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排序方式: 共有90条查询结果,搜索用时 15 毫秒
1.
Cheng Sheng Dr. Zheng Ling Dr. Tanveer Ahmad Prof. Dr. Fang Xie Prof. Dr. Wanbin Zhang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(23):e202200128
Regioselective [3+3] annulation of alkynyl ketimines with α-cyano ketones for the synthesis of polysubstituted 4H-pyran derivatives with a quaternary CF3-containing center has been realized by using Cu(OAc)2 as the catalyst. The novel strategy tolerates a wide range of α-CF3 alkynyl ketimines and α-cyano ketones with both aryl and alkyl substitutents. A preliminary asymmetric synthesis of chiral product 3 has been attempted by using copper and chiral thiourea as the cocatalyst with excellent yields (86-99 %) and good enantioselectivities (71–78 % ee). Furthermore, product 3 aa could be obtained on a gram-scale reaction with 75 % yield and 99 % ee after recrystallization. Several products were also transformed readily. Control experiments indicate that the reaction involves a process with a base-catalyzed or chiral thiourea-catalyzed Mannich-type reaction followed by a highly regioselective copper-catalyzed ring-closing reaction on the alkynyl moiety in a 6-endo-dig fashion. 相似文献
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3.
R. Santhosh Reddy Tanveer Mahamadali Shaikh Varun Rawat Pratibha U. Karabal Gajanan Dewkar Gurunath Suryavanshi Arumugam Sudalai 《Catalysis Surveys from Asia》2010,14(1):21-32
A novel, exceptionally stable titanium superoxide radical ion was prepared and its structure determined by FTIR, ESR, Raman
spectroscopy, X-ray diffraction, thermogravimetric/differential thermal analysis and elemental analysis. This heterogeneous
catalyst has been found to be effective for the selective oxidation of aromatic amines and phenols to the corresponding nitro
aromatics and p-quinones, respectively. In addition, this non-toxic, inexpensive and reusable catalyst has also been used in aminobromination
of olefins, which proceed to give the 1, 2-bromoaminated anti-Markovnikov product. A brief account of these results is summarized in this review. 相似文献
4.
Afaq Shagufta Khan Sadia Kazmi Mehdi Hassan Fatima Itrat Malik Abdul Inamullah Farah Farhad Zahid Abbas Tanveer Tareen Rasool Bakhsh 《Chemistry of Natural Compounds》2021,57(2):269-273
Chemistry of Natural Compounds - Armatans A (1) and B (2), new isoflavans, have been isolated from the EtOAc-soluble fraction of the MeOH extract of Colutea armata Hemsl. & Lace, along with... 相似文献
5.
Tanveer Hussain Bokhari Muhammad Bilal Butt Saira Hina Munawar Iqbal Muhammad Daud Muhammad Imran 《Journal of Radioanalytical and Nuclear Chemistry》2017,314(3):1487-1496
The field of therapeutic nuclear medicine is emerging rapidly as choice of treatment in oncology and other cellular malignancies. The growth of this branch of nuclear medicine is greatly facilitated by the introduction of a number of new radiopharmaceuticals and radionuclides. 90Y-radiopharmaceuticals have confirmed their worth in medical and clinical areas in a very short span of time. The 90Y is a radioisotope widely used for therapeutic purposes and considerable perfection has been made to understand the chemistry of 90Y-labeled radiopharmaceuticals. The development of these radiopharmaceuticals can be made favorable by using appropriate buffer, incubation period, optimal pH, specific activity and reaction temperature. In this review, we have discussed the preparation of range of 90Y transporting biological molecules such as antibodies radiolabeled peptides, antigens and microsphere with their clinical applications. 相似文献
6.
Tanveer AhmadHongsub Bae Ilsu Rhee Yongmin ChangJaejun Lee Sungwook Hong 《Current Applied Physics》2012,12(3):969-974
We investigate the particle size dependence of the relaxivity of hydrogen protons in an aqueous solution of iron oxide (Fe3O4) nanoparticles coated in silica for biocompatibility. The T1 and T2 relaxation times for various concentrations of silica-coated nanoparticles were determined by a magnetic resonance scanner. We find that the relaxivity increased linearly with increasing particle size. The T2 relaxivity (R2) is more than 50 times larger than the T1 relaxivity (R1) for the nanoparticle contrast agent, which reflects the fact that the T2 relaxation is mainly influenced by outer sphere processes. The high R2/R1 ratio demonstrates that silica-coated iron oxide nanoparticles may serve as a T2 contrast agents in magnetic resonance imaging with high efficacy. 相似文献
7.
Tanveer M. Shaikh 《Tetrahedron letters》2005,46(33):5589-5592
NaIO4 oxidizes lithium bromide efficiently under acidic conditions to functionalize alkylbenzenes and alkanes and produce the corresponding bromo and acetoxy derivatives in excellent yields. The protocol also demonstrates the direct conversion of cyclohexane into trans-1,2-dibromocyclohexane in moderate yield. 相似文献
8.
NaIO4-mediated selective oxidation of alkylarenes and benzylic bromides/alcohols to carbonyl derivatives using water as solvent 总被引:1,自引:0,他引:1
A new transition-metal-free, sodium metaperiodate (NaIO4)-mediated direct oxidation of methylarenes and benzylic bromides to the corresponding aromatic carboxylic acids is described. Under the same reaction conditions, benzylic alcohols are selectively oxidized to afford the corresponding aldehydes in good yields without undergoing overoxidation. Unprecedentedly, oxidation of benzyl bromide, toluene, or benzyl alcohol with NaIO4 underwent nuclear bromination followed by oxidation to give 4-bromobenzoic acid in 60-79% yields. 相似文献
9.
Tanveer ul Haq Zia Ahmad Nawaz Khan Majid Hussain Ibrar Hassan Iftikhar Hussain Gul 《高分子科学》2016,34(12):1500-1509
The dielectric and mechanical properties of hybrid polymer nanocomposites of polystyrene/polyaniline/carbon nanotubes coated with polyaniline(PCNTs) have been investigated using impedance analyzer and extensometer. The blends of PS/PANI formed the heterogeneous phase separated morphology in which PCNTs are dispersed uniformly. The incorporation of a small amount of PCNTs into the blend of PS/PANI has remarkably increased the dielectric properties. Similarly, the AC conductivity of PS/PANI is also increased five orders of magnitude from 1.6 × 10~(-10) to 2.0 × 10~(-5) S·cm~(-1) in the hybrid nanocomposites. Such behavior of hybrid nanocomposites is owing to the interfacial polarization occurring due to the presence of multicomponent domains with varying conductivity character of the phases from insulative PS to poor conductor PANI to highly conductive CNTs. Meanwhile, the tensile modulus and tensile strength are also enhanced significantly up to 55% and 160%, respectively, without much loss of ductility for three phase hybrid nanocomposites as compared to the neat PS. Thereby, the hybrid nanocomposites of PS/PANI/_P CNTs become stiffer, stronger and tougher as compared to the neat systems. 相似文献
10.