全文获取类型
收费全文 | 2912篇 |
免费 | 110篇 |
国内免费 | 691篇 |
专业分类
化学 | 3150篇 |
晶体学 | 36篇 |
力学 | 18篇 |
综合类 | 9篇 |
数学 | 13篇 |
物理学 | 487篇 |
出版年
2024年 | 2篇 |
2023年 | 47篇 |
2022年 | 56篇 |
2021年 | 69篇 |
2020年 | 78篇 |
2019年 | 80篇 |
2018年 | 79篇 |
2017年 | 91篇 |
2016年 | 102篇 |
2015年 | 109篇 |
2014年 | 144篇 |
2013年 | 167篇 |
2012年 | 153篇 |
2011年 | 208篇 |
2010年 | 118篇 |
2009年 | 175篇 |
2008年 | 157篇 |
2007年 | 225篇 |
2006年 | 166篇 |
2005年 | 172篇 |
2004年 | 146篇 |
2003年 | 118篇 |
2002年 | 122篇 |
2001年 | 116篇 |
2000年 | 100篇 |
1999年 | 113篇 |
1998年 | 88篇 |
1997年 | 74篇 |
1996年 | 69篇 |
1995年 | 72篇 |
1994年 | 61篇 |
1993年 | 53篇 |
1992年 | 51篇 |
1991年 | 27篇 |
1990年 | 26篇 |
1989年 | 23篇 |
1988年 | 18篇 |
1987年 | 5篇 |
1986年 | 6篇 |
1985年 | 6篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 5篇 |
1980年 | 2篇 |
1979年 | 4篇 |
1978年 | 1篇 |
1971年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有3713条查询结果,搜索用时 15 毫秒
1.
The first-principles DFT calculations together with microkinetic analysis reveal the complex catalytic mechanism of low-content NO oxidation on CrO2(110) at room temperature. It quantitatively makes clear that CrO2(110) can exhibit considerable activity with the Mars-van-Krevelen mechanism preferred, and the nitrate species serves as the key poisoning species. 相似文献
2.
Sheikdawood Parveen Thathan Premkumar Subbiyan Poornima Subbiah Govindarajan 《Journal of Saudi Chemical Society》2019,23(6):691-701
Metal complexes ([ML2], where M = Fe, Co, or Zn; HL = 2-[(6-ethyl-5-oxo-4,5-dihydro-2H-[1,2,4]triazin-3-ylidene)-hydrazono]-butyric acid, C9H13N5O3) of a Schiff base derived from α-ketobutyric acid (α-KBA) and diaminoguanidine (Damgu) were synthesized and characterized using elemental, spectral, and thermal studies. The metal complexes exhibited similar decomposition behavior, with a highly exothermic final decomposition step resulting in the formation of metal oxides. Isomorphism among the complexes was revealed using a powder X-ray diffraction (PXRD) technique. Solid solution precursors ([Zn1/3M2/3(L)2], where M = Fe, Co) were synthesized and characterized using various physico-chemical techniques. A thermal decomposition technique was used to prepare spinel-type zinc cobaltite (ZnCo2O4) and zinc ferrite (ZnFe2O4) nanocrystalline particles with the synthesized single source precursors. Structural studies using PXRD ascertained the predominant crystal phase to be spinel. Transmission electron microscopy (TEM) and high-resolution TEM (HRTEM) showed a mean nanoparticle size of 18 ± 2 nm. Magnetic measurements revealed a weak magnetic behavior in the synthesized spinels. In the aqueous phase, the spinels exhibited catalytic activity, reducing 4-nitrophenol (4-NP) in the presence of NaBH4 at room temperature. Additionally, the study demonstrated that the catalyst can be recovered and reused for five cycles with a more than 85% conversion efficiency. 相似文献
3.
The urge of developing modern alternatives regarding industrial production has led to the creation of novel techniques that help overcome critical disadvantages from traditional batch mechanochemistry. One promising strategy includes the merging of flow processes with mechanochemistry. Two technologies are herein highlighted: twin-screw extrusion (TSE) and Impact (induction) in Continuous flow HEated Mechanochemistry (I-CHEM) allowing not only the industrial production of polymers but also active pharmaceutical ingredients, synthesis of (nano)materials, and the obtention of high-added value products from biomass and wastes valorization. 相似文献
4.
