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1.
Ali Raza Hala A. Hejazi Sami Ullah Khan M. Ijaz Khan Kamel Smida Iskander Tlili 《印度化学会志》2022,99(7):100568
In this investigation, a mixed convective nanoparticles fluid flow over an inclined plate is deliberated. The effects of slip boundary wall and magnetic field are also considered. The dimensionless governing system for the considered problem is attained by implementing recent definitions of fractional derivatives (FD). The generalized solution is obtained through the Laplace Transformation Scheme (LTS) for the momentum and thermal expressions. To improve the novelty and to demonstrate some more physical perception of the stated research work, some remarkable special cases of velocity distribution through CF and AB-fractional derivative concept are addressed, whose daily life implication is well known in the existing literature. Moreover, to evaluate the physical interest of the stated problem, the outcomes of the obtained system graphical illustrations are made by utilizing MATHEMATICA. As a result, we concluded that the aluminium oxide nanoparticles show more decaying behavior as compared to titanium oxide nanoparticles for temperature and velocity profile. Furthermore, both fields i.e., momentum and thermal distributions are increased with the help of rising estimations parameter. Current results report novel applications in enhancement of heat transfer, thermal engineering, chemical processes, engineering and electronics devices, solar systems, extrusion processes, fission reactions etc. 相似文献
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双金属有机骨架及其衍生物一方面具有单金属有机骨架孔道丰富、比表面积大、结构可调、活性位点丰富等特点,另一方面具有双组分与多孔结构之间的协同效应,因而受到了研究人员的密切关注,在储能、催化、分离、传感器、医药、气体存储等领域广泛应用。和单金属MOFs类似,双金属MOFs的导电性不佳、结构易坍塌,这极大地限制了其在电化学储能中的应用。通过对双金属MOFs进行热处理,易得到分布均匀的多孔碳@双金属氧化物/硫化物/磷化物/硒化物等衍生物,不仅保持了独特的多孔结构,而且提高了材料的导电性和结构稳定性,有利于在电化学储能中的应用。因此,本文从双金属MOFs中的主要金属离子入手,综述了双金属MOFs及其衍生物用于超级电容器、锂离子电池、钠离子电池、金属空气电池等电化学储能器件的最新应用进展。在此基础上,总结了双金属MOFs在电化学储能应用中的优势,并对其制备、作用机理和后处理研究提出了建议。 相似文献
4.
《Arabian Journal of Chemistry》2022,15(11):104176
In this work, a new highly selective and sensitive fluorescent sensor for detecting Cu2+ was developed based on rhodamine fluorophore. It displayed strong fluorescence “turn-on” effect upon addition of Cu2+, and possessed the function of naked eye recognition. The fluorescence enhancement also enabled the sensor to quantitatively analyze Cu2+ due to the formation of a stable 1:1 metal–ligand complex in a short time, and the complex possesses relatively good pH stability. In addition, the density functional theory calculations were adopted to investigate the molecular orbitals as well as the spatial structure. Simultaneously, the cell imaging and zebra fish experiments provided a broader application prospect in biological system. 相似文献
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当初值不光滑时,时间分数阶齐次扩散方程数值方法的精度会下降.为了得到高阶时间收敛格式,提出加权移位的Grünwald-Letnikov的修正格式,运用Lubich的修正方法,得到非光滑时间分数阶齐次扩散方程的收敛阶仍为O(k2).最后,通过数值算例验证了数值计算结果与理论计算结果一致. 相似文献
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Meihua Shen Dr. Xinpeng Zhao Dr. Lu Han Nanxi Jin Prof. Song Liu Prof. Tao Jia Prof. Zhijun Chen Prof. Xiuhua Zhao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(20):e202104137
Solar-driven interfacial vaporization by localizing solar-thermal energy conversion to the air−water interface has attracted tremendous attention. In the process of converting solar energy into heat energy, photothermal materials play an essential role. Herein, a flexible solar-thermal material di-cyan substituted 5,12-dibutylquinacridone (DCN−4CQA)@Paper was developed by coating photothermal quinacridone derivatives on the cellulose paper. The DCN−4CQA@Paper combines desired chemical and physical properties, broadband light-absorbing, and shape-conforming abilities that render efficient photothermic vaporization. Notably, synergetic coupling of solar-steam and solar-electricity technologies by integrating DCN−4CQA@Paper and the thermoelectric devices is realized without trade-offs, highlighting the practical consideration toward more impactful solar heat exploitation. Such solar distillation and low-grade heat-to-electricity generation functions can provide potential opportunities for fresh water and electricity supply in off-grid or remote areas. 相似文献
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Dr. Joaquim Torra Dr. Felipe Viela Dr. Diego Megías Dr. Begoña Sot Prof. Cristina Flors 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(19):e202200026
CRANAD-2 is a fluorogenic curcumin derivative used for near-infrared detection and imaging in vivo of amyloid aggregates, which are involved in neurodegenerative diseases. We explore the performance of CRANAD-2 in two super-resolution imaging techniques, namely stimulated emission depletion (STED) and single-molecule localization microscopy (SMLM), with markedly different fluorophore requirements. By conveniently adapting the concentration of CRANAD-2, which transiently binds to amyloid fibrils, we show that it performs well in both techniques, achieving a resolution in the range of 45–55 nm. Correlation of SMLM with atomic force microscopy (AFM) validates the resolution of fine features in the reconstructed super-resolved image. The good performance and versatility of CRANAD-2 provides a powerful tool for near-infrared nanoscopic imaging of amyloids in vitro and in vivo. 相似文献
8.
