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1.
Low-efficiency charge separation in metal sulfides is a major obstacle to realizing high photocatalytic performance. Herein, we propose the concept of a similar surface domain potential difference between adjacent microdomains with and without surface S vacancies on ZnIn2S4 to mediate charge separation. Defective ZnIn2S4 microspheres (DZISNPs) are prepared through a solvothermal method combined with a low-temperature hydrogenation surface engineering strategy. The as-prepared DZISNPs with a narrowed bandgap of 2.38 eV possess a large specific surface area of 178.5 m2 g?1, a pore size of 6.89 nm, and a pore volume of 0.36 cm3 g?1, which further improves the visible light absorption. The resultant DZISNPs exhibit excellent visible light activity (2.15 mmol h?1 g?1), which is ~two-fold higher than that of the original DZISNP. The experimental results and DFT calculations reveal that the enhanced property can be a result of the surface S vacancy-induced surface domain potential difference, promoting the spatial separation of electrons and holes. Furthermore, the long-term stability of the DZISNPs indicates that the formation of surface S vacancies can inhibit the photocorrosion of ZnIn2S4. This strategy provides new insights for fabricating highly efficient and stable sulfide photocatalysts.  相似文献   
2.
Si-based materials possess huge potential as an excellent anode material for Li-ion batteries. However, how to realize scalable synthesis of Si-based anode with a long cycling life and high-performance is still a critical challenge. Here a water-in-oil microemulsion process followed by UV illumination, calcination, and hydrothermal method to produce yolk-shell Si@void@C embedded in interconnected 3D porous carbon network architecture using silicon nanoparticles is reported. As a result, the sample Si@void@C/C-2 electrode has achieved a reversible capacity of 1160 mA h g−1 at 0.2 A g−1 after 300 cycles and a stable long cycling life of 480 mA h g−1 at 1 A g−1 after 1000 cycles. A full battery with the synthesized anode shows a capacity of 128 mA h g−1 at 0.2 A g−1 as well as good cycling stability after 1100th cycles. Such excellent electrochemical performance is ascribed to its unique structure, the yolk-shell void space, highly robust carbon shells and interconnected porous carbon nets that can improve the conductivity of the electrode, buffer the volume expansion, and also suppress Si nanoparticles stress variation. This water-in oil system makes it possible for mass production of environmentally friendly synthesis of core–shell structure.  相似文献   
3.
This study investigated the effects of different treatment of alkaline pH-shifting on milk protein concentrate (MPC), micellar casein concentrate (MCC) and whey protein isolate (WPI) assisted by the same ultrasound conditions, including changes in the physicochemical properties, solubility and foaming capacity. The solubility of milk proteins had a significant increase with gradual enhancement of ultrasound-assisted alkaline pH-shifting (p < 0.05), especially for MCC up to 99.50 %. Also, treatment made a significant decline in the particle size of MPC and MCC, as well as the turbidity of the proteins (p < 0.05). The foaming capacity of MPC, MCC, and WPI was all improved, especially at pH 11, and at this pH, the milk protein also showed the highest surface hydrophobicity. The best foaming capacity at pH 11 was the result of the combined effect of particle size, potential, protein conformation, solubility, and surface hydrophobicity. In conclusion, ultrasound-assisted pH-shifting treatment was found to be effective in improving the physicochemical properties and solubility and foaming capacity of milk proteins, especially MCC, with promising application prospect in food industry.  相似文献   
4.
Multidrug resistance of cancer cells is a major obstacle for cancer chemotherapy. Herein, we present a nanocarrier that can release chemotherapeutic agents to induce tumor cell death and generate NO under NIR to overcome multidrug resistance in cancer chemotherapy. Owing to the unique structure of the water channel in this controlled release system for chemotherapeutic agents, the nanocarrier surface is equipped with more active sites to graft NO donor molecules. The released NO performs very well in reversing multidrug resistance by inhibiting P-gp expression. Our findings provide new insight into multidrug resistance cancer therapy and controlled release nanocarriers for multiple drugs.  相似文献   
5.