亚甲基蓝和环丙沙星是水体中2种污染物, 对生态环境有潜在危害. 本文以市政剩余活性污泥为原料, 氯化锌为活化剂热解制备污泥基吸附剂, 研究盐酸酸洗浓度、氯化锌浓度、热解温度、热解时间等对污泥基吸附剂吸附水中亚甲基蓝和环丙沙星性能的影响. 结果表明 (1)污泥基吸附剂对亚甲基蓝的吸附性能随盐酸酸洗浓度的增大而增加, 对环丙沙星的吸附性能则随盐酸酸洗浓度的增大呈先降后增趋势, 两者均在1.500mol·L-1盐酸浓度下取得最优值. (2)污泥基吸附剂对亚甲基蓝和环丙沙星的吸附性能随氯化锌浓度和热解温度的增加呈先升后降趋势, 在氯化锌浓度为4.0mol·L-1、热解温度为500℃时有最优值; 随着热解时间的延长, 污泥基吸附剂对亚甲基蓝和环丙沙星的吸附性能分别在500℃热解70min和80min时有最优值. (3)污泥基吸附剂的最佳制备条件为 氯化锌4.0mol·L-1活化2h、500℃热解70min和80min、1.500mol·L-1盐酸酸洗; 以此制得的污泥基吸附剂对亚甲基蓝和环丙沙星的去除率分别为97.7%和96.4%, 平衡吸附量分别为97.9mg·g-1和3.9mg·g-1, 且污泥基吸附剂对亚甲基蓝和环丙沙星的吸附过程均符合准二级动力学方程. 相似文献
5.
Dr. Waleed Alsalahi Dr. Adam W. Augustyniak Dr. Włodzimierz Tylus Prof. Dr. Anna M. Trzeciak 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(6):e202103538
The new nanocomposites, Pd/C/ZrO2, PdO/ZrO2, and Pd/PdO/ZrO2, were prepared by thermal conversion of Pd@UiO-66-Zr−NH2 (MOF) in nitrogen or air atmosphere. The presence of Pd nanoparticles, uniformly distributed on the ZrO2 or C/ZrO2 matrix, was evidenced by transmission electron microscopy, scanning electron microscopy (SEM), Raman and X-ray Photoelectron Spectroscopy (XPS) methods. All pyrolysed composites retained the shape of the MOF template. They catalyze carbonylative Suzuki coupling under 1 atm CO with an efficiency significantly higher than the original Pd@UiO-66-Zr−NH2. The most active PdO/ZrO2 composite, formed benzophenone with TOF up to 1600 h−1, while by using Pd@UiO-66-Zr−NH2, much lower TOF values, 51–95 h−1, were achieved. After the reaction, PdO/ZrO2 was recovered with the same composition and catalytic activity. Very good results were also obtained in the transfer hydrogenation of benzophenones to alcohols with Pd/C/ZrO2 and PdO/ZrO2 catalysts under microwave irradiation. 相似文献
6.
《Particuology》2018
Silicoaluminophosphates (SAPOs) with different pore structures were synthesized through the implementation of polyethylene glycol (PEG) as a mesopores impregnation agent. Using PEGs with different molecular weights (MWs) and concentrations in the synthesis precursor, several samples were synthesized and characterized. Applying a PEG capping agent to the precursors led to the formation of tuned mesopores within the microporous matrix of the SAPO. The effects of the PEG molecular weight and PEG/Al molar ratio were investigated to maximize the efficiency of the catalyst in the methanol-to-olefin (MTO) process. Using PEG with a MW of 6000 resulted in the formation of both Zeolite Rho and chabazite structural frameworks (i.e., DNL-6 and SAPO-34). Pure SAPO-34 samples were successfully prepared using PEG with a MW of 4000. Our results showed that the PEG concentrations affect the porosity and acidity of the synthesized materials. Furthermore, the SAPO-34 sample synthesized with PEG (MW of 4000) and a PEG/Al molar ratio of 0.0125 showed a superior catalytic stability in the MTO reaction owing to the tuned bi-modal porosity and tailored acidity pattern. Finally, through reactivation experiments, it was found that the catalyst is stable even after several regeneration cycles. 相似文献
7.
