Enhancement of light-emitting efficiency of OLED by the electromagnetic-wave tunneling

In this Letter we present a new method enhancing the light-emission efficiency by electromagnetic-wave tunneling. The tunneling through negative-permittivity media has been confirmed recently. Under the conditions required by the method the transmittance of the emitted light can be close to unit for the normal incidence and also holds for the case of oblique incidence. The conditions of the tunneling for the proposed structure are given for E and H polarization, respectively.     

Amplification without population inversion in a three-level Λ-type system with an external coherent magnetic field

In this Letter, we investigate the amplification without inversion (AWI) in a new scheme, a three-level Λ-type system which the two lower states are coupled by an external magnetic field. We find that, owing to the presence of the external magnetic field, the absorption of the probing field is very sensitive to the relative phase of the probing and the pumping fields. By appropriately choosing the Rabi frequency of the pumping field, the Lamor frequency of the external magnetic field and the relative phase, AWI can be realized.     

Global well-posedness for the 3-D MHD equations with partial diffusion in the periodic domain

In this paper, we prove the global well-posedness of the 3-D magnetohydrodynamics(MHD) equations with partial diffusion in the periodic domain when the initial velocity is small and the initial magnetic field is close to a background magnetic field satisfying the Diophantine condition.     

A new three-particle-interaction model to predict the thermodynamic properties of different electrolytes

In this study, Guggenheim charging process, which involves the radial Boltzmann distribution, was introduced to develop a new predictive model with three parameters, ion–ion distance parameter, ion–solvent parameter, and solvation parameter. In this model, the ion–ion and ion–solvent molecule interaction are all included in the charging process, and it is independent of the temperature and solvent. This new model was applied to correlate the experimental data from literatures for 208 electrolytes aqueous solution at T = 298.15 K of which the concentration range is wide. The calculated results agreed well with the experimental ones for most electrolytes, especially for the prediction in high ionic strength. The estimation of solvation parameter S also gave that the solvation tendency for cations and anions follow a trend, which is in consistent with results published in literature. Investigations were also been made in calculations for electrolytes solutions at other temperatures and non-aqueous system, which proved this model was also feasible.     

Unlabeled Fluoroimmunoassay with a Europium Chelate

Unlabeled fluoroimmunoassay with a europium chelate is described. The recommended method is simple because the complicated labeling process is omitted. The recovery of some samples ranges from 91 to 111%. The relative standard deviation of the method is less than 10%. The detection limit is about 10⁻¹⁰mol liter⁻¹antigen.     

Synthesis and Characteristics of a New Fluorogenic Substrate for Horseradish Peroxidase

N,N′-Dicyanomethyl-o-phenylenediamine was synthesized with a 90% yield by a reaction ofo-phenylenediamine with chloroacetonitrile in triethylamine. Our experimental results showed that it was the effective fluorogenic substrate for horseradish peroxidase (HRP) and hemin. TheK_mfor the HRP system was 48 μM,and that for hemin was 1.3 μM.Properties of the substrate were evaluated from the detection limits of enzymes and H₂O₂. The linear ranges for the determination of HRP and hemin were 21–150 pMand 2–20 nM,respectively. The linear range for the determination of H₂O₂using HRP or hemin was 18–140 and 60–1000 nM,respectively. The structural elucidation of the fluorescent product using NMR and mass spectral techniques was proposed to be 1,2-dihydro-2-imido-imidazo[1,2-a] quinoxaline. Based on the product structure and earlier reports, the possible reaction mechanism of HRP and the substrate was also proposed, i.e., two steps for ring closures, one step of isomerization, and a final step of oxidative dehydrogenation.     

The extended negative factor counting method for tridiagonal block matrices with cross links

The NFC (negative factor counting) method ws extended to solve the eigenvalue problem of tridiagonal block matrices with elements corresponding to cross links which may be derived from the quantum-chemical calculation on a native protein molecule. The mathematical proof of the necessary theorem is given in detail.     

Synthesis and X-ray crystal structure of oxamido-bridged heterobinuclear Ni(Ⅱ)-Cu(Ⅱ) complexes

The two complexes [Ni(oxen)Cu(L)2](ClO4)2.xH2O (L=2,2'-bipyridyl(bpy), 1,10-phenanthroline(phen)) have been synthesized, where oxen is N,N'-bis(2-aminoethyl)oxamido di-anion. The crystal structure of [Ni(oxen)Cu(bpy)2](ClO4)2.CH3OH has been determined by X-ray diffraction method. The crystal is triclinic system, space group P1 with a=12.179(1),b=12.298(2), c=11.476(2) A, a=97.57(1), B=97.52(1), 7=80.29(2), V=1669.04(67) A3, Z=2, Dcalcd=1.667 g/cm3. The structure has been refined to final R of 0.076 and Rw of 0.080, respectively. The complexes have an extended oxamido-bridged structure and consist of Ni(Ⅱ) ion in a square planar environment and Cu(Ⅱ) ion in a distorted octahedral environment.     

Metal ion separation and concentration with supported liquid membranes

An experimental study of metal ion separations by supported liquid membranes is described. The supported liquid membranes (SLMs) use the extraction reagents D2EHPA, LIX 64N, DNNSA and Aliquat 336 as carriers. SLMs with different geometries (plane and cylindrical) have been studied and the experimental results have been compared with the results obtained from mathematical models. The best experimental conditions to perform a Cu(II)Zn(II) separation and Cr(III) and Cr(VI) recovery have been identified.