无机与有机混合物的含量分析——以探究鼻可乐成分为例

在化学实验课堂上,以生活中常见药品作为实验对象更能激发起学生对化学学习的兴趣。鼻可乐是一种常见的市售洗鼻剂,主要成分为氯化钠、柠檬酸与柠檬酸钠,是一种典型的无机物与有机物的混合体系。本文设计了对鼻可乐的组成进行定量分析的方法,并且通过实验验证其合理性,以期为鼻可乐成分分析实验进入高校分析化学实验课堂提供指导方法。学生通过该实验不仅能掌握恒重坩埚、沉淀滴定等实验基本操作方法,而且能更好地理解定量分析数据的方法。     

Accuracy and CPU time of JE-TLM,PLRC-TLM and CRC-TLM methods for plasma medium

The current density (JE), the piecewise linear recursive convolution (PLRC) and the constant convolution recursive (CRC) techniques are developed and integrated into the transmission line matrix (TLM) algorithm. A comparison of these three schemes according to the criteria of accuracy and CPU time is presented. Numerical experiments show that JE provides the most accurate solution and requires the least CPU time; PLRC is nearly as accurate but consumes more CPU time than CRC.     

A postscript on aggregate Farrell efficiencies

In this note we derive alternative weighting schemes that complement those of Färe and Zelenyuk (2003) for consistent aggregation of Farrell efficiencies when the technology exhibits (global) constant returns to scale.     

First stability eigenvalue characterization of CMC Hopf tori into Riemannian Killing submersions

We find out upper bounds for the first eigenvalue of the stability operator for compact constant mean curvature orientable surfaces immersed in a Riemannian Killing submersion. As a consequence, the strong stability of such surfaces is studied. We also characterize constant mean curvature Hopf tori as the only ones attaining the bound in certain cases.     

LIMITATIONS ON PRESCRIBING THE HOPF DIFFERENTIAL FOR MINIMAL SURFACES IN H3

ABSTRACT

The Hopf map from minimal surfaces in H ³ to holomorphic quadratic differentials on H ² is considered. Whether or not a given quadratic differential is in the image of this map is determined by the global existence/non-existence of solutions to a certain quasi-linear PDE. It is shown that this map is not surjective.     

On the K-stability of complete intersections in polarized manifolds

We consider the problem of existence of constant scalar curvature Kähler metrics on complete intersections of sections of vector bundles. In particular we give general formulas relating the Futaki invariant of such a manifold to the weight of sections defining it and to the Futaki invariant of the ambient manifold. As applications we give a new Mukai–Umemura–Tian like example of Fano 5-fold admitting no Kähler–Einstein metric, and a strong evidence of K-stability of complete intersections in Grassmannians.     

Quinone-recognition by Four-point Hydrogen Bonding in Porphyrin System Having Urea Moiety

5,15- cis -bis(Ureidophenyl)porphyrins have significant recognizing ability for p -benzoquinones through four-point hydrogen bonding. Although an unusual temperature-dependence of the complexation is observed with bis( N '-phenylureidophenyl) porphyrin, bis( N '-ethylureidophenyl)porphyrin shows a satisfactorily linear van't Hoff plot and recognizes an electron-rich p -benzoquinone such as tetramethyl- p -benzoquinone more effectively, which is ascribed to the large enthalpy change in the complex.     

Distinguishability of equivalent circuits containing CPEs: Part I. Theoretical part

Constant phase elements (CPEs) with impedance Z_CPE=1/(Qs^α_f) are widely used to explain electrochemical impedance spectroscopy (EIS) data. It has long been known that different circuits can explain EIS data in an equivalent manner because they exhibit identical impedance for all frequencies (two-terminal non-distinguishable (TTND) circuit). Equivalent circuits containing two CPEs are considered here. TTND circuits containing two CPEs become distinguishable, at least theoretically, if the CPE exponents are different. The experimental distinguishability of these circuits is discussed. The 12 transformation formulae between the four circuits containing two CPEs and two resistors are given for CPEs with equal exponents.     

Design of a curved surface constant force mechanism

A new curved surface constant force mechanism which mainly consists of a roller and a curved surface has been proposed. The magnitude and the direction of normal force caused by squeezing between the roller and the curved surface satisfy a certain relationship, thus the decomposed force of the normal force keeps constant in a certain direction all the times. According to the envelope theorem, the trajectory of the roller center and the profile of the curved surface are obtained by ignoring friction. Then, the influence of the friction is discussed in detail. In addition, the simulation is performed to verify the theoretical calculation. The simulation results show that the output force is relatively constant and the friction has little effect on the output force.