Separation of lignosulfonate from its aqueous solution using supported liquid membrane

This paper presents an experimental and theoretical study on facilitated transport of lignosulfonate (LS) through a flat sheet supported liquid membrane using trioctylamine (TOA) as carrier and dichloroethane as diluent. The studies were carried out with various support materials and operating conditions (viz. carrier concentration, strip phase concentration, salt concentration, etc.) and their effects on the transport of LS. The results were analyzed to identify a suitable combination of support and operating condition that would yield best performance of the supported liquid membrane (SLM) in terms of fast and efficient transport of LS. The stability of the SLM was assessed in terms of loss of liquid from the pores of membrane support. The SLM is found to be stable till 10 h. Co-transport mechanism has been adopted in this work by using NaOH as the strip phase. It was observed that extraction of LS is increased with increase in concentration of NaOH up to a limiting value of 0.5 M NaOH. Difference of salt concentration between feed and strip phase considerably affect the separation process. The diffusional resistances of organic membrane (Δorg) and aqueous solution (Δaq) calculated from the permeation model, which is again a combination of three unique mechanisms viz., diffusion through a feed aqueous layer, a fast interfacial chemical reaction, and diffusion of carrier–complex through the organic membrane, are found to be 609.9 and 176.6 s cm⁻¹, respectively. The values of the diffusion coefficient in the membrane (D_org) and in the bulk organic phase (D_complex) are 1.67×10⁻⁹ and 6.68 × 10⁻⁸ m²s⁻¹, respectively. The extraction of LS is about 90%. Nearly 43% of LS can be recovered at optimum condition.     

Fleet algorithm for X-ray pulsar profile construction and TOA solution based on compressed sensing

X-ray pulse profile and time of arrival (TOA) are the two important physical quantities for pulsar navigation. With the standard and integrated X-ray pulse profiles modeled, X-ray pulse profile construction is studied and TOA is solved using compressed sensing (CS) technology. The observation matrix and waveform complete dictionary are mainly examined. A column vector-based matching pursuit algorithm is presented. The feasibility of obtaining X-ray pulse profile construction by compressed sensing technology is verified by numerical simulation. Compared with the X-ray pulse profile construction method based on epoch folding, the proposed method exhibits improved real-time performance, and its detection time for integrated X-ray pulse profile could be reduced by one order of magnitude. This proposed method can also solve for TOA solution and construct the X-ray pulse profile simultaneously, which is essential to improve pulsar navigation efficiency.     

明胶-海藻酸钙复合膜胶囊萃取Cr2O72-的传质动力学研究

采用胶囊化技术制备三辛胺(TOA)的明胶-海藻酸钙复合膜胶囊,考察其在硫酸介质中萃取Cr2O72-的传质动力学．通过对渗透系数的测定,得出了适于微胶囊萃取的最佳条件:海藻酸钠质量浓度为0.7％,明胶质量浓度为5％-6％,V水／V油=3 :2。     

面向低强度无线网络信号接收谱参数估计研究

针对以北斗卫星导航信号为代表的亚纳秒级的低强度无线网络信号在定位中难以获取精确时间估计及角度估计,且易受环境噪声影响,使其定位精度不高等难题,本文提出了基于亚纳秒级的低强度无线网络信号接收谱参数估计方法。首先通过抽样方式,将发射信号抽样为多维独立子信号并独立建模,通过构造噪声空间与子信号空间在对应列向量正交化的基础上精确获取TOA估计;随后利用复数域映射,在获取TOA估计基础上采取比对方式精确地获取DOA估计。最后对本文参数估计方法进行了精度分析。测试数据显示：与 PM算法、ESPRIT算法相比,本文技术在TOA及DOA估计上更为精确;同时在信号强度低且背景噪声干扰严重的情况下,本文方法仍可有效的维持参数估计精度。     

Simultaneous separation of mercury and lignosulfonate from aqueous solution using supported liquid membrane

This paper presents an experimental investigation on facilitated and simultaneous transport of mercury and lignosulfonate (LS) through a flat sheet supported liquid membrane (SLM) having Nylon 6,6 as support, trioctylamine (TOA) as carrier and dichloroethane as solvent. The experiments were performed at various operating conditions such as strip phase concentration, feed pH, carrier concentration and feed concentration to find the best set of parameters that would yield the maximum separation of pure mercury as well as its mixture with LS. The experiments were performed in co-transport mode using NaOH as the strip phase. It was observed that extraction of mercury as well as its mixture increases with increase in concentration of NaOH up to a certain limit 0.1 M NaOH in case of pure solution and 0.2 M NaOH in case of mixture). Feed phase pH significantly affects the mercury separation process. However, initial feed concentration does not affect the extraction process appreciably. Separation of mixture of mercury and LS behaves in a similar way as their pure solution; however the extraction is low in comparison to pure solution. The extraction of mercury from its pure solution is about 81% in 1 h. The extraction of mercury and LS from their mixture is about 52.6% and 50.2%, respectively at optimum condition and in a period of 2 h.     

