突体剖面线型的流噪声机理分析和试验研究

本文在分析突体马蹄涡和湍流脉动压力特性的基础上，在中国船舶科学研究中心０３Ｂ水筒，试验比较了不同剖面线型的突体模型流动噪声，降噪效果３－５ｄＢ，提出了突体部面低噪声设计的实验依据和具体方法。     

Skeletal and appendage diversity as design elements in the synthesis of a discovery library of nonaromatic polycyclic 5-iminooxazolidin-2-ones, hydantoins, and acylureas

Amino-acid derived cross-conjugated trienes were used as a starting point for the synthesis of a discovery library of over 200 polycyclic 5-iminooxazolidin-2-ones, hydantoins, and acylureas. The main feature of this library synthesis is a triple branching strategy, which provides efficient access to five skeletally diverse scaffolds. In addition, four sets of building blocks were applied in both a front end and a back end diversification strategy. Multiple fused rings were obtained by cyclization of diamides with phosgene and stereoselective Diels-Alder reactions with maleimides. The 5-iminooxazolidin-2-one scaffold was rearranged into the isomeric hydantoin scaffold through a sequence of ring-opening and ring-closing reactions.     

Increasing appendage diversity on 3,4-dihydro-3-oxo-2H-1,4-benzoxazines via Aphos–Pd(OAc)2-catalyzed Suzuki–Miyaura cross-coupling of aryl chlorides

A library of 32 members of 3,4-dihydro-3-oxo-2H-1,4-benzoxazines has been synthesized from two substituted 2-aminophenols via microwave-assisted one-pot regioselective annulation of 2-bromoalkanoates and subsequent Suzuki–Miyaura cross-coupling of the chloro-substituted scaffolds. The latter transformation was carried out using our Aphos–Pd(OAc)₂ catalyst and the coupling of the aryl chlorides with arylboronic acids proceeded under mild reaction conditions at 60–80 °C in THF–H₂O (10:1) in the presence of K₃PO₄·3H₂O as the base to furnish the corresponding biaryl products in 80–98% yields.     

Attitude maneuver of liquid-filled spacecraft with a flexible appendage by momentum wheel

Attitude maneuver of liquid-filled spacecraft with an appendage as a cantilever beam by momentum wheel is studied.The dynamic equations are derived by conservation of angular momentum and force equilibrium principle.A feedback control strategy of the momentum wheel is applied for the attitude maneuver.The residual nutation of the spacecraft in maneuver process changes with some chosen parameters,such as steady state time,locations of the liquid container and the appendage,and appendage parameters.The results indicate that locations in the second and fourth quadrants of the body-fixed coordinate system and the second quadrant of the wall of the main body are better choices for placing the liquid containers and the appendage than other locations if they can be placed randomly.Higher density and thicker cross section are better for lowering the residual nutation if they can be changed.Light appendage can be modeled as a rigid body,which results in a larger residual nutation than a flexible model though.The residual nutation decreases with increasing absolute value of the initial sloshing angular height.