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Fluid Dynamics - To predict the boundary layer transition on swept wings, experimental and numerical researches were conducted to obtained the accurate boundary layer transition front and to... 相似文献
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We present the design procedure for the elastic GHz-ranged demultiplexer based on a solid-solid phononic crystal platform. It consists of a T-shaped waveguide with three arms. The PnC platform consists of a square array of infinitely long rods of Tungsten embedded in PMMA background. In order to have a wide band gap, it is essential that constituent materials have large contrast in physical properties. These materials have large contrast in their physical properties and it gives us the possibility of having complete band gaps with low filling fractions. To calculate the band diagram and transmission field map, the finite element method (FEM) has been employed. The main waveguides are made by removing one row or one column of rods. For each arm, the radius of rods is modified to have three different defects. Therefore, the designed demultiplexer can separate three frequencies in the range of GHz. To the best of our knowledge, it is for the first time. 相似文献
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Yongxing Tang Yajun Yu Xinyu Wei Jin Yang Yeting Zhu Yun-Hui Zhao Zilong Tang Zhihua Zhou Xiaofang Li Xianyong Yu 《Tetrahedron letters》2019,60(43):151187
A novel 6-endo-dig cyclization followed by oxidation/elimination of o-alkynylarylaldimines with 4-hydroxybenzylamine was developed for preparation of isoquinolines. The intermediates of this tandem reaction were monitored by mass spectroscopy (MS) to confirm the reaction pathway. This methodology was further applied to the design and synthesis of a novel ratiometric chemosensor for determination of fluoride. 相似文献
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Herein we summarized some clean preparation examples to emphasize the concept of dual roles design (or named as “two birds one stone strategy”) in green and sustainable chemistry. In those examples, the reactants and/or solvent play dual roles rendering a cleaner organic preparation process. Consequently, both the chemical waste and manufacturing cost could be reduced. 相似文献
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Alcohol fuels oxidation plays a significant role in carbon sustainable cycling and high-performance catalyst with a strong anti-poisoning effect is desired. Herein, Pt-Ni alloy supported on the N-doped graphene aerogel synthesized by simple freeze-drying and annealing was demonstrated to have such catalytic ability for alcohol fuel oxidation. Pt-Ni alloy particles were found uniformly dispersed over the surface of 3D N-doped graphene aerogel. High anti-poisoning ability for CO-like intermediates... 相似文献
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Ligand-promoted copper-catalyzed cascade reactions have become a robust tool for the synthesis of cyclic compounds. Although numerous ligands have been developed, this review focuses on the introduction of commercially available 1,10-phenanthroline-promoted copper-catalyzed cascade reactions in recent years. Moreover, based on original articles, this review highlights product yields in the presence and absence of the ligand, and the possible mechanistic role of the ‘copper/1,10-phenanthroline’ catalytic system. 相似文献