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1.
A simple and rapid capillary electrophoretic method was developed for the simultaneous determination of noradrenaline (NA) and dopamine (DA) in Portulaca oleracea L. The buffer solution used in this method was 40 mM tris (hydroxymethyl) aminomethane (Tris)-H3PO4 at pH 2.00 containing 15% methanol. The effects of pH value, organic modifier, and applied voltage were investigated. The linear ranges of NA and DA were 0.5-100 microg/mL (r=0.9952) and 6.25-200 microg/mL (r=0.9992), respectively. The relative standard deviations of the corrected peak area were 6.73% and 4.26%, respectively. NA and DA in Portulaca oleracea L. were simultaneous determined successfully within 5.6 min. In this way, the contents of NA and DA in different parts (stem, leaves, and seeds) of P. oleracea L. and in different extracts of leaves with different solvents (distilled water, 50% methanol, and methanol) were studied. 相似文献
2.
Shuo Shi Runhua Lu Taotao Wang Haiying Sun Hanqing Wang 《Journal of Dispersion Science and Technology》2013,34(4):1247-1262
The phase composition and properties of microemulsion system of Titron N-101 / n-pentanol/ n-octane/ water (ammonia solution) were studied. CeO2 nanopaticles were prepared by the reaction of cerous nitrate. 相似文献
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In this work we present a study of growth and characterization of ZnS/carbon nanotube (CNT) composites. The composites were prepared with a chemical mix technique and characterized by SEM analysis, Auger Electron Spectroscopy (AES) and Cathodoluminescence (CL) spectroscopy. The analyses show that the sample is formed by a direct contact between CNT and zinc sulfide. In particular, SEM images show CNTs wrapped around ZnS micrometer particles. Furthermore, AES spectroscopy shows the absence of chemical bonds between ZnS and CNT and that the sample homogeneity increases with the CNT amount in the composite.Finally CL studies show that our composites present a visible luminescence signal centered at about 500 nm, with a shift of luminescence emission peak linked to the amount of CNT in the sample. 相似文献
6.
Single-component monolayer of novel multi-thiol coronary molecule and two-component mixed monolayer composed of coronary molecule and n-alkanethiol on gold substrates are described. The assembly of monolayers is characterized by ellipsometry, infrared spectroscopy and X-ray photoelectron spectroscope. The electrochemical properties of the single- and two-component monolayers are evaluated by cyclic voltammetry and electrochemical impedance spectroscopy experiments. Coronary molecule with multi-thiol groups has the ability to form stable monolayer via the interaction of mercapto groups and Au surface. Electrochemical impedance measurements indicate that 89.9% of the gold surface is blocked by the coronary molecule, which is attributed to the special spatial structure of the coronary molecule. The uncovered site on gold surface in coronary molecule monolayer could be occupied by the second suitable molecule. The mixed monolayer prepared by stepwise assembly of coronary molecule and n-alkanethiol has complete compact packing and few defects. 相似文献
7.
Super-hydrophilic properties of TiO2-DLC nanocomposite films fabricated by the simple electrochemical process 总被引:1,自引:0,他引:1
Anatase TiO2 nanoparticles incorporated DLC films were successfully deposited on single crystalline silicon substrates by the electrolysis of TiO2-methanol solution under ambient atmospheric pressure and low temperature. Anatase TiO2 nanoparticles were embedded into amorphous carbon matrix, forming the typical nanocrystalline/amorphous nanocomposite films, confirmed by transmission electron microscopy (TEM). TiO2 incorporation effectively increased the sp3-hybridized carbon concentration in the composite film, and further regulated the microstructure and surface morphology. Furthermore, the static contact testing completely displayed, TiO2 incorporation got the composite films super-hydrophilic, which fundamentally improved the wetting ability of DLC film. 相似文献
8.
Fu-bao Zheng Chang-wen Zhang Pei-ji Wang Hang-xing Luan 《Solid State Communications》2012,152(14):1199-1202
The electronic and magnetic properties of N-doped ZnO nanosheets are investigated by density functional theory using local spin density approximation. The results show that in an isolated N-doped ZnO nanosheet, there is a clear spontaneous polarization of N 2p state with a magnetic moment 1.0 μB/N. We also find that the doped nitrogen atoms in ZnO nanosheets have a clustering tendency with ferromagnetic coupling between them, and thus a high room-temperature ferromagnetic nature is expected. The ferromagnetic coupling in N-doped ZnO nanosheets can be attributed to the hole-mediated double-exchange mechanism through strong p–d interaction between nitrogen and zinc atoms. 相似文献
9.
Baixing Liu Xianqiang Pei Qihua Wang Tingmei Wang Xiaojun Sun 《Journal of Macromolecular Science: Physics》2013,52(11):2245-2254
Effects of atomic oxygen (AO) irradiation on the structural and tribological behaviors of polytetrafluoroethylene (PTFE) composites filled with both glass fibers and Al2O3 were investigated in a ground-based simulation facility, in which the average energy of AO was about 5 eV and the flux was 5.0 × 1015/cm2 s. It was found that AO irradiation first induced the degradation of PTFE molecular chains on the sample surface, and then resulted in a change of surface morphology. The addition of Al2O3 filler significantly increased the AO resistance property of PTFE composites. Friction and wear tests indicated that AO irradiation affected the wear rate and increased the friction coefficient of specimens. The PTFE composite containing 10% Al2O3 exhibit the best AO resistance and lower wear rate after long time AO irradiation. 相似文献
10.
The present work reports a simple and time-saving method to fabricate cupric stearate film on zinc substrate by a solution-immersion process. Superhydrophobic surfaces are conventionally prepared employing two steps: roughening a surface and lowering its surface energy. The fabrication of superhydrophobic cupric stearate surface is reported using a one-step process by immersing a zinc plate coated with copper into the stearic acid solution, simplifying the complexity of two different steps involved in the conventional methods. The surface of the zinc plate coated with copper is found to be covered with low surface energy cupric stearate film providing the water contact angle of 160 ± 1° with the rolling off properties. In addition, the damaged superhydrophobic surface can restore superhydrophobicity property by immersing the surface into the stearic acid solution again. 相似文献