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1.
The effects of air sparging (0–16 L min−1) and mechanical mixing (0–400 rpm) on enhancing the sonochemical degradation of rhodamine B (RhB) was investigated using a 28 kHz sonoreactor. The degradation of RhB followed pseudo first-order kinetics, where sparging or mixing induced a large sonochemical enhancement. The kinetic constant varied in three stages (gradually increased → increased exponentially → decreased slightly) as the rate of sparging or mixing increased, where the stages were similar for both processes. The highest sonochemical activity was obtained with sparging at 8 L min−1 or mixing at 200 rpm, where the standing wave field was significantly deformed by sparging and mixing, respectively. The cavitational oxidation activity was concentrated at the bottom of the sonicator when higher sparging or mixing rates were employed. Therefore, the large enhancement in the sonochemical oxidation was attributed mainly to the direct disturbance of the ultrasound transmission and the resulting change in the cavitation-active zone in this study. The effect of the position of air sparging and mixing was investigated. The indirect inhibition of the ultrasound transmission resulted in less enhancement of the sonochemical activity. Moreover, the effect of various sparging gases including air, N2, O2, Ar, CO2, and an Ar/O2 (8:2) mixture was compared, where all gases except CO2 induced an enhancement in the sonochemical activity, irrespective of the concentration of dissolved oxygen. The highest activity was obtained with the Ar/O2 (8:2) mixture. Therefore, it was revealed that the sonochemical oxidation activity could be further enhanced by applying gas sparging using the optimal gas.  相似文献   
2.
研究了温度场中非保守功能梯度材料(FGM)圆板的非线性力学行为。基于经典板理论,推导了受非保守力作用的FGM圆板在温度场中的控制微分方程。采用打靶法分析了由陶瓷二氧化锆和金属钛合金两相材料组成的非保守FGM圆板在均匀和非均匀升温场中的非线性力学行为。给出了不同均匀升温和非均匀升温场下,FGM圆板在非保守载荷作用下的平衡路径和平衡构形。分析并讨论了均匀和非均匀升温、材料梯度指数对非保守圆板过屈曲和弯曲行为的影响。结果表明:温度场中,非保守FGM圆板发生弯曲而纯陶瓷圆板会发生过屈曲行为;当梯度指数p=2,非保守载荷q=52时,均匀升温场中非保守圆板的变形大于非均匀升温场中非保守圆板的变形。  相似文献   
3.
基于Euler-Bernoulli梁理论的经典纤维模型忽略了剪切变形给截面带来的影响,为了得到更加精确的梁单元模型,该文基于考虑剪切效应的纤维梁单元,根据Timoshenko梁理论,推导了该纤维梁单元的刚度矩阵,并结合弹塑性增量理论,同时考虑了几何非线性和材料非线性的双重影响,建立了压弯剪复杂应力状态下结构非线性有限元分析理论。该文最后利用MATLAB编制了相关计算程序,对钢筋混凝土和矩形钢管混凝土的典型压弯剪构件进行有限元数值模拟,得到了构件的荷载-位移非线性全过程曲线。典型算例的验证结果表明:该文建立的非线性有限元分析理论是通用、可行和正确的。  相似文献   
4.
The recent developments in the application of single-crystalline (SC) cathode materials in solid-state batteries are discussed in this mini-review. The characteristics of SC and poly-crystalline (PC) cathode materials are explored, with emphasis on the kinetic and mechanical properties. The critical factors influencing their performance in liquid electrolyte and solid-state battery cells are investigated. Finally, the advantages and disadvantages of both morphologies are discussed and considerations to ensure a fair comparison between SC and PC cathodes in different systems are raised.  相似文献   
5.
The influence of ultrasound treatment (US) on cellular damage of olive leaf tissue was studied. Mechanical damage and thermal effect of US were characterized. The level of tissue damage was defined by the diffusivity disintegration index ZD based on the diffusivity of solutes extracted from olive leaves differently treated. The Arrhenius form using the temperature dependences of the thermal treatment time within the temperature interval 20–90 °C was observed for the thermal process. The corresponding activation energy ΔUT was estimated as 57 kJ/mol. The temperature dependences of electrical conductivity were measured for extracts of intact and maximally treated olive leaves. Then the diffusivity disintegration index ZD and total phenolic compounds recovery for three studied US powers were calculated (100, 200, and 400 W). The results evidenced that the mechanically stimulated damage in olive leaf tissue can occur even at a low US power of 100 W if treatment time is long enough (t = 3.5 h). The US treatment noticeably accelerated the diffusion process mechanically in addition to its thermal effect. Trials in aqueous solution revealed the dependence of polyphenols extraction on damage level with respect to the US power applied.  相似文献   
6.
