Noninvasive Temperature Measurement in Dental Materials Using Nd3+, Yb3+ Doped Nanoparticles Emitting in the Near Infrared Region

In this work, the application of near infrared (NIR)-emitting NaYbF₄:1%Tm³⁺@NaLuF₄:30%Nd³⁺ core–shell nanoparticles is reported for noninvasive probing and monitoring the temperature during photopolymerization of dental materials. When excited at 808 nm, the synthesized nanoparticles emit NIR photoluminescence (PL) with two distinctive peaks at 865 and 980 nm which correspond to radiative transitions from the doped Nd³⁺ and Yb³⁺ ions, respectively. Luminescence intensity ratio between these two bands is found to vary with temperature due to temperature-dependent electronic excitation energy transfer between Nd³⁺ and Yb³⁺ ions at the core/shell interface. This finding allows luminescence ratiometric evaluation of the in situ temperature during photopolymerization of resin cement (doped with nanoparticles) in a veneer placement procedure. In addition, the NIR emission also enables PL imaging of the distribution of the adhesive under the veneer. The results highlight that rare-earth ions–doped nanoparticles with both excitation and emission in the NIR spectral range are advantageous for both PL-based nanothermometry and imaging due to the reduced attenuation of NIR light by dental ceramics.     

Hydrodynamics of flow over a transversely oscillating circular cylinder beneath a free surface

In this paper, hydrodynamic force coefficients and wake vortex structures of uniform flow over a transversely oscillating circular cylinder beneath a free surface were numerically investigated by an adaptive Cartesian cut-cell/level-set method. At a fixed Reynolds number, 100, a series of simulations covering three Froude numbers, two submergence depths, and three oscillation amplitudes were performed over a wide range of oscillation frequency. Results show that, for a deeply submerged cylinder with sufficiently large oscillation amplitudes, both the lift amplitude jump and the lift phase sharp drop exist, not accompanied by significant changes of vortex shedding timing. The near-cylinder vortex structure changes when the lift amplitude jump occurs. For a cylinder oscillating beneath a free surface, larger oscillation amplitude or submergence depth causes higher time-averaged drag for frequency ratio (=oscillation frequency/natural vortex shedding frequency) greater than 1.25. All near-free-surface cases exhibit negative time-averaged lift the magnitude of which increases with decreasing submergence depth. In contrast to a deeply submerged cylinder, occurrences of beating in the temporal variation of lift are fewer for a cylinder oscillating beneath a free surface, especially for small submergence depth. For the highest Froude number investigated, the lift frequency is locked to the cylinder oscillation frequency for frequency ratios higher than one. The vortex shedding mode tends to be double-row for deep and single-row for shallow submergence. Proximity to the free surface would change or destroy the near-cylinder vortex structure characteristic of deep-submergence cases. The lift amplitude jump is smoother for smaller submergence depth. Similar to deep-submergence cases, the vortex shedding frequency is not necessarily the same as the primary-mode frequency of the lift coefficient. The frequency of the induced free surface wave is exactly the cylinder oscillation frequency. The trends of wave length variation with the Froude number and frequency ratio agree with those predicted by the linear theory of small-amplitude free surface waves.     

The near wake of sinusoidal wavy cylinders: Three-dimensional POD analyses

Three-dimensional (3D) proper orthogonal decomposition (POD) analyses are conducted to investigate the near wake of sinusoidal wavy cylinders. For a wave amplitude a/D_m = 0.152, three typical spanwise wavelengths (λ_z) of the wavy cylinder are taken into account, i.e., λ_z/D_m = 1.89, 3.79 and 6.06, where D_m is the mean diameter of the wavy cylinder, among which λ_z/D_m = 1.89 and 6.06 are the optimum wavelengths corresponding to the largest reduction/suppression of fluid forces acting on the wavy cylinder. Time- and space-resolved three-component velocities of the near wake flow, obtained from large eddy simulation (LES) at a subcritical Reynolds number Re = 3 × 10³, are used in the 3D POD analyses. Comparison is made among the wavy cylinders of the three λ_z/D_m values as well as between them and a smooth cylinder, in terms of POD modes, mode energy, mode coefficients, as well as reconstructed flow structures by lower modes. For the optimum λ_z/D_m = 1.89 and 6.06, energy associated with the first two POD modes is significantly reduced compared with that for λ_z/D_m = 3.79 and the smooth cylinder. Distinct characteristics are observed on the lower POD modes for the wavy cylinders. It is found that the first two POD modes for λ_z/D_m = 1.89 and 6.06 are linked to large-scale streamwise vortices that are additionally introduced into the near wake due to the wavy geometry. Meanwhile, POD mode 3 suggests that the wavy cylinder with the larger optimum λ_z/D_m (= 6.06) generates dominant hairpin-like and spanwise coherent structures (CSs) shedding from the saddle at a different frequency from those shedding from the node. Evolutionary development of these CSs is discussed based on reconstructed flows.     