美国宝石学院19世纪30年代起,首先建立了一套成熟的钻石颜色分级系统。传统上,钻石颜色分级靠目视以及与成套标准比色石比较确定。目视分级结果被一些因素如检验环境、钻石尺寸,分级人员等所影响。因此经常出现对一个样品,即使是同一个人在相同环境分级检测也容易出现分级偏差。为了避免上述问题,利用检测设备来评估钻石颜色,成为钻石领域的一个研究热点。可是目前没有达到评估钻石颜色分级的要求。该研究给出了一个有意义的方法来定量表征钻石的颜色。该方法使用显微微区定位检测方法来定量评估钻石颜色,同时该方法可以避免钻石尺寸大小对钻石颜色分级的影响。可见光分光光度计原理被使用在该方法。该方法由样品系统、微区定位显示系统、信号收集与计算系统组成。D65光源被使用,并且色温保持在(6 500±200) K; 高分辨率CCD探测器作为信号采集设备。该方法准确检测了几套不同大小和颜色的带国家(中国)标准证书的钻石样品,结果表明,该方法能够快速、准确的测量钻石的颜色坐标,并自动转换为钻石分级系统对应的颜色分级级别,同时靠使用微区定位检测技术,对圆钻型钻石测试能够排除钻石尺寸引起的颜色分级偏差。该方法对钻石分级是一个有益的潜在技术。  相似文献   
6.
冬奥冰雪运动摩擦阻力影响运动健儿成绩,减少滑雪板与雪面之间摩擦阻力,有助于提升滑雪时的行进速度,提高运动员成绩排名. 研究冰雪表面摩擦学,有助于认识冰雪表面水润滑机理,为设计高性能滑雪板和雪蜡材料提供相关的研究基础. 因此,本文作者从冰雪表面摩擦学开始,简要介绍冰雪表面水润滑机理及影响冰雪表面摩擦学性能的影响因素,如环境参数(运动环境的温度/湿度)、雪基参数(雪面硬度、密度,雪面温度/湿度、冰晶大小、雪面污染物)、滑雪板基底参数及雪蜡的使用等;着重介绍了滑雪运动必备的材料-滑雪板减阻蜡的作用和分类,含氟雪蜡对人员环境的危害,雪蜡的选择与打蜡方式对雪板减阻性能的影响以及国内外现有的冰雪摩擦测试装置. 最后,对我国现有冰雪摩擦学基础研究,冰雪运动摩擦学及雪蜡材料的应用开发研究提出了几点建议和期望.   相似文献   
7.
8.
Micro/nanoscale photonic barcodes based on multicolor luminescent segmented heterojunctions hold potential for applications in information security. However, such multicolor heterojunctions reported thus far are exclusively based on static luminescent signals, thus restricting their application in advanced confidential information protection. Reported here is a strategy to design responsive photonic barcodes with heterobimetallic (Tb3+/Eu3+) metal—organic framework multicolor heterostructures. The spatial colors could be precisely controlled by thermally manipulating the energy-transfer process between the two lanthanides, thus achieving responsive covert photonic barcodes. Also demonstrated is that spatially resolved responsive barcodes with multi-responsive features could be created in a single heterostructure. These findings offer unique opportunities to purposely design highly integrated responsive microstructures and smart devices toward advanced anti-counterfeiting applications.  相似文献   
9.
Meng  Xia  Wang  Lizhen  Zhai  Yunge  Duan  Hongdong 《Research on Chemical Intermediates》2020,46(12):5517-5533
Research on Chemical Intermediates - Two novel Schiff-base fluorescent probes bearing different substituents were synthesized by the reaction of indole derivatives with 4-aminoantipyrine. The...  相似文献   
10.
In this review, we discuss the application of cellulose nanoparticles as a sustainable and cost-effective source of green stabilizers for formulation of foodstuff. Fibrillar cellulose nanocrystal and nanofibril stabilize Pickering systems because of their ability to adsorb at the oil/water interfaces, forming protective layers. They also form associative structures in the continuous phase, increasing their viscoelastic properties and preventing flocculation. We describe the chemical and structural features of nanocelluloses and discuss the principles that support their utilization as stabilizers, especially in the context of recent prospects in food and health domains, given safety and regulatory advances. In addition, we describe the benefits of combining nanocelluloses with other food ingredients to extend their functional attributes. Particularly, nanocellulose-based Pickering emulsions are used to create edible soft materials with multiple functionalities. This article is expected to stimulate the use of nanocelluloses as functional ingredients to create food products with improved performance and novel properties.  相似文献   
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