全文获取类型
收费全文 | 3202篇 |
免费 | 358篇 |
国内免费 | 271篇 |
专业分类
化学 | 2427篇 |
晶体学 | 40篇 |
力学 | 146篇 |
综合类 | 15篇 |
数学 | 325篇 |
物理学 | 878篇 |
出版年
2023年 | 35篇 |
2022年 | 32篇 |
2021年 | 78篇 |
2020年 | 98篇 |
2019年 | 120篇 |
2018年 | 94篇 |
2017年 | 77篇 |
2016年 | 126篇 |
2015年 | 159篇 |
2014年 | 171篇 |
2013年 | 243篇 |
2012年 | 292篇 |
2011年 | 276篇 |
2010年 | 187篇 |
2009年 | 195篇 |
2008年 | 229篇 |
2007年 | 188篇 |
2006年 | 165篇 |
2005年 | 160篇 |
2004年 | 108篇 |
2003年 | 104篇 |
2002年 | 94篇 |
2001年 | 55篇 |
2000年 | 43篇 |
1999年 | 43篇 |
1998年 | 33篇 |
1997年 | 26篇 |
1996年 | 25篇 |
1995年 | 30篇 |
1994年 | 29篇 |
1993年 | 15篇 |
1992年 | 20篇 |
1991年 | 20篇 |
1990年 | 17篇 |
1989年 | 13篇 |
1987年 | 7篇 |
1986年 | 6篇 |
1985年 | 11篇 |
1984年 | 6篇 |
1982年 | 5篇 |
1980年 | 25篇 |
1978年 | 19篇 |
1977年 | 46篇 |
1976年 | 16篇 |
1975年 | 18篇 |
1974年 | 11篇 |
1973年 | 5篇 |
1970年 | 5篇 |
1968年 | 5篇 |
1943年 | 10篇 |
排序方式: 共有3831条查询结果,搜索用时 21 毫秒
1.
Annals of Global Analysis and Geometry - Let $$(T^k,h_k)=(S_{r_1}^1\times S_{r_2}^1 \times \cdots \times S_{r_k}^1, dt_1^2+dt_2^2+\cdots +dt_k^2)$$ be flat tori, $$r_k\ge \cdots \ge r_2\ge... 相似文献
2.
3.
通过制备磁性大孔有机共聚物材料(Fe3O4@SiO2@PLS)和磁性金属有机骨架材料(Fe3O4@ZIF-8),将两种材料同时作为磁性吸附剂,建立了混合吸附剂磁性固相萃取/高效液相色谱-串联质谱(MSPE/HPLC-MS/MS)测定水中4种磺胺类和8种喹诺酮类抗生素残留的分析方法.通过扫描电子显微镜(SEM)、傅里叶变换红外光谱(FT-IR)和X-射线衍射仪(XRD)对两种磁性材料进行表面形貌和结构表征,结果显示,亲水亲脂大孔有机共聚物(PLS)包覆于磁性纳米粒子Fe3O4表面,且Fe3O4成功附着于正六边形金属有机骨架材料(ZIF-8)晶体表面,可以满足磁性固相萃取的要求.通过优化吸附剂用量、萃取方式、吸附时间、样品pH值、洗脱剂种类及洗脱时间,在最优的实验条件下,12种目标物的线性范围为0.5~10μg/L,相关系数(r2)为0.9961~0.9998,检出限(S/N=3)为0.01~0.14μg/L,定量下限(S/N=10)为0.04~0.45μg/L.所建方法成功用于水中12种目标抗生素的检测,在3个加标水平下的回收率为75.0%~107%,相对标准偏差(RSD)为0.50%~5.5%.该方法适用于水中痕量磺胺类和喹诺酮类抗生素残留的分析. 相似文献
4.
Yiguang Ju 《Proceedings of the Combustion Institute》2021,38(1):83-119
Low-temperature flames such as cool flames, warm flames, double flames, and auto-ignition assisted flames play a critical role in the performance of advanced engines and fuel design. In this paper, an overview of the recent progresses in understanding low-temperature flames and dynamics as well as their impacts on combustion, advanced engines, and fuel development will be presented. Specifically, at first, a brief review of the history of cool flames is made. Then, the recent experimental studies and computational modeling of the flame structures, dynamics, and burning limits of non-premixed and premixed cool flames, warm flames, and double flames are presented. The flammability limit diagram and the temperature-dependent chain-branching reaction pathways, respectively, for hot, warm, and cool flames at elevated temperature and pressure will be discussed and analyzed. After that, the effect of low temperature auto-ignition of auto-igniting mixtures at high ignition Damköhler numbers at engine conditions on the propagation of cool flames, warm flames, and double flames as well as turbulent flames will be discussed. Finally, a new platform using low temperature flames for the development and validation of chemical kinetic models of alternative fuels will be presented. Discussions of future research of the dynamics and control of low temperature flames under engine conditions will be made. 相似文献
5.
