A Closed‐Loop Control Strategy for Producing Nitrile Rubber of Uniform Chemical Composition in a Semibatch Reactor: A Simulation Study

To improve the quality of industrial nitrile rubbers, the copolymer chemical composition, p_A(t), should ideally be kept constant along the reaction. This work proposes a closed‐loop control strategy for the semibatch operation of the reactor with the aim of regulating p_A(t) within a reduced range of variability. The proposed strategy is evaluated by simulating a mathematical model of the process. To this effect, a simplified mathematical model of the reaction is first derived and then utilized to obtain a suboptimal control law and a soft‐sensor that estimates the polymerization rates. The suboptimal control law is compensated by adding a term proportional to errors in p_A(t). The simulated example considers the production of the low‐composition AJLT grade, with the copolymerization reaction represented by a detailed mathematical model adjusted to an industrial plant. Due to the high performance of the soft‐sensor, the simulation results suggest that the proposed closed‐loop strategy is efficient to adequately regulate p_A(t) in spite of structural and parametric uncertainties, while other quality variables remained practically unaffected.     

级联光栅结合Sagnac环的可调谐光纤激光器

提出并验证了一种单-双波长可调谐掺铒光纤激光器。利用级联光纤布拉格光栅(Cascaded Fiber Bragg gratings,Cascaded FBGs)结合Sagnac环结构所产生的复合滤波效应,实现较高精细度滤波,并通过调节环内偏振控制器(Polarization Controller,PC),引入双折射效应,得到波长可调谐的光纤激光器。基于耦合模理论并使用传输矩阵法对该结构的传输特性进行了分析,在此基础上搭建实验系统,验证了理论分析的正确性。实验结果表明:通过调节PC,激光器输出激光的波长范围约为1 555.644～1 556.112 nm,双波长间隔的可调范围约为0.108～0.452 nm,单-双波长的边模抑制比(SMSR)均高于40 dB;在稳定性测试中,输出单-双波长激光的波长最大漂移量小于0.008 nm。该方法具有结构简单、调谐方便、易于实现且精细度较高的优点,可应用于密集波分复用及全光通信系统等领域。     

表面效应对铁<100>间隙型位错环的影响

在材料辐照损伤过程中,间隙型位错环的形成及动力学行为严重影响材料在辐照条件下的服役行为.在常用的以体心立方铁为基的合金材料中,1/2<111>和<100>是两种主要的位错环,其对辐照损伤的影响一直都是核材料领域研究的热点之一.在之前的研究中,人们对{111}面与单个1/2<111>位错环的相互作用进行了深入研究,发现表面对位错环性质确实有重要的影响.采用分子动力学方法,在原子尺度详细研究了另一个重要的表面铁{100}面对<100>间隙型位错环动力学过程的影响.模拟发现位错环伯格斯矢量与表面法线方向的关系、距表面的深度、位错环之间的相互作用以及温度等,都对位错环与表面的相互作用产生重要影响,其中,表面作用下的伯格斯矢量的演化以及<100>位错环在此过程中的一维运动首次被发现.基于这些模拟结果,就<100>位错环对表面辐照损伤结构的影响进行详细地研究,给出<100>位错环对表面凹凸结构的贡献,这些结果为理解辐照过程中材料表面的演化提供一种可能的解释.     

一种超导重力仪磁悬浮力的等效计算

为实现超导重力仪磁悬浮力的精确计算,以GWR型超导重力仪为模型基础,采用有限元的思想,将超导球表面电流理想化为多个等高共轴电流环,计算出各个电流环与超导线圈的作用力,求和得到线圈与超导球间的磁悬浮力。利用MATLAB完成计算程序实现,通过改变下线圈电流和上、下线圈电流比,获得满足一定条件的磁悬浮力及其梯度。选取合适的模型参数,计算出线圈对质量为m=4.069 g超导球的磁悬浮力大小为:Ftotal=3.988×10^-2N,磁悬浮力梯度为:-9.699×10^-3N/m,此时悬浮力梯度合适,满足系统稳定性和灵敏度的要求。     

Polarization-enhanced bulk photovoltaic effect of BiFeO3 epitaxial film under standard solar illumination

In this Letter, we report the polarization-enhanced bulk photovoltaic effect (BPV) in pristine BiFeO₃ (BFO) epitaxial film under standard 1 sun AM 1.5 G illumination. High-quality epitaxial BFO films are grown on (001)-oriented niobium doped-SrTiO₃ substrates by pulsed laser deposition. The best BFO film based photovoltaic device achieves a power conversion efficiency of 0.0062% under standard illumination. Besides, it is found that the number of bipolar pulses plays a key role in improving the short-circuit current density and open-circuit voltage. These results are beneficial for further understanding of physical origin of the photovoltaic properties in ferroelectric oxides.     

Heat transfer from a vertical tube bundle under natural circulation conditions

A rectangular loop (thermosyphon) was used to measure the average heat transfer coefficients for water at atmospheric pressure under natural circulation conditions. A twenty-one tube bundle with tubes 1.65 m long and 9.55 mm in diameter, and a pitch-to-diameter ratio of 1.33, was used as a test heat exchanger in one of the vertical legs of the loop. A natural circulation flow in the loop developed due to buoyancy differences of the fluid in its two vertical legs. Flow visualization experiments were performed to determine the flow regimes associated with natural circulation flow longitudinal to a tube bundle. Empirical correlations for the average Nusselt number have been developed and are reported. Grid spacers arranged on tube bundles were shown to enhance heat transfer, especially for laminar flow, without any noticeable increase in pressure drop.     

A Multibody Loop Constraints Approach for Modelling Cam/Follower Devices

This paper proposes a formulation for modelling mechanisms witha cam/follower type of contact using a multibody approach in relativecoordinates. The proposed approach is inspired from the wheel/railcontact model developed by Fisette and Samin but, in the present case,possible intermittent contact between the cam and the follower isconsidered, for generality purposes.Loop kinematicconstraints are introduced to satisfy tangent and punctual contact aslong as the bodies lean against each other. The effective presence (ornot) of the contact is governed by the sign of the normal constraintforce which can be computed thanks to the Lagrange multiplierstechnique.The above-mentioned option to kinematicallyconstraint the bodies in their contact phase unavoidably leads to ashift from one model to another when a contact disappears (or,conversely, reappears). Indeed, this increases (or decreases) the numberof degrees of freedom of the current system. The control of the variablepartitioning is thus absolutely necessary and is all the more complex sothat practical applications can contain several pairs of bodies inintermittent contact.Illustrative examples are proposed: acomparison with another multibody formalism, an experimental validationand the modelling of universal wheels of mobile robots which representsa quite original application of the proposed formulation.     

超声波的光外差接收

激光接收超声是一种非接触式的超声接收技术，它在超声无损评估及检测领域有重要的应用。本文设计研制了激光外差干涉接收超声的实验系统，该系统由声光调制器产生光频的频移，锁相环进行位相解调。文中重点讨论：（１）在光学部分，外差干涉光路空间准直性对信噪比的影响。（２）在信号处理电路部分，锁相环电路特性分析及其参数确定     

随机压电智能桁架结构闭环控制概率动力响应分析

针对随机压电智能桁架结构研究了基于概率的结构闭环控制系统动力响应分析模型与方法．考虑结构的物理参数、几何尺寸、外荷载幅值以及闭环系统控制力同时具有随机性时，利用振型迭加法导出了结构动力响应随机变量的数字特征计算表达式．通过算例考察了智能结构物理参数、几何尺寸、外荷载幅值以及控制力的随机性对结构闭环控制系统动力响应的影响，并获得了若干有意义的结论．