全文获取类型
收费全文 | 43505篇 |
免费 | 3470篇 |
国内免费 | 2853篇 |
专业分类
化学 | 19929篇 |
晶体学 | 278篇 |
力学 | 6980篇 |
综合类 | 279篇 |
数学 | 10039篇 |
物理学 | 12323篇 |
出版年
2023年 | 350篇 |
2022年 | 587篇 |
2021年 | 1333篇 |
2020年 | 1103篇 |
2019年 | 1045篇 |
2018年 | 769篇 |
2017年 | 987篇 |
2016年 | 1210篇 |
2015年 | 1170篇 |
2014年 | 1666篇 |
2013年 | 2938篇 |
2012年 | 1973篇 |
2011年 | 2295篇 |
2010年 | 1991篇 |
2009年 | 2680篇 |
2008年 | 2706篇 |
2007年 | 2948篇 |
2006年 | 2389篇 |
2005年 | 1692篇 |
2004年 | 1398篇 |
2003年 | 1583篇 |
2002年 | 1451篇 |
2001年 | 1383篇 |
2000年 | 1054篇 |
1999年 | 868篇 |
1998年 | 800篇 |
1997年 | 682篇 |
1996年 | 708篇 |
1995年 | 695篇 |
1994年 | 621篇 |
1993年 | 631篇 |
1992年 | 523篇 |
1991年 | 374篇 |
1990年 | 284篇 |
1989年 | 237篇 |
1988年 | 264篇 |
1987年 | 267篇 |
1986年 | 270篇 |
1985年 | 367篇 |
1984年 | 279篇 |
1983年 | 162篇 |
1982年 | 346篇 |
1981年 | 503篇 |
1980年 | 428篇 |
1979年 | 480篇 |
1978年 | 376篇 |
1977年 | 282篇 |
1976年 | 241篇 |
1974年 | 75篇 |
1973年 | 153篇 |
排序方式: 共有10000条查询结果,搜索用时 20 毫秒
1.
二维材料MXene纳米片由于具有较大的比表面积和较高的电子迁移率而受到广泛的关注。本文采用基于密度泛函理论的第一性原理计算,对单层MXene纳米片Ti2N电磁特性的过渡金属(Sc、V、Zr)掺杂效应进行了系统研究。结果表明,所有过渡金属掺杂体系结合能均为负值,结构均稳定;其中Ti2N-Sc体系的形成能为-2.242 eV,结构更易形成,且保持稳定;掺杂后Ti2N-Sc、Ti2N-Zr体系磁矩增大;此外,Ti2N-Sc体系中保留了较高的自旋极化率,达到84.9%,可预测该体系在自旋电子学中具有潜在的应用价值。 相似文献
2.
Applied Mathematics and Mechanics - Mechanical models of residually stressed fibre-reinforced solids, which do not resist bending, have been developed in the literature. However, in some residually... 相似文献
3.
Dariusz Marek Adam Domaski Joanna Domaska Jakub Szygua Tadeusz Czachrski Jerzy Klamka 《Entropy (Basel, Switzerland)》2021,23(5)
In this article, a way to employ the diffusion approximation to model interplay between TCP and UDP flows is presented. In order to control traffic congestion, an environment of IP routers applying AQM (Active Queue Management) algorithms has been introduced. Furthermore, the impact of the fractional controller and its parameters on the transport protocols is investigated. The controller has been elaborated in accordance with the control theory. The TCP and UDP flows are transmitted simultaneously and are mutually independent. Only the TCP is controlled by the AQM algorithm. Our diffusion model allows a single TCP or UDP flow to start or end at any time, which distinguishes it from those previously described in the literature. 相似文献
4.