Russian Journal of Organic Chemistry - N-Aryl anthranilic acid drugs have been synthesized by a simple, environmentally friendly, low-cost, and high-yielding modified Ullmann coupling reaction... 相似文献
6.
Sim Woojeong Lee Booyeong Kim Dong Ju Lee Jeong A Kim Jaewon Chung Jintai 《Nonlinear dynamics》2022,108(2):987-1004
Nonlinear Dynamics - This study analyzes the vibro-impact behavior of two adjacent cantilever beams subjected to vibration generated by applying harmonic excitation to their rigid base. For the... 相似文献
7.
Russian Journal of Organic Chemistry - (Z)-2-(5-Amino-1,2,4-thiadiazole-3-yl)-2-(methoxyimino)acetic acid, an important intermediate product in the synthesis of Ceftobiprole, was prepared... 相似文献
8.
Huiwen Zheng Hailin Zhang Yu Fan Ge Ju Hongbin Zhao Jianhui Fang Jiujun Zhang Jiaqiang Xu 《中国化学快报》2020,31(1):210-216
Recently,the development of new electrode materials for lithium-ion batteries(LIBs)has received intensive attention.As an important family of inorganic materials,mixed Mo-based transition metal oxides system is focused as anode materials.In the present work,a simple route has been adopted for the synthesis of layered-flake-likeβ-SnMo04 Nano-assemblies,which have been explored as potential anode materials for the first time in lithium-ion battery(LIB).Overall,the current reports on metal molybdate as anode materials are still rarely.As the anode material for LIBs,it was observed that the fabricated anode is capable of delivering a steady state capacity of almost 400 mAh/g up to 300 cycles under the influence of200 mA/g current density.Further,the anode material is suitable for use as a rated capacity anode because of its high current density tolerance.The present study can be further extended for the generation of a wide variety of other novel materials for multidisciplinary energy related applications. 相似文献
9.
QiuHong Wang Abdusalam Abdukerim Wei Chen Xun Chen YunHua Chen XiangYi Cui YingJie Fan DeQing Fang ChangBo Fu LiSheng Geng Karl Giboni Franco Giuliani LinHui Gu XuYuan Guo Ke Han ChangDa He Di Huang Yan Huang YanLin Huang Zhou Huang Peng Ji XiangDong Ji YongLin Ju YiHui Lai Kun Liang HuaXuan Liu JiangLai Liu WenBo Ma YuGang Ma YaJun Mao Yue Meng Parinya Namwongsa KaiXiang Ni JinHua Ning XuYang Ning XiangXiang Ren ChangSong Shang Lin Si AnDi Tan AnQing Wang HongWei Wang Meng Wang SiGuang Wang XiuLi Wang Zhou Wang MengMeng Wu ShiYong Wu JingKai Xia MengJiao Xiao PengWei Xie BinBin Yan JiJun Yang Yong Yang ChunXu Yu Jumin Yuan Dan Zhang HongGuang Zhang Tao Zhang Li Zhao QiBin Zheng JiFang Zhou Ning Zhou XiaoPeng Zhou 《中国科学:物理学 力学 天文学(英文版)》2020,(3):54-63
In dark matter direct detection experiments,neutron is a serious source of background,which can mimic the dark matter-nucleus scattering signals.In this paper,we present an improved evaluation of the neutron background in the PandaX-II dark matter experiment by a novel approach.Instead of fully relying on the Monte Carlo simulation,the overall neutron background is determined from the neutron-induced high energy signals in the data.In addition,the probability of producing a dark-matter-like background per neutron is evaluated with a complete Monte Carlo generator,where the correlated emission of neutron(s)andγ(s)in the(α,n)reactions and spontaneous fissions is taken into consideration.With this method,the neutron backgrounds in the Run 9(26-ton-day)and Run 10(28-ton-day)data sets of PandaX-II are estimated to be(0.66±0.24)and(0.47±0.25)events,respectively. 相似文献
10.
采用施加压力的方法将聚苯硫醚熔体凝固,凝固后获得的聚苯硫醚样品经过降温和卸压后在常温常压下回收. X射线衍射和差示扫描量热分析表明:约20 ms时间的快速压缩过程可以抑制熔体结晶,制备出非晶态聚苯硫醚块材,样品的表面及中心都是非晶态.非晶态聚苯硫醚的玻璃化转变温度和晶化温度分别为318和362 K.常压下的退火实验表明,非晶态聚苯硫醚在425 K等温结晶的产物为正交相晶型.压致凝固法中熔体的凝固不是靠温度变化,而是靠压力变化,样品表面和内部处在一致的温度下同时受压凝固,避免了热传导对非晶尺寸的影响,因此非常有利于获得结构均匀的大尺寸非晶态材料. 相似文献