以三苯胺为单体, 无水三氯化铁为催化剂, 二甲醇缩甲醛为外交联剂, 通过机械球磨不同比例的三苯胺、 三氯化铁和二甲醇缩甲醛, 合成了PAF-106s(PAF-106a~PAF-106c, PAF: porous aromatic framework). 红外光谱、 元素分析、 X射线光电子能谱和固体核磁共振波谱等表征结果证明发生了聚合反应. 氮气吸附结果表明, 三苯胺、 三氯化铁和二甲醇缩甲醛的比例影响PAF-106s的多孔性能. 三氯化铁和三苯胺摩尔比从3∶1增加到12∶1时, PAF-106c的BET比表面积从PAF-106a的135 m2/g增加到280 m2/g. 引入二甲醇缩甲醛后, PAF- 106d~PAF-106g的BET比表面积随三氯化铁和二甲醇缩甲醛摩尔比的增加而逐渐降低. 在273和298 K下, 测试了PAF-106c的C2烃吸附性能, 并采用理想吸附溶液理论计算了C2H2/C2H4和C2H6/C2H4分离比.  相似文献   
7.
This review critically evaluates the plastic accumulation challenges and their environmental (primarily) and human (secondarily) impacts. It also emphasizes on their degradation and fragmentation phenomena under marine conditions. In addition, it takes into account the leachability of the various chemical substances (additives) embedded in plastic products to improve their polymeric properties and extend their life. Regardless of their effectiveness in enhancing the polymeric function of plastic products, these additives can potentially contaminate air, soil, food, and water. Several findings have shown that, regardless of their types and sizes, plastics can be degraded and/or fragmented under marine conditions. Therefore, the estimation of fragmentation and degradation rates via a reliable developed model is required to better understand the marine environmental status. The main parameter, which is responsible for initiating the fragmentation of plastics, is sunlight/UV radiation. Yet, UV- radiation alone is not enough to fragment some plastic polymer types under marine conditions, additional factors are needed such as mechanical abrasion. It should be also mentioned that most current studies on plastic degradation and fragmentation centered on the primary stages of degradation. Thus, further studies are needed to better understand these phenomena and to identify their fate and environmental effects.  相似文献   
8.
This paper deals with the asymptotic behavior of solutions to a class of non-autonomous Lamé systems modeling the physical phenomenon of isotropic elasticity. The main feature of this model is that the nonlinearity can be decomposed into a subcritical part and a critical one. We first show that the system generates a non-autonomous dynamical system, and then prove that the system has a minimal universe pullback attractor. The upper-semicontinuity of these pullback attractors is also established as the perturbation parameter of the external force tends to zero. The quasi-stability ideas developed by Chueshov and Lasiecka (2010, 2008, 2015) are used to prove the pullback asymptotic compactness of the solutions in order to overcome the difficulty caused by the critical growthness of the nonlinearity.  相似文献   
9.

The wavelet multiresolution interpolation for continuous functions defined on a finite interval is developed in this study by using a simple alternative of transformation matrix. The wavelet multiresolution interpolation Galerkin method that applies this interpolation to represent the unknown function and nonlinear terms independently is proposed to solve the boundary value problems with the mixed Dirichlet-Robin boundary conditions and various nonlinearities, including transcendental ones, in which the discretization process is as simple as that in solving linear problems, and only common two-term connection coefficients are needed. All matrices are independent of unknown node values and lead to high efficiency in the calculation of the residual and Jacobian matrices needed in Newton’s method, which does not require numerical integration in the resulting nonlinear discrete system. The validity of the proposed method is examined through several nonlinear problems with interior or boundary layers. The results demonstrate that the proposed wavelet method shows excellent accuracy and stability against nonuniform grids, and high resolution of localized steep gradients can be achieved by using local refined multiresolution grids. In addition, Newton’s method converges rapidly in solving the nonlinear discrete system created by the proposed wavelet method, including the initial guess far from real solutions.

  相似文献   
10.
In the paper, we try to study the mechanism of the existence of Gaussian waves in high degree logarithmic nonlinear wave motions. We first construct two model equations which include the high order dispersion and a second degree logarithmic nonlinearity. And then we prove that the Gaussian waves can exist for high degree logarithmic nonlinear wave equations if the balance between the dispersion and logarithmic nonlinearity is kept. Our mathematical tool is the logarithmic trial equation method.  相似文献   
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