Mengjie Liu Te‐Chun Chu Agnes Jocher Mica C. Smith Istvan Lengyel William H. Green 《国际化学动力学杂志》2021,53(1):27-42
Using Reaction Mechanism Generator (RMG), we have automatically constructed a detailed mechanism for acetylene pyrolysis, which predicts formation of polycyclic aromatic hydrocarbons (PAHs) up to pyrene. To improve the data available for formation pathways from naphthalene to pyrene, new high‐pressure limit reaction rate coefficients and species thermochemistry were calculated using a combination of electronic structure data from the literature and new quantum calculations. Pressure‐dependent kinetics for the CH potential energy surface calculated by Zádor et al. were incorporated to ensure accurate pathways for acetylene initiation reactions. After adding these new data into the RMG database, a pressure‐dependent mechanism was generated in a single RMG simulation which captures chemistry from C to C. In general, the RMG‐generated model accurately predicts major species profiles in comparison to plug‐flow reactor data from the literature. The primary shortcoming of the model is that formation of anthracene, phenanthrene, and pyrene are underpredicted, and PAHs beyond pyrene are not captured. Reaction path analysis was performed for the RMG model to identify key pathways. Notable conclusions include the importance of accounting for the acetone impurity in acetylene in accurately predicting formation of odd‐carbon species, the remarkably low contribution of acetylene dimerization to vinylacetylene or diacetylene, and the dominance of the hydrogen abstraction CH addition (HACA) mechanism in the formation pathways to all PAH species in the model. This work demonstrates the improved ability of RMG to model PAH formation, while highlighting the need for more kinetics data for elementary reaction pathways to larger PAHs. 相似文献
8.
The evaluation and interpretation of the behavior of construction materials under fire conditions have been complicated. Over the last few years, artificial intelligence (AI) has emerged as a reliable method to tackle this engineering problem. This review summarizes existing studies that applied AI to predict the fire performance of different construction materials (e.g., concrete, steel, timber, and composites). The prediction of the flame retardancy of some structural components such as beams, columns, slabs, and connections by utilizing AI-based models is also discussed. The end of this review offers insights on the advantages, existing challenges, and recommendations for the development of AI techniques used to evaluate the fire performance of construction materials and their flame retardancy. This review offers a comprehensive overview to researchers in the fields of fire engineering and material science, and it encourages them to explore and consider the use of AI in future research projects. 相似文献
9.
《Mendeleev Communications》2022,32(5):700-702
Kinetic modeling of pyrolysis of acetylene diluted with argon showed a strong influence of small additives of oxygen on the routes of formation of soot nuclei. The influence of oxygen on various channels of formation and consumption of propargyl radicals C3H3, which are important precursors of soot formation, as well as the fundamental possibility of controlling the process of soot formation and its properties are considered. 相似文献
10.
合金化可以调节贵金属纳米材料的物理化学性质,从而显著提升它们的电催化性能。尽管合金化在过去的20多年里已取得诸多成果,但是如何充分发挥纳米合金的组分优势仍需深入的探究。本研究通过一步溶液相合成法实现了类金属硼(B)合金化的钯基介孔纳米催化剂材料的合成,同时探究了B原子的组分优势和介孔形貌的结构优势在碱性介质中电化学甲醇氧化反应(MOR)的协同作用。最优PdCuB介孔纳米催化剂表现出优异的电化学MOR活性和稳定性。机理研究表明,优异的催化活性源于B原子在Pd基介孔纳米催化剂中的积极协同作用;该协同作用通过电子效应(改变Pd的表面电子结构从而减弱CO基中间体的吸附)和双功能效应(促进OH_(2)的吸附从而氧化CO基中间体)在动力学上加速了有毒CO基中间体的去除(提高甲醇氧化的决速步骤)。同时,B原子的间隙插入和介孔结构抑制了物理奥斯特瓦尔德(Ostwald)熟化过程,显著增加了催化剂的稳定性。 相似文献