ZHANG Kai-lin ZHOU Min SHI Ying-ying LI Shu-qi MA Li-fu ZHANG Xian-yi WANG Yan KONG Xiang-lei 《光谱学与光谱分析》2021,41(8):2325-2331
光解离光谱在气相离子结构及动力学研究中发挥着重要的作用。这种方法非常灵活,可在实验室中利用不同种类的激光器及质谱仪的结合来开展相应的研究。但也存在一些问题,例如,自动化水平低,费时,长时间的操作容易引入人为错误,使实验结果的可信度降低。为解决此类问题,该工作开发了一套可用于光谱自动采集和分析的程序AutoMS。该程序包含:(1)AutoSpecMS用于在无需改变原仪器配套的商业化操作软件的前提下,实现多台商业激光器及一台商业高分辨FT-ICR质谱仪的集成,只需要预设参数即可自动获取action光谱;(2)AutoDataMS用于实验数据的分析,可以通过一维、二维或三维图示的方法来展示光解离质谱和光谱等。为验证改程序的可行性,针对tetraphenylpyrrin(四苯基卟啉,TPP),tetra(4-carboxypyryl)porphyrin(四对羧基苯基卟啉,TCPP)以及tetra(4-aminophenyl)porphyrin(四对氨基苯基卟啉,TCPP)三种卟啉衍生物分别开展了相应的实验。使用光解离光谱自动采集程序采集了TPP, TCPP和TAPP在210~700 nm波段的紫外-可见光解离光谱。同时获得了相关光解离碎片离子的单通道光谱,有利于用户对所研究体系的解离机理及解离动力学等方面开展深入的分析探讨。光解离质谱可观察到目标离子在特定波长激光照射下的具体解离碎片,与光解离光谱相结合,可以更好地帮助研究者理解离子在特定波段内的光解离行为。使用AutoDataMS可分别获得样品的2D及3D光解离质谱-光谱,增强了结果的可视化,使研究者更方便地获得光谱中的相关信息。对数据进行进一步分析可看出,不同的取代基对紫外可见光谱的吸收产生了差异明显的影响。此外通过AutoDataMS程序的功能扩展,还实现了对质子化TPP在500~650 nm波段内各离子的相关度分析,加深了对实验数据的理解。由此可见该方法及程序具有较好的扩展性和实用性,并可以为其他相关的工作提供很好的参考。 相似文献
9.
《Journal of Saudi Chemical Society》2022,26(1):101398
A straightforward, cost effective and eco-friendly protocol for the Biginelli reaction relying on the use of readily available hypophosphorous acid is presented. The methodology developed displays improvements compared to existing methods, is high-yielding, robust and was applied to a panel of dihydropyrimidines and thio-derivatives with various substituents. Related urea derivatives such as guanidines, benzimidazoles and benzothiazoles also reacted efficiently to afford more complex scaffolds. Thus, this rapid and convenient catalysis allows access to a wide diversity of structures including original biologically relevant heterocycles. 相似文献
10.
This work is concerned with the extension of the Jacobi spectral Galerkin method to a class of nonlinear fractional pantograph differential equations. First, the fractional differential equation is converted to a nonlinear Volterra integral equation with weakly singular kernel. Second, we analyze the existence and uniqueness of solutions for the obtained integral equation. Then, the Galerkin method is used for solving the equivalent integral equation. The error estimates for the proposed method are also investigated. Finally, illustrative examples are presented to confirm our theoretical analysis. 相似文献