首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   9779篇
  免费   1294篇
  国内免费   829篇
化学   6336篇
晶体学   46篇
力学   235篇
综合类   87篇
数学   2257篇
物理学   2941篇
  2024年   3篇
  2023年   75篇
  2022年   142篇
  2021年   174篇
  2020年   268篇
  2019年   270篇
  2018年   275篇
  2017年   331篇
  2016年   283篇
  2015年   332篇
  2014年   414篇
  2013年   1329篇
  2012年   577篇
  2011年   521篇
  2010年   432篇
  2009年   548篇
  2008年   584篇
  2007年   694篇
  2006年   614篇
  2005年   547篇
  2004年   506篇
  2003年   471篇
  2002年   380篇
  2001年   296篇
  2000年   307篇
  1999年   249篇
  1998年   234篇
  1997年   161篇
  1996年   180篇
  1995年   151篇
  1994年   120篇
  1993年   102篇
  1992年   77篇
  1991年   54篇
  1990年   41篇
  1989年   34篇
  1988年   26篇
  1987年   18篇
  1986年   14篇
  1985年   13篇
  1984年   12篇
  1982年   5篇
  1981年   4篇
  1980年   2篇
  1979年   7篇
  1978年   3篇
  1977年   4篇
  1974年   6篇
  1973年   2篇
  1971年   2篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
The increasing application of positron emission tomography (PET) in nuclear medicine has stimulated the extensive development of a multitude of novel and versatile techniques to introduce fluorine-18, especially for the radiolabelling of biologically or pharmacologically active molecules. Taking into consideration that the introduction of fluorine-18 (t1/2=109.8 min) mostly proceeds under harsh conditions, radiolabelling of such molecules represents a challenge and is of enormous interest. Ideally, it should proceed in a regioselective manner under mild physiological conditions, in an acceptable time span, with high yields and high specific activities. Special attention has been drawn to 2-fluoroethyl and 3-fluoropropyl groups, which are often the active sites of radiofluorinated compounds. Precursors containing an ammonium leaving group – such as a strained azetidinium or aziridinium moiety – can help to overcome these obstacles leading to a convenient and mild introduction of [18F]fluoride with high radiochemical yields.  相似文献   
2.
A detailed study of the geometry, aromatic character, electronic and magnetic properties for a series of positively charged N-doped polycyclic aromatic hydrocarbons (PAHs) was performed. Magnetic properties of the examined molecules were analyzed by means of the magnetically induced current density calculated using the diamagnetic-zero version of the continuous transformation of origin of current density (CTOCD-DZ) method. The comparative study of the local aromaticity of the studied molecules was performed using several different indices: energy effect (ef), harmonic oscillator model of aromaticity (HOMA) index, six centre delocalization index (SCI) and nucleus independent chemical shifts (NICS). The presence of N-atoms in the inner rings was found to cause a planarity distortion in the studied N-doped systems. The geometric changes and charged nature of the studied N-doped systems do not significantly influence the current density and the local aromaticity distribution in comparison with the corresponding parent benzenoid hydrocarbons. The present study demonstrates how quantum chemical calculations can be used for rational design of novel PAHs and for fine tuning of their properties.  相似文献   
3.
Ti2O3 thin films have been prepared through atomic layer deposition and subjected to electrical resistivity measurements as a function of temperature. The as-prepared films were stable for up to three weeks. In Ti2O3 thin films, the insulator-metal transition is observed at ∼80 K, with nearly 3–4 orders of magnitude change in resistivity. The anomalous increase in electrical resistivity in the films is in accordance with the two-band model. However, the energy interval between the bands depending on the crystallographic c/a ratio leads to a change in electrical resistivity as a function of temperature.  相似文献   
4.
Xinwen Ma 《中国物理 B》2022,31(9):93401-093401
The research progresses on the investigations of atomic structure and collision dynamics with highly charged ions based on the heavy ion storage rings and electron ion beam traps in recent 20 years are reviewed. The structure part covers test of quantum electrodynamics and electron correlation in strong Coulomb field studied through dielectronic recombination spectroscopy and VUV/x-ray spectroscopy. The collision dynamics part includes charge exchange dynamics in ion-atom collisions mainly in Bohr velocity region, ion-induced fragmentation mechanisms of molecules, hydrogen-bound and van de Waals bound clusters, interference, and phase information observed in ion-atom/molecule collisions. With this achievements, two aspects of theoretical studies related to low energy and relativistic energy collisions are presented. The applications of data relevant to key atomic processes like dielectronic recombination and charge exchanges involving highly charged ions are discussed. At the end of this review, some future prospects of research related to highly charged ions are proposed.  相似文献   
5.
