始孔洞首先扩张而形成微裂纹,随后微裂纹沿着片层界面由外向内发生桥接,片层发生局部屈曲和层间开裂,形成宏观裂纹,导致角鞘内裂纹密度急剧上升。片层之间不仅存在大量纤维黏接(提高了层间拉伸/剪切强度),而且孔洞互不连通,这些因素抑制了层间裂纹的快速传播,使得各处裂纹只能独立缓慢发展而无法贯通样品。波浪状片层使裂纹传播路径更加曲折,层间屈曲增加了片层摩擦耗能。这些机制使得牛角表现出加工硬化,也是牛角在纵向方向呈现优良韧性的主要原因。  相似文献   
2.
冲击载荷作用下边界条件对方板的毁伤破坏具有很大影响。利用落锤试验机开展了不同边界支撑下固支方板的冲击试验,为获取固支方板边界撕裂的典型破坏模式,专门设计加工了与固支方板尺寸相当的冲击锤头和可改变倒角的方板支撑框架。研究结果表明:(1)冲击载荷作用下,固支方板呈现出塑性大变形、单边撕裂、双边撕裂等典型破坏模式,倒角越小,方板越容易撕裂;(2)边界支撑对固支方板中心位移、整体变形轮廓影响较小,但对方板的撕裂长度、临界撕裂阈值存在较大影响;(3)不同边界支撑主要改变方板边界处的剪切应变,边界支撑倒角越小,剪切效果越明显,方板边界临界撕裂应变位于[0.191,0.241]区间。  相似文献   
3.
A continuum damage model was developed to describe the finite tensile deformation of tough double-network (DN) hydrogels synthesized by polymerization of a water-soluble monomer inside a highly crosslinked rigid polyelectrolyte network. Damage evolution in DN hydrogels was characterized by performing loading-unloading tensile tests and oscillatory shear rheometry on DN hydrogels synthesized from 3-sulfopropyl acrylate potassium salt (SAPS) and acrylamide (AAm). The model can explain all the mechanical features of finite tensile deformation of DN hydrogels, including idealized Mullins effect and permanent set observed after unloading, qualitatively and quantitatively. The constitutive equation can describe the finite elasto-plastic tensile behavior of DN hydrogels without resorting to a yield function. It was showed that tensile mechanics of DN hydrogels in the model is controlled by two material parameters which are related to the elastic moduli of first and second networks. In effect, the ratio of these two parameters is a dimensionless number that controls the behavior of material. The model can capture the stable branch of material response during neck propagation where engineering stress becomes constant. Consistent with experimental data, by increasing the elastic modulus of the second network the finite tensile behavior of the DN hydrogel changes from necking to strain hardening.  相似文献   
4.
To study drag force on a moving heavy quark through a plasma, we use a deformed AdS space-time, in which deformation parameter c describes non-conformality in AdS/QCD. In this case, the quark is mapped to a probe string in the AdS space. Considering the probable contribution of the deformation parameter in the probe string, we apply a general form of c-dependent string ansatz in the drag force computation. Then, we find the acceptable value of this parameter as it satisfies QCD calculations. Using this result, we also discuss the diffusion constant which is in agreement with the phenomenological result for the non-relativistic limit. Also, we show that while in absence of a deformation parameter, the probe string is a strictly increasing function of radial coordinate, the c-dependent probe string has a maximum value versus z.  相似文献   
5.
采用分子动力学模拟计算方法,考察具有较高层错能的Al纳米线沿不同晶向的力学行为和变形机制。在相同计算条件下与具有较低层错能的Ni、Cu、Au和Ag等FCC金属纳米线进行比较。结果表明:在力学行为方面,Al纳米线的弹性模量呈现明显的结构各向异性,满足E[111] > E[110] > E[100]的关系,这一关系在FCC金属纳米线中普遍成立;Al纳米线的屈服应力随晶向呈现σy[100] > σy[111] > σy[110]的关系,这一关系在具有较低层错能的FCC金属纳米线中不具有普遍性,这与体系中位错形成机制密切相关。根据拉伸变形过程微观结构的演变规律,阐明Al纳米线不同晶向的变形机制,并与具有较低层错能的Ni、Cu、Au和Ag等FCC金属纳米线的变形机制进行比较。结果表明,对于尺度较小的高层错能Al纳米线,Schmid因子和广义层错能均难以准确预测其变形机制。  相似文献   
6.
