利用手持技术探究酸碱性对高锰酸钾氧化性的影响

高锰酸钾作为常用的氧化剂,其氧化性强弱与体系酸碱性相关。通过手持技术,利用氧化还原电势(ORP)传感器和pH传感器去探究体系酸碱性对高锰酸钾氧化性的影响。实验发现:pH在酸性条件下,高锰酸钾溶液的氧化性明显增强,随着体系pH的减小,氧化性继续增强;在碱性条件下,其氧化性明显减弱,随着体系pH的增大,其氧化性继续减弱。实际实验中需要根据各种综合因素选用适宜酸碱性的高锰酸钾溶液做氧化剂。     

具非自治微小扰动的脉冲方程三个古典解的存在性

在半直线无穷区间上,我们研究具有微小非自治扰动项的脉冲方程边值问题的古典解,应用变分方法和相应的临界点理论得到了三个古典解的存在性.     

从“概念转变”到“概念理解”——科学概念学习研究的转向

当前国际科学概念学习研究显示了从“概念转变”到“概念理解”的转向。通过分析概念转变教学研究的结果,得出影响概念转变的关键因素在于学生对科学概念的理解。阐释了概念理解的内涵、特征,探讨了概念理解与高级思维的关系、概念理解水平、概念理解的教学和评价等内容。     

无穷区间上二阶微分方程的边值问题

利用Schauder不动点定理讨论了一类非线性二阶微分方程在无穷区间上的边值问题无界解的存在性，部分改进了郭大钧教授最近得到的结果。     

非线性奇异边值问题的正解

利用锥映射的不动点指数定量，研究了一类非线性奇异边值问题多个正解的存在性问题。在构造的解的存在条件之下，证明了奇异边值问题至少有两个正解的存在性定理。     

532-nm picosecond pulse generated in a passively mode-locked Nd:YVO_4 laser

A diode-pumped continuous-wave （CW） mode-locked Nd：YVO4/KTP green laser with semiconductor saturable absorber mirror （SESAM） is demonstrated. The maximum output power of CW mode-locked green laser is obtained to be 552 mW at the incident pump power of 7.25 W, corresponding to an opticai-optical conversion efficiency of about 7.6%. The 532-nm CW mode-locked pulse duration is estimated to be about 8.4 ps with the repetition rate of 87 MHz.     

Some class 1 graphs on <Emphasis Type="Italic">g</Emphasis><Subscript><Emphasis Type="Italic">c</Emphasis></Subscript>-colorings

An edge-coloring of a graph G is an assignment of colors to all the edges of G. A g _c -coloring of a graph G is an edge-coloring of G such that each color appears at each vertex at least g(v) times. The maximum integer k such that G has a g _c -coloring with k colors is called the g _c -chromatic index of G and denoted by \(\chi\prime_{g_{c}}\)(G). In this paper, we extend a result on edge-covering coloring of Zhang and Liu in 2011, and give a new sufficient condition for a simple graph G to satisfy \(\chi\prime_{g_{c}}\)(G) = δ _g (G), where \(\delta_{g}\left(G\right) = min_{v\epsilon V (G)}\left\{\lfloor\frac{d\left(v\right)}{g\left(v\right)}\rfloor\right\}\).     

Stability analysis of impulsive delayed switched systems and applications

In this paper, a general class of impulsive delayed switched systems is considered. By employing the Lyapunov–Razumikhin method and some analysis techniques, we established several global asymptotic stability and global exponential stability criteria for the considered impulsive delayed switched systems, which improve and extend some recent works. As an application, the result of global exponential stability are used to study a class of uncertain linear switched systems with time‐varying delays. Several LMI‐based conditions are proposed to guarantee the global robust stability and global exponential stabilization. The designed memoryless state feedback controller can be easily checked by the LMI toolbox in Matlab. Moreover, the dwell time constraint is imposed for the switching law. Finally, two numerical examples and their simulations are given to show the effectiveness of our proposed results. Copyright © 2012 John Wiley & Sons, Ltd.     

超临界流体CO2萃取中药有效成分的抗氧化性的分光光度法研究

利用超临界流体二氧化碳萃取技术提取中药虎杖、大黄、炒白术中黄酮类化合物。在pH8．2的HCl—tris缓冲溶液中利用邻苯三酚自氧化法测定提取物对超氧阴离子自由基的消除作用。用茜素紫作显色剂的分光光度法在pH9．0的HCl—tris缓冲体系中测定中药提取物对Co^2 H2O2体系所产生的羟基自由基的消除作用,并对实验条件进行了探讨。实验结果表明,3种中药提取物对自由基都有消除作用,其中虎杖的效果最好。     

Molecular Dynamic Simulation on the Absorbing Process of Isolating and Coating of α-olefin Drag Reducing Polymer

The absorbing process in isolating and coating process of α-olefin drag reducing polymer was studied by molecular dynamic simulation method, on basis of coating theory of α-olefin drag reducing polymer particles with polyurethane as coating material. The distributions of sodium laurate, sodium dodecyl sulfate, and sodium dodecyl benzene sulfonate on the surface of α-olefin drag reducing polymer particles were almost the same, but the bending degrees of them were obviously different. The bending degree of SLA molecules was greater than those of the other two surfactant molecules. Simulation results of absorbing and accu-mulating structure showed that, though hydrophobic properties of surfactant molecules were almost the same, water density around long chain sulfonate sodium was bigger than that around alkyl sulfate sodium. This property goes against useful absorbing and accumulating on the surface of α-olefin drag reducing polymer particles; simulation results of interactions of different surfactant and multiple hydroxyl compounds on surface of particles showed that, interactions of different surfactant and one kind of multiple hydroxyl compound were similar to those of one kind of surfactant and different multiple hydroxyl compounds. These two contrast types of interactions also exhibited the differences of absorbing distribution and closing degrees to surface of particles. The sequence of closing degrees was derived from sim-ulation; control step of addition polymerization interaction in coating process was absorbing mass transfer process, so the more closed to surface of particle the multiple hydroxyl com-pounds were, the easier interactions with isocyanate were. Simulation results represented the compatibility relationship between surfactant and multiple hydroxyl compounds. The isolating and coating processes of α-olefin drag reducing polymer were further understood on molecule and atom level through above simulation research, and based on the simulation, a referenced theoretical basis was provided for practical optimal selection and experimental preparation of α-olefin drag reducing polymer particles suspension isolation agent.