Kai-Feng Yin 《中国物理 B》2022,31(11):110703-110703
Zero-field single-beam atomic magnetometers with transverse parametric modulation for ultra-weak magnetic field detection have attracted widespread attention recently. In this study, we present a comprehensive response model and propose a modification method of conventional first harmonic response by introducing the second harmonic correction. The proposed modification method gives improvement in dynamic range and reduction of linearity error. Additionally, our modification method shows suppression of response instability caused by optical intensity and frequency fluctuations. An atomic magnetometer with single-beam configuration is built to compare the performance between our proposed method and the conventional method. The results indicate that our method's magnetic field response signal achieves a 5-fold expansion of dynamic range from 2 nT to 10 nT, with the linearity error decreased from 5% to 1%. Under the fluctuations of 5% for optical intensity and ±15 GHz detuning of frequency, the proposed modification method maintains intensity-related instability less than 1% and frequency-related instability less than 8% while the conventional method suffers 15% and 38%, respectively. Our method is promising for future high-sensitive and long-term stable optically pumped atomic sensors.  相似文献   
6.
Herein, we propose a scheme for the realization of two-dimensional atomic localization in aλ-type three-level atomic medium such that the atom interacts with the two orthogonal standing-wave fields and a probe field. Because of the spatially dependent atom-field interaction, the information about the position of the atom can be obtained by monitoring the probe transmission spectra of the weak probe field for the first time. A single and double sharp localized peaks are observed in the one-wavelength domain. We have theoretically archived high-resolution and high-precision atomic localization within a region smaller thanλ/25×λ/25. The results may have potential applications in the field of nano-lithography and advance laser cooling technology.  相似文献   
7.
Let G be a finite group, H be a proper subgroup of G, and S be a unitary subring of C. The kernel of the restriction map S[Irr(G)] → S[Irr(H)] as a ring homomorphism is studied. As a corollary, the main result in [Isaacs, I. M. and Navarro, G., Injective restriction of characters, Arch. Math., 108, 2017, 437–439] is reproved.  相似文献   
8.
Let R be an associative unital ring and not necessarily commutative.We analyze conditions under which every n × n matrix A over R is expressible as a sum A =E1 +…+ Es + N of (commuting) idempotent matrices Ei and a nilpotent matrix N.  相似文献   
9.
Application of rotary tillage has been increased due to less tillage passes required, reduced draft, and greater efficiency through reduction in wheel slippage. Early failure of the bearing of tractor power take-off (PTO) shaft was observed in tractors of power range 30–35 horsepower during rotary tillage. An instrumentation setup involving an extended octagonal ring transducer (EORT) was developed and installed at the bottom of the bearing to measure the axial load and the vertical component of the radial load. The horizontal component of radial load was measured by strain gauges. Based on measured loads, the bearing life was assessed. Independent variables were: operating depth, number of blades, gear setting, engine speed, and tyre size. The average axial and radial loads varied from 786–3869 N, and 134–430 N, respectively. However, bearing experienced very high peak loads during each trial. The peak axial and radial loads was recorded between 1081–7534 N and 566–1794 N, respectively. The estimated bearing life based on peak loads was 171.98–28341.39 h. Based on the findings, it may be concluded that the average loads were not sufficient to cause quick failure of PTO bearing, rather sudden peak loads might be the root cause of early failure.  相似文献   
10.
介绍了一种使用钢环和碳纤维复合材料环共同预紧方式的两面顶超高压模具,该结构在全钢环两面顶模具的基础上,使用一层碳纤维复合材料环代替最外层钢环,得到了一种具有碳纤维复合材料环的超高压模具。这种设计避免了大直径钢环难以制造加工的问题,形成一种以钢环与复合材料环共同对压缸预紧的新型预紧方式。数值分析表明:该模具结构设计具有可行性,可以在一定程度上减小压缸的周向应力、最大剪切应力和等效应力。此外,对碳纤维复合材料环进行了失效判别。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号