Developing oxygen evolution reaction (OER) electrocatalyst based on earth-abundant materials holds great promise for ascertaining water-splitting to surmount its deprived kinetics. In this regard, NiFe-LDH (layered double hydroxide) receives considerable attention owing to their layered structure. However, they still suffer from poor electronic conductivity and structural stability. We combined NiFe-LDH nanosheets with Magnéli phase Ti4O7 into a heterostructured composite. A series of analyses reveal that decorating Ti4O7 facilitates charge transfer to enhance the conductivity of NiFe-LDH-Ti4O7. During electrochemical measurement, Ni2+ is transformed to metastable Ni3+ (Ni (OH)→ NiOOH) before the OER onset potential. Thus, the presence of Ni3+ as the main active sites could improve the chemisorption of OH? to facilitate OER. As a result, the NiFe-LDH-Ti4O7 catalyst delivers as low as onset potential (1.43 V). Combining the holey structure (NiFe-LDH and Ti4O7) and the defect engineering generated on NiFe-LDH-Ti4O7 as a synergistic effect improves the OER performance. The inclusion of Ti4O7 in the composite leads to more vacancy sites, as evidenced by the extended X-ray absorption fine structure (EXAFS) analysis. The obtained defective structure with a low coordination environment would improve the electronic conductivity and facilitate the adsorption process of H2O onto metal cations, thereby increasing the intrinsic catalytic activity of NiOOH. The strong coupling of NiFe-LDH and Ti4O7 also increases the stability, and the heterostructured composite helps maintain the structural robustness of the LDH.  相似文献   
7.
We report an experimental investigation of free falling super-hydrophobic (SH) spheres in glycerine-water mixtures over a wide range of Reynolds number. SH coatings have the ability to reduce the contact area between the surrounding liquid and the solid surface by entrapping an air layer in the surface roughness. We investigate the effect of this air plastron on the hydrodynamic performance of spheres, focusing our attention on the onset of wake instabilities. Our results emphasise the key role of the surface roughness properties on the triggering of wake instabilities. It is shown that, unlike what was reported in previous numerical studies on SH bluff-bodies, local deformation of the interface may act as a by-pass mechanism promoting earlier transition, yielding a decrease of the critical Reynolds number at which the wake becomes unstable. A scenario coupling the hydrodynamic instabilities (scaling with the Reynolds number) and the interface deformation (scaling with the roughness-based Weber number) is proposed to describe the different transition mechanisms in presence of SH surfaces. It is found that the promotion of wake instabilities over SH surfaces occurs when the roughness-based Weber number is larger than a critical threshold. These findings are of primary importance for guiding the design of resilient and efficient SH surfaces.  相似文献   
8.
飞火是开放空间中大尺度火灾非连续性蔓延的主要形式。本文通过不同热流下的木质飞火颗粒自由燃烧实验,揭示不同燃烧状态飞火颗粒的结构变形、质量损失及温度分布的变化规律。研究表明,颗粒结构变形受材料化学反应机制和热机械力作用共同影响;颗粒燃烧反应易造成热解气体的内部积聚,以致内压激增、诱发喷射或喷溅细小颗粒的现象;阴燃过程颗粒表面温度变化较小但持续时间很长,明火状态的颗粒持续高温并且温度与质量变化剧烈。  相似文献   
9.
采用基于第一性原理的全势能线性缀加平面波方法计算闪锌矿结构CaC和SrC的电子结构.计算结果表明,锌矿结构CaC和SrC是自旋向上电子为非金属性的半金属,其半金属隙分别为0.83 eV和0.81 eV.磁性的计算分析表明,CaC和SrC的晶胞总磁矩都为2.00μB,C的原子磁矩较强,Ca和Sr的原子磁矩较弱.使晶格均匀体形变△a/a0限于±15%,在此范围内计算CaC和SrC的电子结构.计算研究表明,当闪锌矿结构CaC和SrC的晶格常数分别为0.490 nm—0.661 nm和0.539 nm—0.707 nm时,它们的半金属性不变,晶胞总磁矩仍然为2.00μB.  相似文献   
10.
相比传统的弹簧法等方法,基于球松弛算法的动网格松弛法在复杂边界大变形条件下可以得到质量更高的边界网格以及更大的极限变形量,但该方法在时间效率上还有提升的空间。引入二重网格,采用动网格松弛法进行稀疏网格的网格变形,将边界位移传递到整个网格计算域;再利用二重网格映射,将稀疏网格位移映射到原有计算网格的节点上。算例表明,改进后的动网格松弛法在极限变形量和变形后网格质量基本保持不变的情况下,能够有效地提高网格变形的计算效率。此外还研究了二重网格的粗细网格节点数之比(粗网格为稀疏网格,细网格为原计算网格)对网格变形的影响,算例表明最佳计算效率出现在粗细网格节点数之比为0.5左右时。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号