Study on autonomous navigation based on pulsar timing model

The basic principle of pulsar timing model was introduced, and the general relativistic corrections were analyzed when pulse time of arrival (TOA) was transferred to coordinate TOA at the Solar System Barycentre. Based on the shifting, an iterative method of autonomous position determination for spacecraft was developed. Accordingly, the linear form of the position offset equation was evolved. Using the initial estimated value of spacecraft’s position as the input of pulsar timing equation, through calculation of the offset between measured or transferred and predicted TOA, the position offset can be solved by Least Squares. At last, the main error sources including modeling error and parameters error were discussed. Supported by the National Defence Laboratory Foundation of China (Grant No. 9140C3601010901) and Science Foundation of Shaanxi Province (Grant No. 2007F12) and the Technology Specialism Foundation of Shaanxi Education Department of Shaanxi Province (Grant No. 07JK332), and the Innovative Research Plan of Xi’an University of Technology (Grant No. 105-210714)     

Teil 2. Untersuchungen zur Extraktionskinetik

Die Kinetik der Extraktion von Salpetersäure durch TOA wird in einer Rührzelle mil definierter, ebener Phasengrenzfläche untersucht. Die theoretischen Beziehungen für die Auswertung der Experimente werden abgeleitet sowie die für die Interpretation der Ergebnisse notwendigen Betrachtungen zum Problem des Stoffübergangs mit chemischer Reaktion durchgefūhrt. Der Stoffübergang wurde mit zwei Testsystemen ohne chemische Reaktion und im System HSO₃/TOA in Tetra untersucht. Die Ergebnisse zeigen, duß der Hauptstoffübergangswiderstand in der organischen Phase liegt. In der wäßrigen Phase findet eine langsame Reaktion statt, die in Extraktoren mit hoher Turbulenz und großer Phasengrenzfläche die Extraktionsgeschwindigkeit begrenzt. Die Mindestverweilzeit des Gemisches in einer Trennstufe derartiger Extraktoren kann auf Grund der Meßergebnisse abgeschätzt werden.     

一种基于自相关的激光脉冲编码信号解码方法

激光脉冲编码是半主动激光制导武器采用的一种抗干扰措施,为满足半主动激光制导武器光电对抗的需要,以激光信号的脉冲到达时间(TOA)为参数,依据激光脉冲编码信号的时间相关性,提出了一种通过首先对由脉冲到达时间组成的脉冲到达时间序列作自相关处理,计算出信号的重复周期,然后再在一个信号周期内,通过确定脉冲重复间隔的时间值、个数和位序来鉴别信号码型,从而实现信号解码的方法。阐述了该解码方法的原理及实现。原理实验和数字仿真实验证明,对于当前半主动激光制导武器采用的大多数激光脉冲编码信号,采用该解码方法,一般在4个信号周期时间内就能实现解码。     

基于多元线性回归分析和Chan算法的三维精确定位研究

基于无线通信基站的室内三维定位问题主要是在已知TOA和基站三维信息的情况计算出终端的位置信息,实际上就是求解方程组中的未知数.首先建立通用模型和算法求解出终端的定位,接着通过优化得到使用尽量少的基站数目实现近似最优精度的定位,然后利用提出的算法实现终端移动轨迹的二维定位,最后结合实际情况,考虑了基站的有效测量距离并设计了有效基站识别算法对问题进行了分析.     

风速对声点阵立靶系统建模及算法的影响研究

室外靶场中点阵声学立靶应用时风对报靶精度有较大影响。使用几何方法推导了激波到达时间、矢量风速、弹丸速度和入射角、着靶位置之间的模型方程,然后将激波到达时间显式表述。该显式表达式可简化非线性最小二乘法求解并加速了收敛性,可同时求得弹丸着靶位置以及速度、入射角,可适用于不同的传感器阵列样式。通过仿真给出了风速对报靶精度影响的误差图。