Current trends in the description of lanthanum strontium manganite oxygen electrode reaction mechanism in a high-temperature solid oxide cell

This review summarizes recent progress in understanding the oxygen reduction and evolution reactions at the lanthanum strontium manganite electrode of a high-temperature solid oxide cell. Information provided here is put into the perspective of the defect chemistry of lanthanum strontium manganite and its impact on the electrode reaction mechanisms itself. After summarizing recent views on the oxygen reduction reaction mechanism, the focus turns to the oxygen evolution reaction, which is significantly less treated in the literature. A combination of the information in the literature on both reactions was the basis for modified reaction mechanism of the oxygen evolution reaction to be proposed under consideration of recent experimental observations and theoretical findings.     

Functional analysis of repositioned anilide derivatives as anticancer compounds

Off the different types cancers 40% of the population have been observed to be affected by leukemia. Contemporary therapeutics is focusing on generation of new synthetic analogues that can exert maximum positive physiological effect with minimum dosage and negligible deleterious side effects. New generation pharmacists are focusing on such promising effects of Imatinib (a potential anti-cancer drug molecule), Dasatinib, Pelitinib and Nilotinib. The present research study focuses on novel synthesized anilides derivative against BCR-ABL kinase as potential anti-leukemic agent. Validation of the compounds by molecular docking with specific BCR-ABL kinase confirmed their activity. Toxicity prediction of these compounds helped to identify sustainability as therapeutic molecules. The IC₅₀ values were calculated (211 ug, 175 ug, 272ug for compounds A, B, C resp.) and the mode of cell death was gauged by DNA laddering assay. The cells were observed to be induced for programmed cell death. By validating and in-vivo testing of three synthesized compounds, the compound B was observed to be more stable thermodynamically with a potentially vital active site and appears to be a promising anti-leukemic factor. The present research thus lays a preliminary platform in world of pharmaceutics, where these new analogues appear to be efficient, target specific and less toxic molecules.     

Formation of tricyclo[6.3.0.02,5]undecane derivatives during attempts to make the rumphellatin A–C oxacarbon skeleton

The results of several approaches to make the 4,4,8-trimethyl-12-oxatricyclo[7.2.1.0^2,5]dodecane motif present in rumphellatins A–C are reported. The strategy adopted involved (9E)-12,12-dimethyl-5-oxatricyclo[8.2.0.0^4,6]dodec-9-en-11-ol as an intermediate, but when attempts were made to connect the third methyl group to the carbon skeleton by reacting the epoxide with MeLi under boron-trifluoride catalysis, an unprecedented transannular reaction occurred. The desired product was not formed; instead, compounds containing a tricyclo[6.3.0.0^2,5]undecane moiety were obtained, in one case in better than 70% yield.     

A different perspective of the teaching philosophy of RL Moore

Dr RL Moore was undoubtedly one of the finest mathematics teachers ever. He developed a unique teaching method designed to teach his students to think like mathematicians. His method was not designed to convey any particular mathematical knowledge. Instead, it was designed to teach his students to think. Today, his method has been modified to focus on using student participation toward the goal of the conveyance of mathematical knowledge rather than on Dr Moore's goal of teaching students to think. This article proposes that undergraduates would be better served if they took at least one course using Dr Moore's original method and his original goal.     

Structures of the twisted N = 1 Schrödinger–Neveu–Schwarz algebra

In this paper, we determine the universal central extension, derivation algebra and automorphism group of the twisted N = 1 Schrödinger–Neveu–Schwarz algebra. Furthermore, we generalize these results to the generalized twisted N = 1 Schrödinger–Neveu–Schwarz algebra in the final section.     

Aromatization of Hantzsch 1,4-Dihydropyridines with Al(NO3)3·9H2O and/or Fe(NO3)3·9H2O in the Presence of Silica Sulfuric Acid Under Mild and Heterogeneous Conditions

A simple and convenient method for the aromatization of Hantzsch 1,4-dihydropyridines to the corresponding pyridines is achieved via combination of aluminum or ferric nitrates and silica sulfuric acid as environmentally friendly and novel oxidizing media. This oxidation was carried out in dichloromethane under heterogeneous conditions with good to excellent yields.     

Experimental Study of Oil Deposition Through a Flow Loop

In this article, the effect of temperature, pressure, and flow rate on deposition rate has been investigated by using chemical analysis method for calculating the deposit thickness and comparing to heat transfer and pressure drop methods. To do so, an experimental high pressure flow loop setup was designed and constructed to conduct various experiments. Caliper readings at the end of each test showed the chemical analysis method in comparison to the heat transfer and pressure drop methods is superior for deposit thickness calculation.     

Syntheses of the Saturated Analogues of 4-Nitrophenol and 4-Nitroaniline

Two syntheses for 4-nitrocyclohexanol and 4-nitrocyclohexanamine are presented. Both conveniently start from commercially available 4-aminocyclohexanol.     

Amine Salt–Catalyzed Synthesis of 5-Substituted 1H-Tetrazoles from Nitriles

The [3 + 2] cycloaddition reaction between sodium azide and various organic nitriles proceeds smoothly in the presence of amine salts as catalyst in dimethylformamide. The corresponding 5-substituted 1-H tetrazoles were obtained under mild condition in good to excellent yields. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications® to view the free supplemental file.     

Cramer’s rule over residue class rings of Bézout domains

Cramer’s rule over residue class rings of Bézout domains is given.