Numerical Analysis of the Fracture Toughness of Low-Density Open-Cell Voronoi Foams

Mechanics of Composite Materials - In this study, the geometry of open-cell foams is simulated using a model based on Voronoi tessellations. The fracture toughness of open-cell foams with Voronoi...     

复合纤维增强混凝土阻尼测试装置开发与试验研究

纤维与聚合物的掺入可以明显改善混凝土材料的阻尼性能。本文首先给出了正弦交变激励下粘弹性材料三点弯曲梁阻尼特性关系,其次首次自主开发了大尺寸材料的阻尼性能测试装置,然后利用开发的装置在频率(0.5~2.0Hz)条件下测定了6种不同配比复合纤维增强阻尼混凝土的损耗因子与储存模量,最后对纤维的阻尼增强机理进行了初步探讨。试验结果表明:复合纤维增强阻尼混凝土与素混凝土相比,提高了混凝土的损耗因子80%~200%。主要原因是聚合物分子在外力作用下的内耗增加了普通混凝土的阻尼能力,而纤维的阻尼增强机理在于纤维的掺入增加了纤维与水泥基材的界面摩擦力。     

EFFECTS OF DISLOCATION CONFIGURATION, CRACK BLUNTING AND FREE SURFACES ON THE TRIGGERING LOAD OF DISLOCATION SOURCES

The effects of dislocation configuration,crack blunting and free surfaces on the triggering load of dislocation sources in the vicinity of a crack or a wedge tip subjected to a tensile load in the far field are investigated.An appropriate triggering criterion for dislocation sources is proposed by considering the configurational forces acting on each dislocation.The triggering behaviors of dislocation sources near the tips of a crack and a wedge are compared.It is also found that the blunting of crack tip and the presence of free surfaces near the crack or the wedge have considerable influences on the triggering load of dislocation sources.This study might be of significance to gaining a deeper understanding of the brittle-to-ductile transition of materials.     

Crack spacing effect for a piezoelectric cylinder under electro-mechanical loading or transient heating

This paper investigates the fracture problem of a piezoelectric cylinder with a periodic array of embedded circular cracks. An electro-mechanical fracture mechanics model is established first. The model is further used to the thermal fracture analysis of a piezoelectric cylinder subjected to a sudden heating on its outer surface. The temperature field and the associated thermal stresses and electric displacements are obtained and are added to the crack surface to form a mixed-mode boundary value problem for the electro-mechanical coupling fracture. The stress and stress intensities are investigated for the effect of crack spacing. Strength evaluation of piezoelectric materials under the transient thermal environment is made and thermal shock resistance of the medium is given.     

A Statistical Study of the Correlation between Geomagnetic Storms and M ≥ 7.0 Global Earthquakes during 1957–2020

In order to find out whether the geomagnetic storms and large-mega earthquakes are correlated or not, statistical studies based on Superposed Epoch Analysis (SEA), significance analysis, and Z test have been applied to the Dst index data and M ≥ 7.0 global earthquakes during 1957–2020. The results indicate that before M ≥ 7.0 global earthquakes, there are clearly higher probabilities of geomagnetic storms than after them. Geomagnetic storms are more likely to be related with shallow earthquakes rather than deep ones. Further statistical investigations of the results based on cumulative storm hours show consistency with those based on storm days, suggesting that the high probability of geomagnetic storms prior to large-mega earthquakes is significant and robust. Some possible mechanisms such as a reverse piezoelectric effect and/or electroosmotic flow are discussed to explain the statistical correlation. The result might open new perspectives in the complex process of earthquakes and the Lithosphere-Atmosphere-Ionosphere (LAI) coupling.