《中国物理 B》2021,30(5):56501-056501
Thermal expansion control is always an obstructive factor and challenging in high precision engineering field. Here,the negative thermal expansion of Nb F_3 and Nb OF_2 was predicted by first-principles calculation with density functional theory and the quasi-harmonic approximation(QHA). We studied the total charge density, thermal vibration, and lattice dynamic to investigate the thermal expansion mechanism. We found that the presence of O induced the relatively strong covalent bond in Nb OF_2, thus weakening the transverse vibration of F and O in Nb OF_2, compared with the case of Nb F_3.In this study, we proposed a way to tailor negative thermal expansion of metal fluorides by introducing the oxygen atoms.The present work not only predicts two NTE compounds, but also provides an insight on thermal expansion control by designing chemical bond type. 相似文献
5.
6.
本文用水热法制备了正交晶系的纳米球状结构的二氧化锡和正交晶系的由片状聚集成球状结构的钨酸铋,并且对二者进行了复合,制备出了二氧化锡/钨酸铋复合光催化材料。采用X射线衍射(XRD)、扫描电子显微镜(SEM)、比表面积测试仪(BET)、紫外可见分光光度计等技术对复合样品的结构、形貌、比表面积、孔容孔径和光学性质进行了表征。用碘钨灯模拟太阳光,分别以二氧化锡、钨酸铋和二氧化锡/钨酸铋复合材料为催化剂降解罗丹明B(RhB),研究所制备的二氧化锡/钨酸铋复合材料的光催化活性。光催化90 min时二氧化锡、钨酸铋和二氧化锡/钨酸铋对罗丹明B的降解率分别是9%、22%和30%。实验结果表明,在可见光下,二氧化锡/钨酸铋复合材料的光催化活性要高于单一的二氧化锡和钨酸铋。 相似文献
7.
Chinese Annals of Mathematics, Series B - In the present article, the authors find and establish stability of multiplier ideal sheaves, which is more general than strong openness. 相似文献
8.
基于一种新的各向异性修正偶应力理论,建立了碳纳米管增强复合材料功能梯度板的自由振动模型。该模型能够描述尺度效应,且仅包含一个尺度参数。基于一阶剪切变形理论和哈密顿原理推演了板的运动微分方程,并以四边简支板为例给出了自振频率的解析解。讨论了板的几何尺寸、碳纳米管体分比含量和分布方式等因素对板的自振频率的影响。结果表明,本文模型所预测的板的自振基频总是高于经典弹性理论的Mindlin板模型的预测结果,两者间的差异在板的几何尺寸接近尺度参数的值时非常明显,且会随着板的几何尺寸的增大而逐渐消失。 相似文献
9.
This paper investigates the pullback asymptotic behaviors for the non-autonomous micropolar fluid flows in 2D bounded domains. We use the energy method, combining with some important properties of the generated processes, to prove the existence of pullback exponential attractors and global pullback attractors and show that they both with finite fractal dimension. Further, we give the relationship between global pullback attractors and pullback exponential attractors. 相似文献
10.
《Wave Motion》2018
Standing surface acoustic wave (SSAW) based microfluidic devices have shown great promise toward fluid and particle manipulation applications in medicine, chemistry, and biotechnology. In this article, we present an analytical model for investigating continuous manipulation of particles (both synthetic and biological) within electroosmotic flow of non-Newtonian bio-fluids in a microfluidic channel under the influence of standing surface acoustic waves (SSAW). The particles are injected along the center of channel into the electroosmotically driven flow of power-law fluids, wherein their transport through the SSAW region is dictated by the hydrodynamic, electrophoretic, and acoustic forces. We first present a mathematical model to analyze the characteristics of electroosmotic flow of non-Newtonian power-law fluids in a hydrophobic slit microchannel. Next, we investigate the trajectories of particles in the flow field due to the combined effect of electroosmotic, electrophoretic, and acoustophoretic forcing mechanisms. The effect of key parameters such as particle size, their physical properties, input power, flow rate, and flow behavior index on the particle trajectories is examined while including the effect of the channel walls. The presented model delineates the methodologies of improving SSAW-based particle separation technology by considering the fluid rheology as well as the surface properties of the channel walls. Therefore, we believe that this model can serve as an efficient tool for device design and quick optimizations to explore novel applications concerning the integration of electroosmotic flows with acoustofluidic technologies. 相似文献