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1.
Four mononuclear copper(II) and zinc(II) complexes were synthesized by the reaction of copper and zinc salts with 3,4-dichlorophenylactic acid, 2-bromophenylactic acid, biphenylacetic acid (O-donor ligand) and bipyridine (N-donor ligands) having the general formulae [(L)2Cu(bp)(H2O)] ( 1 ), [(BpA)2Cu(bp)] ( 2 ), [(L)2Zn(bp)(H2O)] ( 3 ) and [(L*)2Zn(bp)] ( 4 ) (L = 3,4-dichlorophenylacetate, L* = 2-bromophenylacetate bp = bipyridine, and BpA = biphenylacetate). Structures of all compounds were characterized through FT-IR spectroscopy and X-ray diffraction analysis. FT-IR spectra of all complexes confirmed the binding mode of Cu-O and Zn-O. XRD data revealed that complexes 1 – 3 exhibited distorted octahedral arrangement, whereas complex 4 has a distorted tetrahedral environment. Micellization behavior was examined with anionic surfactant (SDS) by conductance measurement as well as absorption spectral analysis. DNA binding study was assessed through viscosity measurement and UV/Vis spectrophotometry. DPPH free radical scavenging assay was measured by UV/Vis spectrophotometry. The results showed nice biological potential of all the complexes. 相似文献
2.
基于拓扑描述函数的连续体结构拓扑优化方法 总被引:14,自引:0,他引:14
提出了一种利用拓扑描述函数(TDF)作为拓扑设计变量求解连续体结构拓扑优化问题
的新方法. 优化问题的目标函数是结构的整体柔顺性,约束条件为对于可利用材料的体积限
制. 这种方法不仅可以消除拓扑优化中经常出现的棋盘格式等数值不稳定现象,而且能够有
效地抑制传统算法处理此类优化问题时所引发的边界扩散效应. 与其它的基于水平集描述函
数的拓扑优化方法相比,所提出的算法不仅无需求解控制水平集函数演化的双曲守恒方
程,而且合理地考虑了目标函数的拓扑导数信息,因而使得算法的计算效率有了显著的提高. 相似文献
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从4种典型裂纹情况的特征展开式出发,运用其微分性质和伪正交性质得到了含有高阶奇异项的J积分表达式.它们是通用的显函数表征的.本研究支持了Hui和Ruina的杰出研究和重要观点,即高阶奇异项和非奇异项一样在小范围屈服描述中扮演着重要角色.研究表明,常规柔度方法确定的J积分已隐含了高阶奇异项的贡献.断裂准则有可能由含高阶奇异项和非奇异项的J积分的临界值来描述 相似文献
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7.
For the analysis of ultrasonic cavitation erosion on the surface of materials, the ultrasonic cavitation erosion experiments for AlCu4Mg1 and Ti6Al4V were carried out, and the changes of surface topography, surface roughness, and Vickers hardness were explored. Cavitation pits gradually expand and deepen with the increase of experiment time, and Ti6Al4V is more difficult to erode by cavitation than AlCu4Mg1. After experiments, the cavitation damage characteristics such as the single pit, the rainbow ring area, the fisheye pit, and some small pits were observed, which can be considered to be induced by a single micro-jet impact, ablation effect caused by the high temperature, micro-jet impingement with a sharp angle, and multibeam micro-jets coupling impact or negative pressure in the local area produced by micro-jet impact, respectively. The surface roughness and Vickers hardness of the material increase slowly after rapid growth at different points in time as the experiment time increases. With the increase of the ultrasonic amplitude, both of them first increase and then decrease after the ultrasonic amplitude is greater than 10.8 μm. The increases in surface roughness and Vickers hardness tend to decrease as the viscosity coefficient increases. Ultrasonic cavitation can cause submicron surface roughness and increase surface hardness by 20.36%, so it can be used as a surface treatment method. 相似文献
8.
Fuzzy ontology representation using OWL 2 总被引:3,自引:0,他引:3
Fernando Bobillo Umberto Straccia 《International Journal of Approximate Reasoning》2011,52(7):1073-1094
The need to deal with vague information in Semantic Web languages is rising in importance and, thus, calls for a standard way to represent such information. We may address this issue by either extending current Semantic Web languages to cope with vagueness, or by providing a procedure to represent such information within current standard languages and tools. In this work, we follow the latter approach, by identifying the syntactic differences that a fuzzy ontology language has to cope with, and by proposing a concrete methodology to represent fuzzy ontologies using OWL 2 annotation properties. We also report on some prototypical implementations: a plug-in to edit fuzzy ontologies using OWL 2 annotations and some parsers that translate fuzzy ontologies represented using our methodology into the languages supported by some reasoners. 相似文献
9.
引入了拓扑覆盖的概念,并结合最小描述元对有限论域上的拓扑覆盖加于研究,得出了拓扑覆盖的最简覆盖和基与最小描述元之间的关系.介绍了在基于有限论域U上的覆盖,构造U上的一个拓扑的方法.并且在最小描述元的基础上将划分下的粗糙隶属函数推广至一般覆盖下的粗糙隶属函数,而后介绍了其相关运用. 相似文献
10.
Bergenia (Saxifragaceae) genus is native to central Asia and encompasses 32 known species. Among these, nine are of pharmacological relevance. In the Indian system of traditional medicine (Ayurveda), “Pashanabheda” (stone breaker) is an elite drug formulation obtained from the rhizomes of B. ligulata. Bergenia species also possess several other biological activities like diuretic, antidiabetic, antitussive, insecticidal, anti-inflammatory, antipyretic, anti-bradykinin, antiviral, antibacterial, antimalarial, hepatoprotective, antiulcer, anticancer, antioxidant, antiobesity, and adaptogenic. This review provides explicit information on the traditional uses, phytochemistry, and pharmacological significance of the genus Bergenia. The extant literature concerned was systematically collected from various databases, weblinks, blogs, books, and theses to select 174 references for detailed analysis. To date, 152 chemical constituents have been identified and characterized from the genus Bergenia that belong to the chemical classes of polyphenols, phenolic-glycosides, lactones, quinones, sterols, tannins, terpenes, and others. B. crassifolia alone possesses 104 bioactive compounds. Meticulous pharmacological and phytochemical studies on Bergenia species and its conservation could yield more reliable compounds and products of pharmacological significance for better healthcare. 相似文献